journal article·2025-07Open access

Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review

Ye Tian, Yu Liu, Yu-Meng Xie, Guo-Yi Zhang, Hai-Long Ye, Dong-Ming Yan, Yun-Jian Li, Bei Li, Hong-Jing Xue, Qing Cai

Abstract

Steel reinforcement corrosion is the main reason for the decrease in the durability of concrete structures, and concrete structures serving in the coupled environment of chloride and sulfate are prone to steel reinforcement corrosion. Therefore, it is necessary to explore the coupled effect of chloride and sulfate on concrete degradation and steel corrosion . This paper provides a comprehensive review of the corrosion of steel reinforcement in concrete structures exposed to coupled invasion of chlorides and sulfates. The natural exposure stations and tests of concrete under chloride and sulfate attack around the world are discussed. The complex interactions and coupled transport models involved in the erosion process of chloride and sulfate ions are explained. From the perspectives of the direct effect of chloride ions on steel corrosion and the influence of sulfate ions on chloride-induced steel corrosion, the mechanism of steel corrosion in a coupled environment of chlorides and sulfates is represented. The paper also summarizes relevant experimental research and numerical simulation research. It emphasizes the importance of further research to clarify the direct mechanism of sulfate ions on the passive film on the steel surface and their reactions in the electrochemical corrosion process. Comprehensive consideration and accurate simulation of the factors influencing steel corrosion are crucial for advancing the prediction of the durability of reinforced concrete structures .
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Research context

OpenAlex topics: Concrete Corrosion and Durability · Corrosion Behavior and Inhibition · Concrete and Cement Materials Research

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References (100+)

Show source-provided references
1. Etman E. Assessment of the behavior of strengthened concrete structural elements[C]//The First International Conference on Civil Engineering. Cairo, Egypt, 1998.
2. Durability of concrete-fifty years of progress
3. Analytical assessment of the bearing capacity of RC beams with corroded steel bars beyond concrete cover cracking10.1016/j.compositesb.2017.03.036 ↗
4. Crack patterns of concrete with a single rebar subjected to non-uniform and localized corrosion10.1016/j.conbuildmat.2016.04.149 ↗
5. Qingdao university of technology
6. Durability of reinforced concrete bridges in marine environments[J]10.1080/15732479.2019.1604769 ↗
7. London
8. Performance of 45-year-old corroded prestressed concrete beams10.1680/stbu.11.00016 ↗
9. Corrosion of carbon steel and corrosion-resistant rebars in concrete structures under chloride ion attack10.1007/s11665-012-0314-0 ↗
10. Composition and origin of the sabkha brines, and their environmental impact on infrastructure in Jizan area, Red Sea Coast, Saudi Arabia[J]10.1007/s12665-015-4913-6 ↗
11. Experimental study on magnesium oxychloride cement concrete[J]
12. Seismic deformation of reinforced concrete piers corroded by saline soil[J]10.1007/s10518-022-01433-9 ↗
13. Correction: The global technical and economic potential of bioenergy from salt-affected soils10.1039/D0EE90035D ↗
14. Progress of the mechanism of sulfate attack on cement-based materials
15. Critical conditions and life prediction of reinforcement corrosion in coral aggregate concrete10.1016/j.conbuildmat.2019.117685 ↗
16. Experimental study on the durability of FRP bars reinforced concrete beams in simulated ocean environment10.1515/secm-2017-0237 ↗
17. Corrosion behavior of low alloy steel bars containing Cr and Al in coral concrete for ocean construction10.1016/j.conbuildmat.2020.119564 ↗
18. Study on concrete deterioration in different NaCl-Na2SO4 solutions and the mechanism of Cl− Diffusion10.3390/ma14175054 ↗
19. Assessment of the durability of concrete from its permeation properties: a review10.1016/S0950-0618(00)00058-1 ↗
20. A review on the deterioration and approaches to enhance the durability of concrete in the marine environment10.1016/j.cemconcomp.2020.103695 ↗
21. Resistance of concretes to external chlorides in the presence and absence of sulphates: a review10.3390/app13010182 ↗
22. Summary of field exposure test of marine concrete structures
23. Attack on plain and blended cements exposed to aggressive sulfate environments10.1016/S0958-9465(01)00082-8 ↗
24. Field evaluation of corrosion mitigation on reinforced concrete in marine exposure conditions10.1016/j.conbuildmat.2018.01.077 ↗
25. Monitoring the corrosion of steel in concrete exposed to a marine environment10.3390/ma13020407 ↗
26. Use of polymer-impregnated concrete permanent form in marine environment: 10-year outdoor exposure in Saudi Arabia10.1016/j.conbuildmat.2013.01.028 ↗
27. Damage evaluation of concrete under field exposure in Xi’an10.3724/SP.J.1249.2015.04378 ↗
28. Mechanism analysis of strength evolution of concrete structure in saline soil area based on 15-year service10.1016/j.conbuildmat.2022.127281 ↗
29. Birnbaum-saunders durability life prediction model of site-exposed concrete in the saline soil area
30. Long-term chloride diffusion in silica fume concrete in harsh marine climates10.1016/j.cemconcomp.2009.08.005 ↗
31. 4-year monitoring of degradation mechanisms of seawater sea-sand concrete exposed to tidal conditions: development of chemical composition and micro-performance10.1016/j.conbuildmat.2023.133475 ↗
32. Utilization of fly ash concrete in marine environment for long term design life analysis10.1016/j.matdes.2009.09.024 ↗
33. Rasheeduzzafar · 1985
34. Deterioration of concrete structures in the environment of the Middle East
35. Climatic zones—A prelude to designing durable concrete structures in the Arabian Gulf10.1016/j.buildenv.2006.04.006 ↗
36. Durability of silica fume concrete exposed to chloride in hot climates10.1061/(ASCE)0899-1561(2001)13:1(41) ↗
37. The effect of Persian Gulf tidal zone exposure on durability of mixes containing silica fume and blast furnace slag10.1016/j.conbuildmat.2008.02.009 ↗
38. Wei · 2017
39. Hydrochemical characteristics and evolution of groundwater in the dried-up river oasis of the Tarim Basin, Central Asia10.1007/s40333-021-0086-1 ↗
40. Secondary salinization of subgrade of southern Xinjiang Railway
41. Study of durability of concrete structures and its influencing factors in south region of Xinjiang
42. A new evaluation method for groundwater quality applied in Guangzhou Region, China: using fuzzy method combining toxicity index10.2175/106143015X14362865227832 ↗
43. Huang · 2012
44. Strength and microstructure analysis of concrete containing rice husk ash under seawater attack by wetting and drying cycles10.1680/adcr.13.00010 ↗
45. Case study of performance of a jetty structure after 25 years of exposure in a marine environment considering earthquake load10.1016/j.engfailanal.2023.107831 ↗
46. Research development of the corrosion of reinforced concrete in saline soil environment
47. Jin · 2006
48. Liu · 2017
49. Research progress of concrete durability in saline soil environment
50. Electrokinetic potential of hydrated cement in relation to adsorption of chlorides10.1016/j.cemconres.2009.01.006 ↗
51. Effects of cathodic prevention on the chloride threshold for steel corrosion in concrete10.1016/j.electacta.2008.09.033 ↗
52. Electrochemical behaviour of steel in plain and blended cement concretes in sulphate and/or chloride environments10.1016/0950-0618(95)00002-W ↗
53. Zhang · 2023
54. The stability of bound chlorides in cement paste with sulfate attack10.1016/j.cemconres.2014.11.010 ↗
55. Influence of bicarbonate ions on the deterioration of mortar bars in sulfate solutions10.1016/j.cemconres.2012.10.016 ↗
56. Numerical simulation on diffusion–reaction behavior of concrete under sulfate–chloride coupled attack
57. Research on the influence of sulfate upon chloride diffusing into concrete of underground structures
58. Underground concrete structure exposure to sulfate and chloride invading environment
59. The impact of sulphate and magnesium on chloride binding in Portland cement paste10.1016/j.cemconres.2014.07.007 ↗
60. Seawater effect on durability of ternary cements. Synergy of chloride and sulphate ions10.1016/j.compositesb.2012.09.089 ↗
61. Damage of concrete in sulfate and chloride solution
62. Effect of sulfate concentration on chloride diffusion of concrete under cyclic load10.3390/ma15062036 ↗
63. Study on concrete deterioration and chloride ion diffusion mechanism by different aqueous NaCl-MgSO4 concentrations10.3390/buildings12111843 ↗
64. Chloride diffusion property of hybrid basalt–polypropylene fibre-reinforced concrete in a chloride–sulphate composite environment under drying–wetting cycles10.3390/ma14051138 ↗
65. The effect of chlorides on the thaumasite form of sulfate attack in limestone cement concrete10.4028/www.scientific.net/MSF.636-637.1349 ↗
66. Strength assessment of cement-based materials under marine conditions subjected to sulfate and chloride attack based on ion distributions10.3390/jmse11061210 ↗
67. Effect of GGBS on performance deterioration of non-dispersible underwater concrete in saline soil
68. Compressive strength, pore structure, and hydration products of slag foam concrete under sulfate and chloride environment10.1016/j.conbuildmat.2023.132141 ↗
69. Structural and material performance of geopolymer concrete: a review10.1016/j.conbuildmat.2018.07.111 ↗
70. Sustainable pavement construction: A systematic literature review of environmental and economic analysis of recycled materials10.1016/j.jclepro.2021.127936 ↗
71. Mechanical performance of low-carbon ultra-high performance engineered cementitious composites (UHP-ECC) with high-volume recycled concrete powder
72. Elucidating the role of recycled concrete aggregate in ductile engineered geopolymer composites: Effects of recycled concrete aggregate content and size
73. Micro-properties and mechanical behavior of high-ductility engineered geopolymer composites (EGC) with recycled concrete and paste powder as green precursor10.1016/j.cemconcomp.2024.105672 ↗
74. Understanding the chloride migration in recycled powder concrete: effects of recycled powder type, replacement rate and substitution pattern10.1016/j.conbuildmat.2024.136825 ↗
75. Optimization and characterization of cementitious composites combining maximum amounts of waste glass powder and treated glass aggregates10.1186/s40069-024-00669-w ↗
76. Experimental investigation on concrete partially replaced with waste glass powder and waste E-plastic10.1016/j.conbuildmat.2021.122400 ↗
77. Durability performance of waste granite and glass powder added concrete10.1016/j.conbuildmat.2020.119075 ↗
78. Chloride transport resistance of alkali-activated concrete exposed to combined chloride, sulfate and carbonation environment10.1016/j.conbuildmat.2023.130353 ↗
79. Effects of electric arc furnace slag powder and fly ash within ternary waste blend on performance of concrete
80. Penetration of chloride ions into cement pastes and concretes10.1111/j.1151-2916.1972.tb13424.x ↗
81. Equivalent relationship of accelerated corrosion based on the chloride ion diffusion property in calcium sulfoaluminate cement-based pastes10.1016/j.icheatmasstransfer.2024.107283 ↗
82. Degradation of concrete in marine environment under coupled chloride and sulfate attack: A numerical and experimental study
83. Numerical simulation of cementitious materials degradation under external sulfate attack10.1016/j.cemconcomp.2009.12.005 ↗
84. Wang · 2016
85. A chemo-transport-damage model for concrete under external sulfate attack10.1016/j.cemconres.2020.106048 ↗
86. Experimental and numerical study of the effects of solution concentration and temperature on concrete under external sulfate attack
87. Effect of interfacial transition zone on the transport of sulfate ions in concrete10.1016/j.conbuildmat.2018.10.140 ↗
88. The effect of rough vs. smooth aggregate surfaces on the characteristics of the interfacial transition zone
89. Coupled models to describe the combined diffusion-reaction behaviour of chloride and sulphate ions in cement-based systems10.1016/j.conbuildmat.2020.118232 ↗
90. Coupled transport of sulfate and chloride ions with adsorption effect: a numerical analysis10.3389/fmats.2020.536517 ↗
91. Thermodynamic modelling and experimental investigation on chloride binding in cement exposed to chloride and chloride-sulfate solution10.1016/j.conbuildmat.2020.118398 ↗
92. A numerical model including thermodynamic equilibrium, kinetic control and surface complexation in order to explain cation type effect on chloride binding capability of concrete10.1016/j.conbuildmat.2018.10.058 ↗
93. Ion-cement hydrate interactions govern multi-ionic transport model for cementitious materials10.1016/j.cemconres.2010.08.019 ↗
94. Zeta-potential study of calcium silicate hydrates interacting with alkaline cations10.1006/jcis.2001.7897 ↗
95. C-S-H/solution interface: experimental and Monte Carlo studies10.1016/j.cemconres.2010.10.002 ↗
96. A chemo-damage-transport model for chloride ions diffusion in cement-based materials: combined effects of sulfate attack and temperature[J]10.1016/j.conbuildmat.2021.123121 ↗
97. Numerical modelling of degradation of cement-based materials under leaching and external sulfate attack10.1016/j.compstruc.2015.05.030 ↗
98. Numerical modeling of chloride diffusion in cement-based materials considering calcium leaching and external sulfate attack10.1016/j.conbuildmat.2023.132913 ↗
99. A chemo-thermo-damage-transport model for concrete subjected to combined chloride-sulfate attack considering the effect of calcium leaching10.1016/j.conbuildmat.2021.124918 ↗
100. Modeling of calcium leaching from cement hydrates coupled with micro-pore formation10.3151/jact.4.395 ↗