Development of an innovative powder adhesive based on epoxy-polyester and lignin for production of particleboards
Source abstract
Abstract
This study presents the development of innovative particleboards bonded with a hybrid powder adhesive composed of epoxy-polyester resin and kraft lignin, aiming to eliminate formaldehyde and volatile organic compounds (VOCs) from the manufacturing process. While powdered epoxy-polyester adhesives are well established in the metal and automotive sectors, their application in wood composites remains largely unexplored and only limited research has explored their potential for particleboard production. Particleboards were manufactured using varying proportions of kraft lignin (0–100%) to partially or fully replace the epoxy-polyester base. The optimal performance was observed with 20% lignin substitution, where mechanical properties such as modulus of rupture (MOR = 8.3 MPa), modulus of elasticity (MOE = 1455 MPa), and internal bond (IB = 0.21 MPa) were comparable to or exceeded those of the control variant without lignin. Despite lower mechanical performance at high lignin ratios (≥80%), 100% lignin-based boards exhibited improved thermal stability and fire resistance, confirmed by TGA, DSC, and cone calorimetry. SEM analysis revealed that lignin contributed to good particle coverage and homogeneous bonding. These results demonstrate the feasibility of using kraft lignin in powder form as a binder or co-binder in wood-based composites. Such particleboards offer a promising alternative for applications in interior non-load-bearing construction and eco-friendly furniture manufacturing.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Lignin and Wood Chemistry · Flame retardant materials and properties · Natural Fiber Reinforced Composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (79)
Show source-provided references
1. Capability of producing lignin-based phenol formaldehyde adhesive for oil palm mesocarp fiber particleboard production with lignin extracted from industrial waste liquor from the kraft pulping process10.1016/j.matpr.2023.05.360 ↗
2. Adhesive systems used in the European particleboard, MDF and OSB industries10.1080/17480272.2017.1396622 ↗
3. Lignin modifications, applications, and possible market prices10.3390/en15186520 ↗
4. A review of the traditional pulping methods and the recent improvements in the pulping processes10.1007/s13399-020-01243-6 ↗
5. A concise review of current lignin production, applications, products and their environmental impact10.1016/j.indcrop.2019.111526 ↗
6. Lignin-based copolymer adhesives for composite wood panels – A review10.1016/j.ijadhadh.2019.102408 ↗
7. Sulfonated Kraft lignin addition in urea–formaldehyde resin10.1007/s10973-019-08075-1 ↗
8. Bio-based epoxy adhesives with lignin-based aromatic monophenols replacing bisphenol A10.3390/polym13223879 ↗
9. A comparison among lignin modification methods on the properties of lignin–phenol–formaldehyde resin as wood adhesive10.3390/polym13203502 ↗
10. Experimental and theoretical investigations of lignin-urea-formaldehyde wood adhesive: density functional theory analysis10.1016/j.ijadhadh.2020.102737 ↗
11. Unlocking the role of lignin for preparing the lignin-based wood adhesive: a review10.1016/j.indcrop.2022.115388 ↗
12. A review on lignin-based epoxy resins: lignin effects on their synthesis and properties10.1016/j.ijbiomac.2022.12.322 ↗
13. Influence of lignin content and pressing time on plywood properties bonded with cold-setting adhesive based on poly (Vinyl Alcohol), lignin, and hexamine10.3390/polym14102111 ↗
14. Modification of plywood with phenol–formaldehyde resin: substitution of phenol by pyrolysis cleavage products of softwood kraft lignin
15. Effect of the addition of lignin on the physical-mechanical properties of particleboards made with pine/hydrangea stems10.1080/20426445.2021.1998301 ↗
16. Novel kraft-lignin-based adhesives for the production of particleboards10.1016/j.compstruct.2024.118344 ↗
17. Hýsek Š., Sahula L., Němec M., Żółtowska S., Kytka T., Wimmer R. Non-standard adhesives for wood-based composites: powder adhesives and bicomponent fibers. J Adhes Sci Technol n.d.;0:1–23. https://doi.org/10.1080/01694243.2024.2423005.10.1080/01694243.2024.2423005 ↗
18. Some of the properties of oriented strandboard manufactured using kraft lignin phenolic resin10.1016/j.jmatprotec.2007.10.039 ↗
19. Fungus-modified lignin and its use in wood adhesive for manufacturing wood composites
20. Partial substitution of pMDI with lignin containing cellulose nanofibrils: low density oriented strand board10.1080/17480272.2020.1769722 ↗
21. Impregnated paper-based decorative laminates prepared from lignin-substituted phenolic resins10.32604/jrm.2020.09755 ↗
22. Paper-based laminates impregnated with a hybrid lignin-phenol-formaldehyde resin10.3390/ma16072669 ↗
23. Hemmilä V., Trischler J., Sandberg D. Lignin: an adhesive raw material of the future or waste of research energy?, 2013, p. 98–103.
24. A review of preparation of binderless fiberboards and its self-bonding mechanism10.1007/s00226-015-0728-6 ↗
25. Chemical modification of plasticized lignins using reactive extrusion10.3389/fchem.2019.00633 ↗
26. The role of lignin in wood working processes using elevated temperatures: an abbreviated literature survey10.1007/s00107-020-01637-3 ↗
27. Suitability of steam exploded residual softwood for the production of binderless panels. Effect of the pre-treatment severity and lignin addition10.1016/S0961-9534(01)00031-9 ↗
28. Overview of the synthesis, characterization, and application of tannin-glyoxal adhesive for wood-based composites10.32604/jrm.2024.051854 ↗
29. Bio-based adhesives and evaluation for wood composites application10.3390/polym9020070 ↗
30. Environmentally friendly starch-based adhesives for bonding high-performance wood composites: a review10.3390/f13101614 ↗
31. A review on citric acid as green modifying agent and binder for wood10.3390/polym12081692 ↗
32. Influence of citric acid on the bond strength of beech wood10.3390/polym13162801 ↗
33. Effect of addition of clay minerals on the properties of epoxy/polyester powder coatings
34. Rapid cure composites used in spray and paints industry
35. Preparation and characterization of fast-curing powder epoxy adhesive at middle temperature10.1098/rsos.180566 ↗
36. Powder coating of veneered particle board surfaces by hot pressing10.1016/j.porgcoat.2013.09.018 ↗
37. Thermochemical and isoconversional kinetic analysis of a polyester–epoxy hybrid powder coating resin for wood based panel finishing10.1016/j.porgcoat.2010.09.023 ↗
38. Influence of thermo-analytical and rheological properties of an epoxy powder coating resin on the quality of coatings on medium density fibreboards (MDF) using in-mould technology10.1016/j.porgcoat.2013.10.016 ↗
39. Atmospheric Pressure Plasma Coating of Wood and MDF with Polyester Powder10.3390/coatings7100171 ↗
40. Application of electrostatic powder coating on wood composite panels using a cooling method. Part 1: Investigation of water intake, abrasion, scratch resistance, and adhesion strength
41. Hýsek Š., Němec M., Herclík M., Kubista K. Lisovaný kompozitní materiál na bázi třísek z recyklovaného dřeva a práškového lepidla (Pressed composite material based on recycled wood particles and powdered adhesive) - 35365 2021.
42. Hýsek Š., Němec M., Herclík M., Kubista K. Technology of production process of lignin-modified powder adhesive, lignin; wood; powder adhesive; composite materiál - TP01010050-V16 2022.
43. Formaldehyde and VOC emissions at different manufacturing stages of wood-based panels10.1016/j.buildenv.2011.07.023 ↗
44. Formaldehyde emission and VOCs from LVLs produced with three grades of urea-formaldehyde resin modified with nanocellulose10.1016/j.buildenv.2015.12.009 ↗
45. ISO 11358-1; Plastics — Thermogravimetry (TG) of polymers - Part 1: General principles 2015.
46. ISO 5660-1; Reaction-to-fire tests — Heat release, smoke production and mass loss rate — Part 1: Heat release rate (cone calorimeter method) and smoke production rate (dynamic measurement) 2015.
47. ČSN E.N. 310; Wood based panels. Determination of modulus of elasticity in bending and of bending strength 1995.
48. ČSN E.N. 319; Particleboard and fibreboard. Determination of tensile strength perpendicular to the plane of the board 1994.
49. ČSN E.N. 317; Particleboards and fibreboards. Determination of swelling in thickness after immersion in water 1995.
50. Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose10.1016/j.vibspec.2004.02.003 ↗
51. Choosing the Right Lignin to Fully Replace Bisphenol A in Epoxy Resin Formulation10.1002/cssc.202002729 ↗
52. Sub-Micro Organosolv Lignin as Bio-Based Epoxy Polymer Component: A Sustainable Curing Agent and Additive10.1002/cssc.202300076 ↗
53. Black liquor-based epoxy resin: Thermosets from untreated kraft lignin10.1016/j.cej.2023.145787 ↗
54. Analysis of Adhesives
55. Bio-based flame retardants: When nature meets fire protection10.1016/j.mser.2017.04.001 ↗
56. Phosphorus and nitrogen derivatization as efficient route for improvement of lignin flame retardant action in PLA10.1016/j.eurpolymj.2016.10.003 ↗
57. Characterization and properties of ion exchangers produced from lignin precipitated after peroxyacid pulping10.15376/biores.3.2.538-548 ↗
58. Thermal modification of wood—a review: chemical changes and hygroscopicity10.1007/s10853-020-05722-z ↗
59. Crosslinking of epoxy-modified phenol novolac (EPN) powder coatings: Particle size and adhesion10.1007/BF02697961 ↗
60. Thermogravimetric Analysis (TGA)
61. Effect of Lignin or Lignosulfonate Addition on the Fire Resistance of Areca (Areca catechu) Particleboards Bonded with Ultra-Low-Emitting Urea-Formaldehyde Resin10.3390/fire6080299 ↗
62. Environmentally friendly protection of European beech against fire and fungal decay using a combination of thermal modification and mineralisation10.1080/17480272.2023.2223508 ↗
63. Wood-based materials with integrated flame-retardancy through lignin adhesive. Fraunhofer Inst Wood Res BrWilhelm-Klauditz-Inst WKI 2020. 〈https://www.wki.fraunhofer.de/en/research-projects/2020/FlammLig_wood-based-materials-with-integrated-flame-retardancy-through-lignin-adhesive.html〉 (accessed February 12, 2025).
64. Burning Properties of Combined Glued Laminated Timber10.3390/fire7010030 ↗
65. A comprehensive review of lignin-reinforced lignocellulosic composites: Enhancing fire resistance and reducing formaldehyde emission10.1016/j.ijbiomac.2024.137714 ↗
66. Recent Developments in Flame-Retardant Lignin-Based Biocomposite: Manufacturing, and characterization10.1007/s10924-022-02494-2 ↗
67. Facile synthesis of intrinsically flame-retardant epoxy thermosets with high mechanical properties from lignin derivatives
68. The effect of lignin as a natural adhesive on the physico-mechanical properties of Vitis vinifera fiberboards10.15376/biores.6.3.2851-2860 ↗
69. Approaching a new generation of fiberboards taking advantage of self lignin as green adhesive10.1016/j.ijbiomac.2017.11.005 ↗
70. ČSN E.N. 302-1; Adhesives for load-bearing timber structures - Test methods - Part 1: Determination of longitudinal tensile shear strength 2013.
71. Wood-based composite made of wood waste and epoxy based ink-waste as adhesive: a cleaner production alternative10.1016/j.jclepro.2018.05.087 ↗
72. Effect of polyethylene on the physical and mechanical properties of particleboard10.1002/masy.201600030 ↗
73. Utilization of recycled poly vinyl chloride (PVC) in combination with wood particles and urea formaldehyde resin as binder to produce multi-layer particle board10.1007/s13196-013-0096-5 ↗
74. Improving core bond strength and dimensional stability of particleboard using polymer powder in core layer10.1016/j.compositesb.2012.01.039 ↗
75. Combined effect of thermoplastic and thermosetting adhesives on properties of particleboard with rice husk core10.1590/1516-1439.286314 ↗
76. The effect of density and resin content on oil palm trunk particleboard10.4028/p-3ae794 ↗
77. About hydrophobicity of lignin: a review of selected chemical methods for lignin valorisation in biopolymer production10.3390/en15176213 ↗
78. Effect of cold plasma surface pre-treatment of wheat straw particles on straw board properties10.15376/biores.13.3.5065-5079 ↗
79. Novel lignin–beeswax adhesive for production of composites from beech and spruce particles10.1016/j.jclepro.2022.132460 ↗