Sustainable construction materials: Application of chitosan biopolymer, rice husk biochar, and hemp fibers in geo-structures

Eco-friendly materials have gained significant attention for soil stabilization and reinforcement in road construction and geo-environmental infrastructure, as traditional additives pose notable environmental concerns. In this study, three concentrations of Chitosan Biopolymer (CBP) (1.5 %, 3 %, and 4.5 %) as a bio-stabilizer, three proportions of Rice Husk Biochar (RHB) (0.5 %, 1 %, and 1.5 %) as a waste-derived filler, and three dosages of Hemp Fiber (HF) (0.2 %, 0.4 %, and 0.6 %) as reinforcement were used to treat sand-kaolinite mixtures (SKM). The samples were cured for 1, 7, 14, 21, and 28 days and subjected to varying numbers of freeze-thaw (F-T) cycles. A diverse range macro-scale laboratory tests, encompassing compaction, unconfined compressive strength (UCS), indirect tensile strength (ITS), F-T durability, ultrasonic pulse velocity (UPV), and thermal conductivity (TC), were performed on the treated samples. In addition, microstructural analyses using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier-transform infrared spectroscopy (FTIR) were conducted to correlate mechanical behavior with micro-scale properties. The optimal dosages of CBP and RHB were first determined through UCS tests, with 3 % CBP and 1 % RHB proving the most effective. These dosages were then used to analyze their impact on other mechanical properties. Results showed that the compressive and tensile strengths of the bio-stabilized soil at the optimum contents of additives increased by 2410.7 kPa and 201.2 %, respectively, compared to the control samples. Incorporating HF into the SKM-CBP-RHB mixtures significantly enhanced their F-T durability after 10 consecutive cycles, reducing strength deterioration and performance degradation compared to the untreated soil. The optimum composition (3 % CBP, 1 % RHB, and 0.4 % HF) led to a 6.1-fold increase in ITS and a minor 2 % reduction in performance after 10 F-T cycles. Moreover, HF incorporation improved the failure strain and reduced the brittleness of the stabilized soil. UPV and TC tests revealed that incorporating HF at levels up to 0.4 %, combined with the optimum CBP-RHB mixture, enhanced soil stiffness by 963.7 MPa and reduced thermal conductivity by 0.76 W·m⁻¹·K⁻¹. The microstructural analysis confirmed these findings, showing enhanced interlocking between SKM and fibers via hydrogel formation. Overall, the study demonstrates that the CBP-RHB-HF composite markedly enhances soil strength and durability, making these additives highly suitable for applications like landfills, embankments, and slopes.