Innovative synthesis of low-carbon cemented backfill materials through synergistic activation of solid wastes: An integrated assessment of economic and environmental impacts

The accumulation of large amounts of steel slag (SS) and oil shale residue (OSR) causes serious pollution due to the lack of effective ways to utilize them. In this study, OSR, SS, and soda residue (SR) were used to synergistically prepare all-solid-waste low-carbon cemented backfill material (ALCCB). No cement and chemical additives were added to this material, and synergistic activation enabled full utilization of the solid wastes. The total solid waste utilization rate was 100%. The mechanical characteristics of the ALCCB and the heavy metal leaching rates were determined. The unconfined compression strength of the ALCCB after 28 days was 5.97 MPa, while the slump was 205 mm. These results met the performance requirements for a filling material. The leaching rates for the heavy metals after 28 days conformed to the guidelines for Class III groundwater quality. The mechanism underlying synergistic hydration of the solid wastes was analyzed at the micro- and macroscale with X-ray diffraction (XRD), thermogravimetric analysis (TG), scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP). The results indicated that hydration of the ALCCB occurred continuously during curing, and the faster early hydration reaction stabilized heavy metal curing at 7 d. In addition, ALCCB offers greater economic and environmental advantages than cementitious materials. Notably, the economic and environmental benefits of ALCCB were found to supersede those of cement-based materials, with a cost reduction of 42.6% and a CO2 emission reduction of 86.9%. This innovative low-carbon mine backfill material effectively promotes the utilization of solid waste resources and supports sustainable development.