Mechanics, hydration phase and pore development of embodied energy and carbon composites based on ultrahigh-volume low-carbon cement with limestone calcined clay

Engineered cement-based composites exhibit excellent deformability, mechanical behavior, fresh performance and durability. However, the traditional cement-based composites incorporating high volume ordinary Portland cement would lead to high carbon footprint. In this study, a new and eco-efficient engineered cement-based composites was designed by incorporating Polypropylene fibers (PPF) and eco-friendly cement with limestone calcined clay (LC3-ECCs). The LC3-ECCs were analyzed and discussed in terms of mechanical properties, microscopic morphology, hydration products and porosity. The study found that the 28-days compressive behavior was above 44.2 MPa, and the flexural strength remained above 4.8 MPa. Because of the formation and gathering of highly polymerized compound products (C-S-H gel, C-A-S-H gel) in the matrix and plenty of ettringite, the bonding effect between PPF and LC3 cementitious matrix is better. Additionally, the LC3-ECCs with 1.5 % volume content of PP fiber showed less porosity beneficial to the mechanical behavior. This study suggests that low-carbon LC3 has the potential to be successfully utilized as the alternative to OPC and is suitable to design sustainable ECCs, and this low-carbon construction product can be also generally applied into some area with the abundant clay sources.