Influence of water-repellent admixtures (Sitren and Stearate materials) on the microstructure and mechanical performance of conventional Portland cement paste and mortar
Source abstract
Abstract
The longevity of mortar and concrete structures can be compromised by the absorption of water and other fluids, leading to deterioration and aesthetic issues. To address this, water-repellent admixtures are employed to enhance the service life of mortar and concrete components by improving their mechanical and microstructural characteristics. This study focus on the effects of incorporating Sitren P 750 and various stearate materials (calcium, zinc, aluminum, and barium) as admixtures with ordinary Portland cement at mortar and paste dosages of 0.5 %, 1.0 %, and 1.5 % of the cement content. We found that mortars with water-repellent admixtures exhibited competitive mechanical properties at all curing ages. Additionally, the study confirmed the contribution of these admixtures to the production of hydration products and the structural development of the mortars, as investigated through scanning electron microscopy, thermogravimetric–derivative thermogravimetric, and X-ray diffraction analyses. Despite alterations in several physical properties and hydration kinetics due to the water-repellent compounds and their dosages, all admixtures provided effective water-repellent protection. This was further corroborated by water contact angle tests and the measurement of the capillary water absorption coefficient for all samples. Identifying the optimal mixture ratio for construction technology and effectively incorporating repellence features is a crucial aspect of this research.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Innovations in Concrete and Construction Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (75)
Show source-provided references
1. Dodson · 2013
2. Kurdowski · 2014
3. Experimental research on influences on mechanical property of C50 waterproof concrete by basalt fiber
4. ‘‘Experimental analysisof waterproofing polymeric pavementsfor concrete bridge
5. Polymers in concrete: a vision for the 21st century10.1016/S0958-9465(99)00032-3 ↗
6. Statistical analysis of the physical properties and durability of water-repellent mortars made with limestone cement, natural hydraulic lime and pozzolana-lime10.1016/j.conbuildmat.2014.12.109 ↗
7. Hydraulic lime mortars with siloxane for waterproofing historic masonry10.1016/j.cemconres.2006.11.007 ↗
8. Hydrophobicity and efflorescence of lightweight fly ash geopolymer incorporated with calcium stearate10.1016/j.jclepro.2022.132449 ↗
9. Improving concrete pavement performance in relation to combined effects of freeze–thaw cycles and de-icing salt
10. Properties of water-repellent concrete mortar containing superhydrophobic oyster shell powder10.1016/j.conbuildmat.2022.127423 ↗
11. Development of water-repellent cement mortar using silane enriched with nanomaterials10.1016/j.porgcoat.2018.08.021 ↗
12. Improving microstructures of concrete using Ca(C18H35O2)210.1016/j.proeng.2015.11.086 ↗
13. Properties of foamed concrete containing water repellents10.1016/j.conbuildmat.2016.06.148 ↗
14. Effect of water-repellent admixtures on the behaviour of aerial lime-based mortars10.1016/j.cemconres.2009.07.026 ↗
15. The influence of water-repellent admixtures on the behaviour and the effectiveness of Portland limestone cement mortars10.1016/j.cemconcomp.2015.02.004 ↗
16. The effects of calcium stearate on mechanical and durability aspects of self-consolidating concretes incorporating silica fume/natural zeolite10.1016/j.conbuildmat.2019.07.144 ↗
17. An alternative admixture to reduce sorptivity of alkaliactivated slag cement by optimising pore structure and introducing hydrophobic. film10.1016/j.cemconcomp.2018.11.004 ↗
18. Influence and effectiveness of water-repellent admixtures on pozzolana–lime mortars for restoration application10.1016/j.conbuildmat.2013.08.030 ↗
19. Multi-crystallization enhancer for concrete waterproofing by pore blocking10.1016/j.conbuildmat.2020.121668 ↗
20. Managing thermal effects in waterproofed concrete with multi-crystallization enhancer10.1016/j.cement.2022.100050 ↗
21. The morphology of entrained air voids in hardened cement paste generated with different anionic surfactants10.1016/j.cemconcomp.2008.02.003 ↗
22. KSL 5201 (Cement Type I) .
23. Uses and specifications of silica sand
24. Artificial weathering of water-repellent mortars suitable for restoration applications
25. The impact of calcium stearate on characteristics of concrete10.1007/s42107-019-00161-x ↗
26. Zinc stearate: its properties and uses10.1108/eb041810 ↗
27. The properties of aluminium stearate and its uses in the coatings and allied industries10.1108/eb041776 ↗
28. Properties of built-up films of barium stearate10.1021/j150385a007 ↗
29. The influence of silicone based water repellents as admixtures on the rheological properties of cement slurry
30. Effect of hydrophobization treatment on the hydration of repair Roman cement mortars10.1016/j.conbuildmat.2012.05.002 ↗
31. EN 12390-3:2009. Testing hardened concrete. Compressive strength of test specimens. European Committee for Standardization.
32. EN 12390-5:2009. Testing hardened concrete. Flexural strength of test specimens. European Committee for Standardization.
33. KSL ISO 679 .
34. KS L 5105 .
35. EN 7044:1972. Determination of consistency of cement mortars using a flow table. European Committee for Standardization.
36. EN 1015-6 2007-05; Methods of test for mortar for masonry – Part 6: Determination of bulk density of fresh mortar. European Committee for Standardization.
37. KSL 3136 .
38. KSL 5111 .
39. Contact angle measurements
40. Brodie BC. XIII. On the atomic weight of graphite. Philos Trans R Soc London. 1859;149:249–259. doi: 10.1098/rstl.1859.0013.10.1098/rstl.1859.0013 ↗
41. A critical review on research progress of graphene/cement based composites10.1016/j.compositesa.2017.07.019 ↗
42. Graphene-engineered cementitious composites: small makes a big impact10.1177/1847980417742304 ↗
43. Reinforcing effects of graphene oxide on portland cement paste10.1061/(ASCE)MT.1943-5533.0001125 ↗
44. Rheological behavior of fresh cement pastes with a graphene oxide additive10.1016/S1872-5805(16)60033-1 ↗
45. Effects of graphene oxide agglomerates on workability, hydration, microstructure and compressive strength of cement paste10.1016/j.conbuildmat.2017.04.058 ↗
46. Effect of graphene oxide on the rheological properties of cement pastes10.1016/j.conbuildmat.2015.07.181 ↗
47. Early-age interaction mechanism between the graphene oxide and cement hydrates10.1016/j.conbuildmat.2017.06.176 ↗
48. Adsorption characteristics of graphene oxide nanosheets on cement10.1039/C6RA10902K ↗
49. Enhancing ultra-early strength of sulphoaluminate cement-based materials by incorporating graphene oxide10.1515/ntrev-2020-0002 ↗
50. Nanocomposite of cement/graphene oxide – impact on hydration kinetics and Young’ s modulus10.1016/j.conbuildmat.2014.12.009 ↗
51. Admixtures effect on fresh state properties of aerial lime based mortars10.1016/j.conbuildmat.2008.06.008 ↗
52. Chloride ion penetration resistance andmicrostructural modification of concrete with the addition of calcium stearate10.1016/j.conbuildmat.2021.126188 ↗
53. The impact of calcium stearate on characteristics of concrete10.1007/s42107-019-00161-x ↗
54. Effect of calcium stearate and aluminum powder on free and restrained drying shrinkage, crack characteristic and mechanical properties of concrete10.1016/j.cemconcomp.2021.104276 ↗
55. Drying shrinkage of concrete containing calcium stearate,(Ca (C18H35O2) 2), with ordinary Portland cement (OPC) as a binder: experimental and modelling studies10.3390/molecules25214880 ↗
56. The impact of calcium stearate on characteristics of concrete10.1007/s42107-019-00161-x ↗
57. Fabrication of self-cleaning fly ash/ polytetrafluoroethylene material for cement mortar spray-coating10.1016/j.jclepro.2020.121748 ↗
58. Novel nano-precursor inhibiting material for improving chloride penetration resistance of concrete: evaluation and mechanism10.3390/ma14205929 ↗
59. Relationship between sorptivity and capillary coefficient for water absorption of cement-based materials: theory analysis and experiment10.1098/rsos.190112 ↗
60. Analysis of selected water absorption coefficient measurements10.1177/1097196305047003 ↗
61. Hydration products of C3A, C3S and Portland cement in the presence of CaCO310.1016/S0008-8846(00)00292-1 ↗
62. Influence of limestone on the hydration of Portland cements10.1016/j.cemconres.2008.01.002 ↗
63. The role of calcium carbonate in cement hydration10.1016/j.cemconres.2006.10.013 ↗
64. Utilization of precipitated CaCO3 from carbon sequestration of industrially emitted CO2 in cementless CaO-activated blastfurnace slag binder system10.1016/j.jclepro.2017.08.097 ↗
65. Insights into early hydration of Portland limestone cement from infrared spectroscopy and isothermal calorimetry10.1016/j.cemconres.2010.06.008 ↗
66. Investigation of the incompatibilities of cement and superplasticizers and their influence on the rheological behavior10.3390/ma13040977 ↗
67. Effect of sodium stearate and calcium ion on dispersion properties of precipitated calcium carbonate suspensions10.1016/j.colsurfa.2003.08.016 ↗
68. Evaluation of capillary water absorption in rendering mortars made with powdered waterproofing additives10.1016/j.conbuildmat.2009.05.002 ↗
69. Retardation of cement hydration caused by heavy metals present in ISF slag used as aggregate10.1016/j.cemconcomp.2008.07.005 ↗
70. A study of thermal decomposition of phases in cementitious systems using HT-XRD and TG10.1016/j.conbuildmat.2018.03.001 ↗
71. Influence of slag characteristics on strength development and reaction products in a CaO-activated slag system10.1016/j.cemconcomp.2016.06.005 ↗
72. Hydration of quaternary Portland cement blends containing blast-furnace slag, siliceous fly ash and limestone powder10.1016/j.cemconcomp.2014.10.001 ↗
73. Analysis of the system 3CaO_Al2O3–CaSO4_2H2O–CaCO3–H2O by FT-IR spectroscopy10.1016/S0008-8846(01)00502-6 ↗
74. Physico-chemical and mechanical characterization of hydraulic mortars containing nano-titania for restoration applications10.1016/j.cemconcomp.2012.07.002 ↗
75. Comparative investigation of the adhesion of Ce conversion layers and silane layers to a AA 2024–T3 substrate through mechanical and electrochemical tests10.1590/S1516-14392007000400013 ↗