Investigation on the impact of different activator to solid ratio on properties and micro-structure of metakaolin geopolymer
Source abstract
Abstract
The aim of this paper is to investigate the effects of different activator -to-solid ratios on water consumption, setting time, fluidity, adhesion properties, bulk density and mechanical properties at standard consistency. The microstructural mechanisms of metakaolin geopolymer were also investigated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). The experimental results showed that for the different activator to solid ratios and mix designs used in this paper, higher ratios enhanced the fluidity, consistency, and setting time. Besides, the standard consistency water consumption of the metakaolin polymer mortar was reduced. SEM and FT-IR tests revealed macroscopic phenomena where the polyaluminum silicate structure improved with increasing activator -to-solids ratios. Excessive sodium silicate reduced strength, thus affecting mechanical properties.
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Research context
OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Magnesium Oxide Properties and Applications
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References (36)
Show source-provided references
1. Preparation and application of alkali-activated materials based on waste glass and coal gangue: a review
2. Sustainable concrete: impacts of existing and emerging materials and technologies on the construction industry10.1061/41168(399)31 ↗
3. A.P. Wilson, Establishing a Mix Design Procedure for Geopolymer Concrete.University of Southern Queensland(2015).
4. Toward green concrete for better sustainable environment10.1016/j.proeng.2014.12.190 ↗
5. Onepart alkali-activated materials: a review10.1016/j.cemconres.2017.10.001 ↗
6. The influence of Si/Al ratio on sulfate durability of metakaolin-based geopolymer10.1016/j.conbuildmat.2020.120735 ↗
7. J. Davidovits, Geopolymers: inorganic polymeric new materials, J. Therm. Anal.1991,37 (8) 1633–1656.DOI:10.1007/BF01912193.10.1007/BF01912193 ↗
8. J Davidorits,Proceeoding First International Conference on Alkaline Cements and Concents, 1994, 131.
9. Alkaline activation of metakaolinite-silica mixtures: role of dissolved silica concentration on the formation of geopolymers10.1016/j.ceramint.2017.06.144 ↗
10. The action of alkalis on blast-furnace slag
11. Influence of the Si/Al ratio in geopolymers on the stability against acidic attack and the immobilization of Pb 2+ and Zn2+
12. Mechanism of geopolymerization and factors influencing its development: a review10.1007/s10853-006-0401-4 ↗
13. Chemically-bonded cementitious materials based on metakaolin
14. Shi · A review on alkali-aggregate reactions in alkali-activated mortars/concretes made with alkali-reactive aggregates,Mater. Struct · 2015 · 48 · 621
15. Technical and commercial progress in the adoption of geopolymer cement10.1016/j.mineng.2011.09.009 ↗
16. Evaluation of the bonding and fatigue properties of an innovative rapid repair structure for concrete pavement10.1016/j.conbuildmat.2019.117484 ↗
17. Davidovits · Geopolymeric Concretes for Environmental Protection.Concrete Int · 1990 · 12 · 30
18. J. Labrincha, F. Pacheco-Torgal, A. Palomo, P. Chindaprasit, C. Leonelli,Handbook of Alkali-Activated Cements, Mortars and Concretes, Woodhead Publishing, 2014.10.1533/9781782422884.1 ↗
19. Disu, A.A., Kolay, P.K. A Critical Appraisal of Soil Stabilization Using Geopolymers: The Past, Present and Future. Int. J. of Geosynth. and Ground Eng 7.2021,23.https://doi.org/10.1007/s40891–021-00267-w.10.1007/s40891-021-00267-w ↗
20. Effect of elevated temperatures on geopolymer paste, mortar and concrete10.1016/j.cemconres.2009.10.017 ↗
21. Resistance of geopolymer and Portland cement based systems to silage effluent attack10.1016/j.cemconres.2016.11.015 ↗
22. H.-S. Kim, S.-H. Lee, H.-Y. Moon, Strength properties and durability aspects of high strength concrete using Korean metakaolin, Constr. Build. Mater. 2007,21(6):1229–1237.https://doi.org/10.1016/j.conbuildmat.2006.05.007.10.1016/j.conbuildmat.2006.05.007 ↗
23. Synthesis of fly ash/metakaolin geopolymer for concrete retrofitting application10.1002/suco.201700286 ↗
24. Durability evaluation of geopolymer and conventional concretes10.1016/j.conbuildmat.2017.01.056 ↗
25. Geopolymers and geopolymeric materials10.1007/BF01904446 ↗
26. Effect of synthesis parameters on the mechanical properties of fly ash-based geopolymers10.1016/j.colsurfa.2006.12.064 ↗
27. Study on setting time of fly ash-based geopolymer
28. Effect of silane coupling agent on the rheological and mechanical properties of alkali-activated ultrafine metakaolin based geopolymers
29. J. Davidovits, Geopolymer chemistry and properties. 1st European Conference on Soft Mineralurgy, Compiegne, France. 1, 25–48 (1998).
30. J. Recent progresses in concretes for nuclear waste and uranium waste containment
31. Fire-resistant aluminosilicate composites10.1002/(SICI)1099-1018(199703)21:2<67::AID-FAM596>3.0.CO;2-N ↗
32. Geopolymer cement to minimize carbon-dioxde greenhouse-warming
33. The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers10.1016/j.colsurfa.2006.05.044 ↗
34. Chen Shikun. Study on the mechanical properties and influencing factors of geopolymer of metakaolin. Zhejiang University,2015.
35. Reaction mechanisms of calcined kaolin processing waste-based geopolymers in the presence of low alkali activator solution10.1016/j.conbuildmat.2019.06.116 ↗
36. Zhu Huajun, Yao Xiao, Zhang Zuhua.Optimization of calcined temperature for kaolin activation.Journal of Building Materials,2008(05):621–625.(in Chinese)https://kns.cnki.net/kcms/detail/detail.aspx?dbcode=CJFD&dbname=CJFD2008&filename=JZCX200805024&uniplatform=NZKPT&v=IZ_LuBqr2bc7Q2x-KVpGIzANB6SGjqqrSG9Sy-jnxfQ8ATeQweqJaadEWk1iIQtY.