Effects of superabsorbent polymers on autogenous shrinkage and microstructure in metakaolin-based cementitious materials
Source abstract
Abstract
The incorporation of superabsorbent polymers (SAPs) and metakaolin in high-strength microconcrete offers a promising strategy to enhance performance while reducing environmental impact through clinker substitution. This study evaluates the feasibility and sustainability of SAP-modified microconcretes by analyzing fresh and hardened-state properties, autogenous shrinkage, and microstructural characteristics. Three microconcrete and paste mixes were investigated: a reference mix and two containing 0.15% and 0.30% SAP by cement mass, all with 10% metakaolin substitution and a constant water/cement ratio without additional curing water. The results demonstrated that SAP effectively mitigated autogenous shrinkage, with MKSAP30 reducing shrinkage by 53% compared to the reference mix. Microstructural analysis revealed a significant refinement in the pore network, reducing the average pore diameter from 508.76 µm (MKREF) to 214.65 µm (MKSAP30), despite an increase in total porosity. Moreover, SAP-modified mixes exhibited improved hydration efficiency, as evidenced by increased C-S-H formation and calcium hydroxide content in thermogravimetric analysis. The elastic modulus increased by 5.2% and 13.9% for MKSAP15 and MKSAP30, respectively, suggesting that enhanced hydration and pozzolanic activity offset the expected mechanical loss due to porosity. These findings highlight the dual benefits of SAP incorporation: improving concrete performance while promoting sustainability. The synergy between SAP and metakaolin enhances durability and mechanical properties, making SAP-modified microconcrete a viable solution for high-performance and environmentally friendly construction applications.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Concrete Properties and Behavior · Concrete and Cement Materials Research · Innovative concrete reinforcement materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (88)
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