journal article·2023-07Open access

A state of the art on effect of alkali activator, precursor, and fibers on properties of geopolymer composites

M. Jegan, R. Annadurai, P.R. Kannan Rajkumar

Abstract

Engineered geopolymer composites (EGC) are a new type of high-performance fiber-reinforced geopolymer composites with improved tensile, flexural, and strain hardening properties. This review article aims to provide an all-encompassing overview on the effect of various factors such as the addition of alkali activators, their chemistry, reaction mechanism, precursors, admixtures, and fibers in hybrid combination on the engineering properties of EGC. Among these, the alkali activator solution plays a crucial role in the geopolymer formulation and its binding capacity. From the review articles, it was found that EGC have higher strain-hardening capacities of about 4–7 % and improved mechanical properties due to enhanced geopolymerization and strong interfacial bond between the fibers and the matrix. The research gap in EGC pertaining to use of low and high-modulus fibers in hybrid combinations, durability, carbonation, and corrosion studies should form the focus of future research.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Recycled Aggregate Concrete Performance

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References (93)

Show source-provided references
1. Durability and mechanical properties of seashell partially-replaced cement
2. A taguchi approach for optimizing design mixture of geopolymer concrete incorporating fly ash, ground granulated blast furnace slag and silica fume10.3390/cryst11111279 ↗
3. Synthesis of new high temperature geo-polymers for reinforced plastics/composites
4. Effect of activator concentration on the strength, ITZ and drying shrinkage of fly ash/slag geopolymer concrete10.1016/j.conbuildmat.2016.05.008 ↗
5. The mechanical properties of fly ash-based geopolymer concrete with alkaline activators10.1016/j.conbuildmat.2013.05.069 ↗
6. Microstructure development of alkali-activated fly ash cement: a descriptive model10.1016/j.cemconres.2004.08.021 ↗
7. M. Jamshidi Avanaki, Physical & mechanical properties of fiber reinforced metakaolin-based geopolymer concrete10.1016/j.conbuildmat.2020.118965 ↗
8. A review: the comparison between alkali-activated slag (Si+ Ca) and metakaolin (Si+ Al) cements10.1016/j.cemconres.2010.03.020 ↗
9. Reaction kinetics, gel character and strength of ambient temperature cured alkali activated slag–fly ash blends10.1016/j.conbuildmat.2015.01.065 ↗
10. Physicochemical properties of binder gel in alkali-activated fly ash/slag exposed to high temperatures10.1016/j.cemconres.2016.08.004 ↗
11. The effects of ground granulated blast-furnace slag blending with fly ash and activator content on the workability and strength properties of geopolymer concrete cured at ambient temperature10.1016/j.matdes.2014.05.001 ↗
12. Investigations on the properties of geopolymer mortar and concrete with mineral admixtures: a review10.1016/j.conbuildmat.2019.08.025 ↗
13. The role of inorganic polymer technology in the development of “green concrete”10.1016/j.cemconres.2007.08.018 ↗
14. A state-of-the-art on development of geopolymer concrete and its field applications
15. Engineered cementitious composites (Ecc) – tailored composites through micromechanical modeling
16. On engineered cementitious composites (ECC)10.3151/jact.1.215 ↗
17. Study on impact of fiber hybridization in material properties of engineered cementitious composites, Estudo sobre o impacto da hibridização de fibras em propriedades materiais de compósitos cemenciosos engenhados
18. Engineering properties of strain hardening geopolymer composites with hybrid polyvinyl alcohol and recycled steel fibres10.1016/j.conbuildmat.2020.120585 ↗
19. M. Ohno, Green and Durable Geopolymer Composites for Sustainable Civil Infrastructure, (2017).
20. Basic performances and potential research problems of strain hardening geopolymer composites: a critical review10.1016/j.conbuildmat.2021.123030 ↗
21. Experimental study on static and dynamic properties of fly ash-slag based strain hardening geopolymer composites10.1016/j.cemconcomp.2022.104481 ↗
22. High-early-strength engineered cementitious composites for fast, durable concrete repair-material properties
23. Centrifugally sprayed engineered cementitious composites: rheology, mechanics, and structural retrofit for concrete pipes10.1016/j.cemconcomp.2022.104473 ↗
24. M.D. Lepech, G.A. Keoleian, V.C. Li, S. Qian, Design of Green Engineered Cementitious Composites for Pavement Overlay Applications, (2008).10.1201/9780203885307.ch130 ↗
25. S. Qian, V.C. Li, Ductile Concrete--Engineered Cementitious Composites (ECC) for Durable Bridge Deck Repair and Rehabilitation, 2011.10.3151/jact.9.339 ↗
26. S.H. Bong, B. Nematollahi, V. Mechtcherine, V.C. Li, K.H. Khayat, 3D Printed Engineered, Strain-Hardening Geopolymer Composite (EGC/SHGC) as Permanent Formwork for Concrete Beam Construction, (2022). doi:10.20944/preprints202203.0390.v1.10.20944/preprints202203.0390.v1 ↗
27. Molarity activity effect on mechanical and microstructure properties of geopolymer concrete: a review
28. B. Nematollahi, J. Sanjayan, Ambient temperature cured one-part engineered geopolymer composite: a sustainable alternative to engineered cementitious composite, in: Proceedings of the Ninth Rilem Int. Symp. Fiber Reinf. Concr., 2016.
29. Matrix design of strain hardening fiber reinforced engineered geopolymer composite10.1016/j.compositesb.2015.11.039 ↗
30. Physical and mechanical properties of new lightweight ambient-cured EPS geopolymer composites10.1061/(ASCE)MT.1943-5533.0003705 ↗
31. The effects of Na2O/SiO2 molar ratio, curing temperature and age on compressive strength, morphology and microstructure of alkali-activated fly ash-based geopolymers10.1016/j.cemconcomp.2011.03.006 ↗
32. Effects of alkali solutions on corrosion durability of geopolymer concrete10.12989/acc.2014.2.2.109 ↗
33. Rice husk ash and fly ash geopolymer hollow block based on NaOH activated
34. Comparison of bacteria-based self-healing methods in metakaolin geopolymer mortars
35. Tensile strain hardening behavior of PVA fiber-reinforced engineered geopolymer composite10.1061/(ASCE)MT.1943-5533.0001242 ↗
36. Modification of phase evolution in alkali-activated blast furnace slag by the incorporation of fly ash10.1016/j.cemconcomp.2013.09.006 ↗
37. Strength and microstructure of class-C fly ash and GGBS blend geopolymer activated in NaOH & NaOH + Na2SiO3
38. On the mechanical performance of K- and Na-based strain-hardening geopolymer composites (SHGC) reinforced with PVA fibers10.1016/j.conbuildmat.2020.118558 ↗
39. Strain-hardening and high-ductile behavior of alkali-activated slag-based composites with added zirconia silica fume10.3390/ma12213523 ↗
40. Silica fume as precursor in the development of sustainable and high-performance MK-based alkali-activated materials reinforced with short PVA fibers10.3389/fmats.2019.00077 ↗
41. Effect of adding methylcellulose on mechanical and vibration properties of geopolymer paste and hybrid fiber-reinforced geopolymer composite10.1061/(ASCE)MT.1943-5533.0003236 ↗
42. Influence of steel slag on the properties of alkali-activated fly ash and blast-furnace slag based fiber reinforced composites10.1016/j.cemconcomp.2020.103875 ↗
43. Properties of polyvinyl alcohol fiber reinforced fly ash based Engineered Geopolymer Composites with zeolite replacement10.1016/j.conbuildmat.2019.117161 ↗
44. Effect of Nanosilica on mechanical properties and microstructure of PVA Fiber-Reinforced Geopolymer Composite (PVA-FRGC)10.3390/ma12213624 ↗
45. Fresh and hardened properties of engineered geopolymer composite with MgO
46. Efficiency of different superplasticizers and retarders on properties of “one-part” fly ash-slag blended geopolymers with different activators10.3390/ma12203410 ↗
47. Effect of superplasticizers on properties of one-part Ca(OH)2/Na2SO4 activated geopolymer pastes10.1016/j.conbuildmat.2019.117990 ↗
48. The effectiveness of different superplasticizers in ambient cured one-part alkali activated pastes10.1016/j.cemconcomp.2018.12.027 ↗
49. Sugarcane bagasse ash-based engineered geopolymer mortar incorporating propylene fibers
50. Comparative study on the effect of fiber type and content on the performance of one-part alkali-activated mortar10.1016/j.conbuildmat.2020.118221 ↗
51. V.C. Li, Engineered cementitious composite (ecc): Material, structural, and durability performance, Concr. Constr. Eng. Handbook, second ed., (2008) 1001–1048.
52. Influence of type and dosage of micro-fibres on the physical properties of fibre reinforced mortar matrixes10.1016/j.conbuildmat.2018.08.058 ↗
53. Effect of synthetic fibers on the properties of geopolymers based on non-heat treated phosphate mine tailing10.1016/j.matchemphys.2020.124147 ↗
54. Mechanical properties of basalt fiber reinforced fly ash-based geopolymer composites
55. Impact of flax and basalt fibre reinforcement on selected properties of geopolymer composites10.3390/su12010118 ↗
56. A. Bhutta, P.H.R. Borges, N. Banthia, Mechanical properties of mk-based geopolymer composites reinforced with pva and pet fibers, in: Proceedings of the Ninth RILEM Symp. Fibre Reinf. Concr., 2016.
57. Investigation on Mode I Fracture Behavior of Hybrid Fiber-Reinforced Geopolymer Composites10.1007/s13369-019-04074-4 ↗
58. Properties of polypropylene fiber reinforced cellular lightweight high calcium fly ash geopolymer mortar
59. Mechanical properties of cotton fabric reinforced geopolymer composites at 200–1000 °C10.1007/s40145-014-0109-x ↗
60. Deflection hardening behavior and elastic modulus of one-part hybrid fiber-reinforced geopolymer composites10.18702/acf.2019.12.5.2.37 ↗
61. SiC fiber reinforced geopolymer composites, part 1: short SiC fiber10.1016/j.ceramint.2015.12.067 ↗
62. Flexural behavior of geopolymer composites reinforced with steel and polypropylene macro fibers10.1016/j.cemconcomp.2016.11.014 ↗
63. The effect of alkali activation solutions with different water glass/NaOH solution ratios on geopolymer composite materials10.1088/1757-899X/660/1/012003 ↗
64. Tensile and flexural behaviour of recycled polyethylene terephthalate (PET) fibre reinforced geopolymer composites10.1016/j.conbuildmat.2020.118438 ↗
65. Performance characteristics of micro fiber-reinforced geopolymer mortars for repair10.1016/j.conbuildmat.2019.04.210 ↗
66. Effect of slag on the mechanical properties and bond strength of fly ash-based engineered geopolymer composites10.1016/j.compositesb.2019.01.092 ↗
67. Comparative strain and deflection hardening behaviour of polyethylene fibre reinforced ambient air and heat cured geopolymer composites10.1016/j.conbuildmat.2017.12.175 ↗
68. Strain-hardening ambient-cured eco-friendly ductile geopolymer composites
69. Impact of added water and superplasticizer on early compressive strength of selected mixtures of palm oil fuel ash-based engineered geopolymer composites10.1016/j.conbuildmat.2016.01.033 ↗
70. Mechanical and fiber-bridging behavior of slag-based composite with high tensile ductility
71. Ultra-high-ductile behavior of a polyethylene fiber-reinforced alkali-activated slag-based composite10.1016/j.cemconcomp.2016.04.002 ↗
72. Tensile behavior of strain-hardening geopolymer composites (SHGC) under impact loading10.1016/j.cemconcomp.2020.103703 ↗
73. Thermal and mechanical properties of sustainable lightweight strain hardening geopolymer composites10.1016/j.acme.2016.08.002 ↗
74. Development and characterization of fly ash based PVA fiber reinforced engineered geopolymer composites incorporating metakaolin
75. Composite properties of high-strength polyethylene fiber-reinforced cement and cementless composites10.1016/j.compstruct.2015.11.046 ↗
76. Tensile performance of eco-friendly ductile geopolymer composites (EDGC) incorporating different micro-fibers10.1016/j.cemconcomp.2019.05.004 ↗
77. Self-healing of engineered geopolymer composites prepared by fly ash and metakaolin
78. Strain hardening fiber reinforced alkali-activated mortar - a feasibility study10.1016/j.conbuildmat.2012.06.007 ↗
79. Effect of glass fiber addition on the strength properties and pore structure of fly ash absed geopolymer composites
80. A feasibility study of strain hardening fiber reinforced fly ash-based geopolymer composites10.1016/j.conbuildmat.2014.02.005 ↗
81. Tensile behavior and microstructure of hybrid fiber ambient cured one-part engineered geopolymer composites10.1016/j.conbuildmat.2018.07.012 ↗
82. Deflection hardening behaviour of short fibre reinforced fly ash based geopolymer composites10.1016/j.matdes.2013.03.063 ↗
83. Experimental and numerical investigations on the flexural performance of geopolymers reinforced with short hybrid polymeric fibres10.1016/j.compositesb.2017.06.001 ↗
84. J. Van Mier, G. Ruiz, C. Andrade, R. Yu, X. Zhang, F.U.A. Shaikh, Y.Y. Lu, M. Maalej, in: Proceedings of the Eighth International Conference on Fracture Mechanics of Concrete and Concrete Structures FraMCoS-8 Development of Ductile Fibre Reinforced Geopolymer Composites, 1064–1071. 〈https://espace.curtin.edu.au/bitstream/handle/20.500.11937/7905/191806_81720_FRAMCOS_8_paper.pdf?sequence=2〉.
85. Effect of sand content on engineering properties of fly ash-slag based strain hardening geopolymer composites
86. Mechanical properties of ambient cured high strength hybrid steel and synthetic fibers reinforced geopolymer composites10.1016/j.cemconcomp.2017.10.011 ↗
87. Comparative deflection hardening behavior of short fiber reinforced geopolymer composites10.1016/j.conbuildmat.2014.07.085 ↗
88. Assessment of Na2SiO3 to NaOH ratio impact on the performance of polypropylene fiber-reinforced geopolymer composites10.1016/j.conbuildmat.2018.08.032 ↗
89. Mix design and flexural toughness of PVA fiber reinforced fly ash-geopolymer composites10.1016/j.conbuildmat.2017.05.172 ↗
90. Tensile properties of a novel fibre reinforced geopolymer composite with enhanced strain hardening characteristics10.1016/j.compstruct.2017.01.085 ↗
91. Characterisation of cotton fibre-reinforced geopolymer composites10.1016/j.compositesb.2013.01.013 ↗
92. Novel fiber-reinforced composite materials based on sustainable geopolymer matrix10.1016/j.proeng.2011.11.2120 ↗
93. The effect of organic and inorganic fibres on the mechanical and thermal properties of aluminate activated geopolymers10.1016/j.compositesb.2015.02.023 ↗