journal article·2024-07Open access

Hydration behavior and cementitious properties of steel slag: From an early age to a long-term

Yu Zhang, Guohai Zhu, Yunsheng Zhang, Xu Wu, Fuqiang Zhang, Junlin Zhang, Xiaomin Li

Abstract

In China, steel slag as a solid waste caused land occupation and environmental pollution, and its utilization ratio is relatively low. To increase the utilization field and ratio of steel slag, hydration behavior and cementitious properties of three types of steel slag were investigated and compared based on test results from an early age to a long-term via multiple techniques. Experimental results suggested that steel slag showed a strong latent hydraulic activity at a later age, and the mechanical strength of steel slag paste specimens (w/b=0.3) could reach 15 MPa at 360 days. Cementitious properties of steel slag were primally depended on the hydration of calcium silicate (C3S and C2S), calcium aluminate (ferrite), glassy phase in steel slag, especially for calcium silicate. The sum amount of calcium silicate in used steel slag was approximately from 21% to 28%, and the amount of C2S was significantly greater than that of C3S. The hydration of C2S and glassy phase resulted in the continuous increase in bound water content of steel slag, and a certain content of C2S still existed in pastes at 360 days. The mechanical strength of steel slag pastes markedly increased at a later age due to more hydrates formed in the microstructure.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Magnesium Oxide Properties and Applications · Recycling and utilization of industrial and municipal waste in materials production

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References (41)

Show source-provided references
1. Overview of iron/steel slag application and development of new utilization technologies
2. A study of factors that influence the hydration activity of mono-component CaO and bi-component CaO/Ca2Fe2O5 systems10.1016/j.cemconres.2016.11.011 ↗
3. World Steel Association, Fact sheet on co-products, in: WorldsteelOrg 2, 2018.
4. Steel slag in China: treatment, recycling, and management10.1016/j.wasman.2018.04.045 ↗
5. Research on mineral characteristics of converter steel slag and its comprehensive utilization of internal and external recycle10.1016/j.jclepro.2017.04.029 ↗
6. Investigation on mechanical properties, durability and micro-structural development of steel slag blended cements10.1007/s10973-011-1853-6 ↗
7. Effect of wet-grinding steel slag on the properties of Portland cement: an activated method and rheology analysis10.1016/j.conbuildmat.2021.122823 ↗
8. Utilization of carbonated and granulated steel slag aggregate in concrete10.1016/j.conbuildmat.2015.03.008 ↗
9. Accelerated carbonation and performance of concrete made with steel slag as binding materials and aggregates10.1016/j.cemconcomp.2017.07.018 ↗
10. Cementitious properties of super-fine steel slag10.1016/j.powtec.2013.04.016 ↗
11. Hydration heat evolution and kinetics of blended cement containing steel slag at different temperatures10.1016/j.tca.2015.02.018 ↗
12. Hydration properties and microstructure characteristics of alkali-activated steel slag10.1016/j.conbuildmat.2020.118141 ↗
13. Structural characteristics and hydration kinetics of modified steel slag10.1016/j.cemconres.2010.11.018 ↗
14. Mechanical performance and microstructure of the calcium carbonate binders produced by carbonating steel slag paste under CO2 curing10.1016/j.cemconres.2016.05.013 ↗
15. Production of cleaner high-strength cementing material using steel slag under elevated temperature carbonation10.1016/j.jclepro.2022.130948 ↗
16. Preparation of high performance blended cements and reclamation of iron concentrate from basic oxygen furnace steel slag10.1016/j.resconrec.2011.09.003 ↗
17. Increase in volume stability of RO phases in steel slag by combined treatment of alkali and dry carbonation10.1016/j.conbuildmat.2023.132345 ↗
18. Improving the hydration activity and volume stability of the RO phases in steel slag by combining alkali and wet carbonation treatments10.1016/j.cemconres.2023.107236 ↗
19. Probe into carbonation mechanism of steel slag via FIB-TEM: the roles of various mineral phases10.1016/j.cemconres.2022.106991 ↗
20. The influence of steel slag on the hydration of cement during the hydration process of complex binder10.1007/s11431-010-4204-0 ↗
21. Inhibition mechanisms of steel slag on the early-age hydration of cement10.1016/j.cemconres.2020.106283 ↗
22. Integrated and innovative steel slag utilization for iron reclamation, green material production and CO2 fixation via accelerated carbonation10.1016/j.jclepro.2016.07.112 ↗
23. Effects of mineralogical changes in BOFS during carbonation on pH and Ca and Si leaching10.1016/j.conbuildmat.2018.10.057 ↗
24. Study on preparation of supplementary cementitious material using microbial CO2 fixation of steel slag powder10.1016/j.conbuildmat.2022.126864 ↗
25. Environmental benefit assessment of steel slag utilization and carbonation: a systematic review
26. Recent advances in the reuse of steel slags and future perspectives as binder and aggregate for alkali-activated materials10.1016/j.conbuildmat.2021.122605 ↗
27. The mechanical strength, microstructure, and transport properties of steel slag reinforced loess soil system
28. Hydration and soundness properties of phosphoric acid modified steel slag powder10.1016/j.conbuildmat.2020.119319 ↗
29. Surface etching and early age hydration mechanisms of steel slag powder with formic acid10.1016/j.conbuildmat.2021.122500 ↗
30. Morphological and mineralogical insights into acetic acid modifying and hydraulic process on steel slag for enhanced reactivity10.1016/j.conbuildmat.2021.125004 ↗
31. Rapid hardening β-C2S mineral and microstructure changes activated by accelerated carbonation curing10.1007/s10973-017-6165-z ↗
32. Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash10.1016/j.cemconres.2010.11.014 ↗
33. Hydration states of AFm cement phases10.1016/j.cemconres.2015.02.011 ↗
34. Effect of alkalis on fresh C–S–H gels. FTIR analysis10.1016/j.cemconres.2009.01.003 ↗
35. Incorporation of Al in C-A-S-H gels with various Ca/Si and Al/Si ratio: Microstructural and structural characteristics with DTA/TG, XRD, FTIR and TEM analysis10.1016/j.conbuildmat.2017.08.091 ↗
36. Effect of relative humidity on the carbonation rate of portlandite, calcium silicate hydrates and ettringite10.1016/j.cemconres.2020.106116 ↗
37. Scrivener · 2016
38. Development of a new rapid, relevant and reliable (R3) test method to evaluate the pozzolanic reactivity of calcined kaolinitic clays10.1016/j.cemconres.2016.02.015 ↗
39. The influence of chemical admixtures on the strength and hydration behavior of lime-based composite cementitious materials10.1016/j.cemconcomp.2019.05.008 ↗
40. Evolution of pore structure in blended systems10.1016/j.cemconres.2015.02.025 ↗
41. Changes in in microstructure characteristics of cement paste on carbonation10.1016/j.cemconres.2018.04.016 ↗