journal article·2026-07Open access

Mechanisms of water-softening and freeze–thaw damage in remolded slurry: Linking microscopic structure evolution to macroscopic durability

Jing Li, Long Wang, Minjie Wen, Yiming Zhang

Abstract

High water content waste slurry generated from large-diameter bored piles exists in a fluid-plastic state, severely limiting its beneficial reuse in geotechnical engineering applications. This study systematically investigates the macroscopic mechanical response, failure mode evolution, microstructural reorganization, and macro–meso coupling mechanisms of remolded waste slurry subjected to the combined effects of water softening and freeze–thaw action. By integrating unconfined compressive strength (UCS) testing, digital image correlation (DIC) monitoring, mercury intrusion porosimetry (MIP), and scanning electron microscopy (SEM) microstructural analysis, the deterioration pathways and coupling effects of water softening and freeze–thaw damage are elucidated. The results demonstrate that as the water content increases from 15% to 21%, both the UCS and the deformation modulus undergo exponential decay, and the softening coefficient exhibits a pronounced nonlinear correlation with water content. Following 12 freeze–thaw cycles, the specimen volume expands progressively and the freeze–thaw coefficient declines by 52.6%; the accompanying particle reorientation and the development of a macropore-throat-dominated pore structure constitute the microstructural origin of strength degradation. Water softening is governed by clay mineral swelling and pore water pressure, which induce non-uniform localized deformation, whereas freeze–thaw damage originates from frost heave associated with the water–ice phase transition and differential thermal contraction among mineral constituents, driving the propagation of crack networks. Under coupled conditions, elevated water content markedly amplifies freeze–thaw deterioration. A durability evaluation framework based on the softening coefficient and freeze–thaw coefficient is established. The remolded waste slurry maintains a macrostructural integrity retention rate exceeding 90% after 10 freeze–thaw cycles, demonstrating pronounced structural self-compaction and pore optimization effects.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Tailings Management and Properties · Geotechnical Engineering and Soil Mechanics · Landfill Environmental Impact Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Research on preparation and performance of clay-based shield tunnel nonsintered bricks10.1155/2021/8186851 ↗
2. Recycling of calcareous shield tunnel muck and industrial solid waste for preparation of self-consolidating backfill slurry: Perspectives on fluidity, mechanical properties, and carbon footprints
3. Strength properties of dredged soil at high water content treated with soda residue, carbide slag, and ground granulated blast furnace slag10.1016/j.conbuildmat.2020.118126 ↗
4. Properties of geopolymers sourced from construction and demolition waste: A review
5. Comparison between physicochemical combined method and conventional cement solidification method for treating heavy metal-contaminated slurry-like mud10.1016/j.jclepro.2025.146460 ↗
6. Sustainable production of construction geomaterials from waste slurry through an optimized low-carbon dewatering–solidification process10.1016/j.psep.2026.108569 ↗
7. Analysis of carbon absorption ability and macro-micro mechanism of MgO solidification carbonation slurry shield centrifugal high plasticity silt10.1016/j.jenvman.2026.128614 ↗
8. A sustainable one-step strategy for highly graphitized capacitive carbons with hierarchical micro–meso–macro porosity10.1039/D1NA00856K ↗
9. Research on the strength influence and crack evolution law of layered backfill based on macro and meso mechanical response10.1016/j.conbuildmat.2024.138493 ↗
10. Dynamic mechanical behavior of magnesium oxysulfate-based titanogypsum foamed concrete: A macro- and meso-scale investigation
11. Geocell-reinforced pourable geopolymeric clayey waste slurry: Performance as a roadway layer under cyclic loading
12. Utilization of tunnel waste slurry and steel slag for preparation of backfill grouting materials: Properties and hydration behavior
13. Diffusion mechanism of shield-synchronous grouting slurry and parameter optimization in water-rich fine sand formations
14. Hydration behavior, microstructural evolution, and mechanical performance of tailings-based solid waste cemented backfill under high-temperature conditions10.1016/j.powtec.2026.122155 ↗
15. Sustainable all-solid-waste ternary geopolymer grouting materials: Mechanical performance and microstructural evolution
16. Research on the properties and microstructural evolution of ecological flowable solidified soil prepared from water treatment plant residual sludge
17. Investigations into the cementation properties and microstructural evolution of coal-derived solid waste-cellulose ether composite grout10.1016/j.conbuildmat.2025.142742 ↗
18. Co-processing of multi-source solid wastes in a coal-water slurry gasifier: Heavy-metal emissions, distribution and environmental risks10.1016/j.jenvman.2025.128505 ↗
19. Resource utilization of waste bored pile slurry: Properties, mechanisms and environmental safety of geopolymer-based lightweight controlled low-strength materials10.1016/j.conbuildmat.2025.144864 ↗
20. Strength characteristics and microscopic mechanism of polymer MDI modified waste slurry with different water binder ratios10.1016/j.conbuildmat.2025.140817 ↗
21. Enhancing dewaterability and purification of waste engineering slurry by environmentally friendly bio-based flocculant10.1016/j.seppur.2025.132906 ↗
22. Durability and microstructure of bulk solid waste recycled concrete load-bearing block under freeze-thaw cycles
23. Enhancing pervious concrete with recycled brick–concrete aggregates through composite modification under freeze–thaw and sulfate conditions10.1016/j.conbuildmat.2025.144458 ↗
24. Influence of fine inclusions in recycled fine aggregates from clay bricks on water transport and pore structure of concrete10.1016/j.conbuildmat.2024.137796 ↗
25. Evaluation of MSA mortar pore structure characteristics in water-saturated curing environment based on Talbot gradation theory10.1016/j.conbuildmat.2024.138109 ↗
26. Evaluating fracture parameters of basalt fiber reinforced and pozzolana slurry modified recycled concrete produced from waste10.1016/j.istruc.2023.02.111 ↗
27. Strength parameters, failure patterns and constitutive model analysis of multimethyl polyphenyl isocyanate modified waste slurry under triaxial loading conditions10.1016/j.jmrt.2025.08.290 ↗
28. Enhanced freeze-thaw resilience of cement mortars through nano-SiO2 and single/hybrid basalt fiber incorporation: Assessing workability, strength, durability
29. A comprehensive review of concrete durability in freeze-thaw conditions: Mechanisms, prevention, and mitigation strategies10.1016/j.istruc.2025.108804 ↗
30. Direct utilization of wet sulfur-rich tailings in alkali-activated slag via a pre-wetting strategy
31. Recyclability potential of multi-generation carbonated recycled aggregate concrete under coupling action of high stress and freeze-thaw cycles
32. Durability of micro-cracked UHPC subjected to coupled freeze-thaw and chloride salt attacks10.1016/j.cemconcomp.2024.105471 ↗
33. Workability mechanical properties of the single and hybrid basalt fiber reinforced volcanic ash-based cement mortars after freeze-thaw cycles10.1016/j.istruc.2023.01.062 ↗
34. Effect of water saturation on mechanical characteristics and damage behavior of cemented paste backfill10.1016/j.jmrt.2021.11.078 ↗
35. Freezing-thawing performance of reactive MgO-admixed silty clay subjected to forced carbonation10.1016/j.coldregions.2021.103330 ↗
36. Durability of carbonated MgO concrete containing fly ash and ground granulated blast-furnace slag10.1016/j.conbuildmat.2018.10.121 ↗
37. Strength and microstructure characteristics of cement-soda residue solidified/stabilized zinc contaminated soil subjected to freezing–thawing cycles10.1016/j.coldregions.2020.102992 ↗
38. ASTM D4318 · 2018
39. ASTM D4972-19 · 2019
40. JTG 3430-2020 · 2020
41. Geotechnical Test Procedure · 2019
42. Micro-scale investigations on the mechanical properties of expansive soil subjected to freeze-thaw cycles10.1016/j.coldregions.2024.104128 ↗
43. The effects of freeze-thaw cycles at different initial soil water contents on soil erodibility in Chinese Mollisol region10.1016/j.catena.2020.104615 ↗
44. Microstructural evolution of saturated normally consolidated kaolinite clay under thermal cycles10.1016/j.enggeo.2023.107101 ↗
45. An alternative method to evaluate the surface free energy of mineral fillers based on the generalized washburn equation10.1016/j.conbuildmat.2019.117164 ↗
46. Seismic response of ultra-large diameter shield tunnel in upper-soft and lower-hard site: Shaking table tests and numerical simulations10.1016/j.soildyn.2022.107634 ↗
47. The influence of long-time water intrusion on the mineral and pore structure of coal10.1016/j.fuel.2020.119848 ↗
48. Experimental study of water distribution affected by stress sensitivity and pore-fracture compressibility of low-rank coals with different levels of water saturation