Tetracycline degradation and hydrogen production over an interface-engineered double S-Scheme g-C3N4/TiO2 heterojunction photocatalyst
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OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Ammonia Synthesis and Nitrogen Reduction
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References (73)
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1. Zhao M, Li WJ, Yang MW, Zhao ZH, Ye R, Mao XW, Padgett P, Chen P (2024) Long-range enhancement of micropollutant adsorption on metal-promoted photocatalysts. Nat Catal 7(8):912–92010.1038/s41929-024-01199-0 ↗
2. Li SJ, Li R, Dong KX, Liu YP, Yu X, Li WY, Liu T, Zhao ZW, Zhang MY, Zhang B, Chen XB (2025) Self-floating Bi4O5Br2/P-doped C3N4/carbon fiber cloth with S-scheme heterostructure for boosted photocatalytic removal of emerging organic contaminants. Chin J Catal 76:37–4910.1016/S1872-2067(25)64780-2 ↗
3. Ma DY, Liang FL, Xue QQ, Liu YP, Zhuang CQ, Li SJ (2025) Interfacial engineering of Cd0.5Zn0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal. Acta Phys-Chim Sin 41(12):100190
4. Klein EY, Impalli I, Poleon S, Denoel P, Cipriano M, Van Boeckel TP, Pecetta S, Bloom DE, Nandi A (2024) Global trends in antibiotic consumption during 2016–2023 and future projections through 2030. Proc Natl Acad Sci U S A 121(49):1–1210.1073/pnas.2411919121 ↗
5. An MZ, Yang Z, Zhang BB, Xue B, Xu GM, Chen WJ, Wang S (2023) Construction of biochar-modified TiO2 anatase-rutile phase S-scheme heterojunction for enhanced performance of photocatalytic degradation and photocatalytic hydrogen evolution. J Environ Chem Eng 11:110367
6. Heng SL, Xia MT, Zhen GY, Chen YH, Wang JY, Chen X, Wnag JD, Li JB, Song YN, Lu XQ (2025) Bio-inspired engineering of a dual sulfur vacancy-engineered Sv-Bi2S3/Sv-ZnIn2S4 Z-scheme heterojunction for boosted photodegradation of chloroquine phosphate. Chem Eng J 519:165380
7. Dai XN, Hu ZH, Wu Y, Yang TT, Ye ZH, Han HT, Zhang Y, Yang YL (2025) Enhanced photocatalytic activity through interface-defect engineering: synergy and process mechanism. Appl Catal B Environ Energy 379:125667
8. Liu ZK, Zhang YX, Wu YL, Yang BL, Zhou ZY, Jin ZL (2025) In situ XPS evidence of fully conjugated COF and C3N4 construct S-scheme heterojunction boosting photogenerated carriers transfer and separate for efficiently photocatalytic hydrogen evolution. J Mater Sci Technol 233(0):48–57
9. Song CH, Zhang YT, Zhang ZF, Wang HT, Zou J (2025) Synergistic carbonyl/vacancy engineering of aspartic acid-modiffed g-C3N4 nanorods for exceptional photocatalytic H2 production. Chem Eng J 525:170465
10. Wang HT, Yu LL, Jiang JZ, Arramel, Zou J (2024) S-doping of the N-sites of g-C3N4 to enhance photocatalytic H2 evolution activity. Acta Phys-Chim Sin 40(5):230504710.3866/PKU.WHXB202305047 ↗
11. Zhang ZF, Song CH, Fan JP, Fang ZJ, Wang HT, Zou J (2025) Morphology and doping engineering of sulfurdoped g-C3N4 hollow nanovesicles for boosting photocatalytic hydrogen production. J Mater Chem A 13:6385–639610.1039/D4TA09249J ↗
12. Duan HQ, Fan JP, Liu C, Zou J, Wang HT (2025) Green synthesis of phosphorus-doped g-C3N4 as an advanced photocatalyst for H2 evolution. Nano 20(9):2550032
13. Fan JP, Wang HT, Liao GD, Song CH, Zou J (2025) Potassium-doped g-C3N4/nitrogen-doped g-C3N4 step-scheme homojunction for enhanced H2 evolution photocatalysis. Sci China Tech Sci 68(6):1620206
14. Xu ZS, Zhang HB, Zhou JY, Huang T, Sun J, Chang C, Chen Z, Liu K, Tong ZF (2025) Sunlight-driven peroxydisulfate activation by floating Ca/Fe-TiO2@polystyrene spheres for efficient moxifloxacin degradation in circulated water: critical roles of Ca/Fe bimetallic ions crosslinking on the stability of catalyst structure and electron transfer of system. Chem Eng J 513:162750
15. Fan JP, Wang HT, Sun W, Duan HQ, Jiang JZ (2024) Recent developments and perspectives of Ti-based transition metal carbides/nitrides for photocatalytic applications: a critical review. Mater Today 76:110–13510.1016/j.mattod.2024.05.003 ↗
16. Wang J, Wang GH, Cheng B, Yu JG, Fan JJ (2021) Sulfur-doped g-C3N4/TiO2 S-scheme heterojunction photocatalyst for congo red photodegradation. Chin J Catal 42(1):56–6810.1016/S1872-2067(20)63634-8 ↗
17. Yang PH, Yang JQ, Zen XY, Gong YY, Zhong JB (2025) Construction of S-scheme Sb2O3/g-C3N4 heterojunctions for photocatalytic CO2 and Cr(VI) reduction. J Colloid Interface Sci 700(3):138648
18. Shawky A, Mohamed RM (2022) S-scheme heterojunctions: emerging designed photocatalysts toward green energy and environmental remediation redox reactions. J Environ Chem Eng 10(5):10824910.1016/j.jece.2022.108249 ↗
19. Wang HT, Fan JP, Zou J, Zheng YJ, Wang DS, Jiang JZ (2024) Sulfur-doped g-C3N4/V2C MXene Schottky junctions for superior photocatalytic H2 evolution. J Mater Chem A 12:3042910.1039/D4TA05929H ↗
20. Li SJ, Dong KX, Dong MJ, Li XY, Chen XB (2024) A plasmonic S-scheme Au/MIL-101(Fe)/BiOBr photocatalyst for efficient synchronous decontamination of Cr(VI) and norfloxacin antibiotic. eScience 4:100208
21. Ren HT, Miao ZC, Zhao YZ, Ghasemi S, Feng XB, Liu EZ, Padervand M (2025) Advances and challenges in multiple S-scheme heterojunction photocatalysts. J Alloy Compd 1028:180646
22. You CJ, Zhang XL, Zhao YQ, Yan RY, Shen YW, Xue QQ, Li WY, Liu T, Jiang JH, Chen XB, Li SJ (2026) Plasmonic effect augmented S-scheme mechanism in Ag/Ag2O/C3N5 photocatalyst enables efficient photocatalytic degradation of antibiotics. J Mater Sci Technol 242:64–7410.1016/j.jmst.2025.05.002 ↗
23. Maitlo HA, Younis SA, Kim K (2025) Understanding oxidation potential and degradation mechanism of acid-treated TiO2 coupled g-C3N4 S-scheme heterojunction photocatalyst for the removal of gaseous formaldehyde. Sep Purif Technol 356:129862
24. Monteiro FC, Guimaraes IDL, Rodrigues PA, Pinho JVA, Conte-Junior CA (2022) Degradation of PAHs using TiO2 as a semiconductor in the heterogeneous photocatalysis process: a systematic review. J Photochem Photobiol A 437:114497
25. Wu XH, Tan LH, Chen GQ, Kang JY, Wang GH (2024) G-C3N4-based S-scheme heterojunction photocatalysts. Sci China Mater 67(2):444–47210.1007/s40843-023-2755-2 ↗
26. Zhu XL, Zhou EL, Tai XS, Zong HB, Yi JJ, Yuan ZM, Zhao XL, Huang P, Xu H, Jiang ZY (2025) G-C3N4 S-scheme homojunction through van der waals interface regulation by intrinsic polymerization tailoring for enhanced photocatalytic H2 evolution and CO2 reduction. Angew Chem Int Ed 64(13):e202425439
27. Balakrishnan A, Chinthala M, Kumar A, Barceló D, Rtimi S (2025) A Z-scheme defect-rich and dimensionally confined double functionalized g-C3N4 homojunction pectin hydrogels for the photocatalysis-self-Fenton-peroxymonosulfate system: unraveling synergistic catalysis and reaction mechanism. Chem Eng J 503:15837810.1016/j.cej.2024.158378 ↗
28. Wang F, Gao Y, Chai Y, Wang CC, Wang JF, Yi XH, Li Y, Fu H, Zhao C, Wang P (2025) Interfacial engineering regulating electronic structure of homologous S-scheme Co3O4@C-TiO2 heterojunction for enhanced fenton-like reaction activity. Appl Catal B Environ 364:124848
29. Wang HW, Zhang JP, Cheng Y, Zhang PY, Tan MH, Yu RH, Zang YF, Li XL (2026) Synergistic enhancement of TiO2 photocatalysis via Bi deposited BiVO4 and narrow-bandgap CuS co-modification: experiment and DFT study. Appl Catal B Environ 380:125814
30. Yang YQ, Ma GS, An ZJ, Wang W, Hu XL, Wang Y, Du ZL, Gong XZ, Tan HY, Guo FX, Tang JG (2025) Preparation of recyclable g-C3N4/TiO2 heterojunction/alginate hydrogelmicrobeads and investigation of their adsorption-photocatalytic properties. Journal of Hazardous Materials Advances 18:100650
31. Qu WB, Louangsouphom B, Ye XL, Liu HM, Wang X (2025) Rare earth/N co-dopants embedded g-C3N4/TiO2-macroporous resin composites for efficient adsorption-photocatalytic removal of microcystin-LR. J Environ Chem Eng 13(5):118632
32. Hu CC, Jhao YK, Chang YT, Kao LH, Chuang KS, Huang JH, Wibowo A (2025) Type-II heterojunction of g-C3N4/TiO2 hollow spheres for photocatalytic H2 production and degradation of organic contaminants in water. J Alloy Compd 1032:181104
33. Gan W, Chen RX, Zhang L, Guo J, Zhang M, Lu YQ, Sun ZQ (2025) Construction of S-scheme cyano-modified g-C3N4/TiO2 film with boosted charge transfer and highly hydrophilic surface for enhanced photocatalytic degradation of Norfloxacin. J Mater Sci Technol 206:74–8710.1016/j.jmst.2024.03.039 ↗
34. Yang YY, Liu XF, Zhou Q, Gao TY, Wu XH, Wang GH (2025) Dual roles of MHCNF in microwave-antenna induced synthesis and efficient photogenerated carriers transfer of g-C3N4/TiO2 heterojunction photocatalyst. Appl Surf Sci 712:16418610.1016/j.apsusc.2025.164186 ↗
35. Liu SR, Ye QJ, Li Q, Ma ZZ, Yang R, Li D, Jiang DL (2025) Enhancing interfacial charge transfer efficiency via π-π interaction in PTA/VC-CN S-scheme heterojunction for efficient photocatalytic CO2 conversion. Chem Eng J 519:16498710.1016/j.cej.2025.164987 ↗
36. Guo ZX, Qin HY, Shan PN, Xiong B, Wang LJ, Shi WL, Sun Y, Guo F (2025) Photo-activated piezoelectric-catalyzed hydrogen peroxide production in pure water by carbon-modified graphitic carbon nitride. Chem Eng J 520:16582910.1016/j.cej.2025.165829 ↗
37. Shan SN, Wei M, Ma LW, Wang YQ, Li GQ, Zhang GJ (2026) Preparation of Cu-doped g-C3N4 photocatalysts using desulfurization wastewater by-salt and the mechanism analysis of their efficient degradation of formaldehyde. Chem Eng J 320:122380
38. Zhao Y, Yang DY, Yu CL, Yan H (2025) A review on photocatalytic CO2 reduction of g-C3N4 and g-C3N4-based photocatalysts modified by CQDs. J Environ Chem Eng 13(2):11534810.1016/j.jece.2025.115348 ↗
39. Aghe S, Bahramifar N, Younesi H, Ziyarati MT (2025) An integrated life cycle assessment of phenol photocatalytic degradation: evaluating environmental and economic impacts of immobilized versus suspended TiO2-based photocatalysts. J Water Process Eng 77:10841110.1016/j.jwpe.2025.108411 ↗
40. Zou YD, Yang BB, Liu Y, Ren Y, Ma JH, Zhou XR, Cheng XW, Deng YH (2018) Controllable interface-induced co-assembly toward highly ordered mesoporous Pt@TiO2/g-C3N4 heterojunctions with enhanced photocatalytic performance. Adv Funct Mater 28(50):180621410.1002/adfm.201806214 ↗
41. Ai LS, Zhao ZB, Song XD, Tang YC, Feng K, Wang XZ, Zhang BL, Bi HH, Qiu JS (2025) Curved-slit effect induced nucleation for g-C3N4 nanorings with double concaves and enhanced photocatalysis. Adv Funct Mater 35(37):2506395
42. Zhou YM, Yang WL, Feng LJ, Hong J, Abbas M, Kawi S (2025) Sunflower-disc-inspired vertical growth of 2D ZnIn2S4 on ultra-thin TiO2: constructing a 3D porous photocatalytic glass film for ultra-efficient organic pollutant degradation. Appl Catal B-Environ 363:124782
43. Xin SS, Ma XM, Lu JR, Zhang GS, Huo SY, Gao MC, Xu P, Liu WJ, Fu WX (2023) Enhanced visible light photoelectrocatalytic degradation of o-chloronitrobenzene through surface plasmonic Au nanoparticles and g-C3N4 co-modified TiO2 nanotube arrays photoanode. Appl Catal B-Environ 323:122174
44. Moon HS, Hsiao KC, Wu MC, Yun YJ, Hsu YJ, Yong KJ (2023) Spatial separation of cocatalysts on Z-Scheme organic/inorganic heterostructure hollow spheres for enhanced photocatalytic H2 evolution and in-depth analysis of the charge-transfer mechanism. Adv Mater 35(4):e2200172
45. Yoon M, Park Y, Sim H, Kwon H, Lee Y, Jang H, Choi S, Son J (2025) 2D vacancy confinement in anatase TiO2 for enhanced photocatalytic activities. Adv Mater 37(15):241306210.1002/adma.202413062 ↗
46. Yang DX, Xia YW, Xiao T, Xu ZP, Lei YF, Jiao Y, Zhu XD, Feng W (2025) Constructing Ag-TiO2-g-C3N4 S-scheme heterojunctions for photocatalytic degradation of malachite green. Opt Mater 159:116652
47. Abdallah SS, Maridevaru MC, Marzouqi F, Selvaraj R (2025) Green synthesis of TiO2@g-C3N4 nanocomposites for the photocatalytic degradation of pesticides and toxic organics present in water and wastewater. J Photochem Photobiol A Chem 459:11601510.1016/j.jphotochem.2024.116015 ↗
48. Santos G, Tian L, Gonçalves R, García H, Rossi L (2025) Boosting CO2 photoreduction efficiency of carbon nitride via S-scheme g-C3N4/Fe2TiO5 heterojunction. Adv Funct Mater 35(29):2422055
49. Wang XL, Zhang HH, Huang YM, Gao LL, Zhang Y, Meng JY, Liao YF, Zong BN, Dai WL, Li HX (2025) Nitrogen defects and interfacial chemical bonds in Fe single-site mediated C3N4 with rod-like Fe2O3 enhanced the S-Scheme heterojunction for efficient energy conversion. Adv Funct Mater 256:242184710.1002/adfm.202421847 ↗
50. Zhou FH, Li WH, Wu J, Yang W, Sun YJ, Zhou H, Ji T, Ling Y, He P, Pan WG, Zhu QZ, Wang DL, Lin J, Liu QZ (2025) Enhanced solar-driven CO2 conversion: the role of Yb-doped CuInS2 quantum Dots on g-C3N4 nanosheets. Appl Catal B-Environ Energy 362:12471610.1016/j.apcatb.2024.124716 ↗
51. Zheng CJ, Guo YB, Zhang CJ, Cao XJ (2025) Nitrogen-defective protonated porous C3N4 nanosheets for enhanced photocatalytic hydrogen production under visible light. Appl Catal B-Environ Energy 365:12487910.1016/j.apcatb.2024.124879 ↗
52. Li SJ, Li XY, Liu YP, Zhang P, Zhang JL, Zhang B (2025) Interfacial engineering of a plasmonic Ag/Ag2CO3/C3N5 S-scheme heterojunction for high-performance photocatalytic degradation of antibiotics. Chin J Catal 72:130–14210.1016/S1872-2067(25)64652-3 ↗
53. You CJ, Wang CC, Cai MJ, Liu YP, Zhu BK, Li SJ (2024) Improved photo-carrier transfer by an internal electric field in BiOBr/N-rich C3N5 3D/2D S-scheme heterojunction for efficiently photocatalytic micropollutant removal. Acta Phys-Chim Sin 40(11):240701410.3866/PKU.WHXB202407014 ↗
54. Hu JW, Xia K, Yang A, Zhang ZH, Xiao W, Liu C, Zhang QF (2024) Interfacial engineering of ultrathin 2D/2D NiPS3/C3N5 heterojunctions for boosting photocatalytic H2 evolution. Acta Phys-Chim Sin 40(5):230504310.3866/PKU.WHXB202305043 ↗
55. Muthee DK, Dejene FB, Munguti LK (2025) Modification of TiO2 anatase-rutile mixed-phase properties using Sn4+ doping for photocatalytic brilliant green degradation. Appl Catal A-Gen 695:12016610.1016/j.apcata.2025.120166 ↗
56. Li CF, Hu ZY, Li WH, Li Y, Su BL (2025) Direct observation of the TiO2 anatase-rutile phase transition by in-situ transmission electron microscopy. Mater Charact 227:11522610.1016/j.matchar.2025.115226 ↗
57. Erdem NG, Caglar B, İnan E, Tuna Ö, Ertis İF, Simsek EB (2026) Incorporation of CuWO4 with hollow tubular g-C3N4: harnessing the potential in photocatalytic degradation, hydrogen production, and supercapacitor applications. Renew Energ 256:12423510.1016/j.renene.2025.124235 ↗
58. Hazaraimi MH, Goh PS, Wang LY, Lau WJ, Subramaniam M, Naidud M, Ismail AF, Hashim N, Kerisnan ND, Yahaya NKEM, Mamat RBR (2025) Multifunctional roles of g-C3N4 in synthesizing N-TiO2/g-C3N4 heterojunction photocatalyst for photodegradation of bisphenol A. Arab J Sci Eng 50(6):1–1510.1007/s13369-024-09758-0 ↗
59. Challagulla S, Payra S, Chakraborty C, Roy S (2019) Determination of band edges and their inffuences on photocatalytic reduction of nitrobenzene by bulk and exfoliated g-C3N4. Phys Chem Chem Phys 21:3174–318310.1039/C8CP06855K ↗
60. Ni JX, Wang W, Liu DM, Zhu Q, Jia JL, Tian JY, Li ZY, Wang X, Xing ZP (2021) Oxygen vacancy-mediated sandwich-structural TiO2 − x/ultrathin g-C3N4/TiO2 − x direct Z-scheme heterojunction visible-light-driven photocatalyst for efffcient removal of high toxic tetracycline antibiotics. J Hazard Mater 408:124432
61. Han Y, Li YJ, Li TY, Zhang QR, Jiao TF (2024) Electrically enhanced adsorption and photocatalytic properties of g-C3N4/TiO2 heterostructure for removal of tetracycline in water: a study by molecular dynamics simulation and experiment. J Mol Liq 415:126412
62. Gu M, Zhang J, Kurganskii IV, Poryvaev AS, Fedin MV, Cheng B, Yu J, Zhang L (2025) Unveiling charge carrier dynamics at organic-inorganic S-scheme heterojunction interfaces: insights from advanced EPR. Adv Mater 37:2414803
63. Xue XL, Wang CY, Zhu X, Ye DD, Yang Y, Wang H, Chen R, Liao Q (2024) Visible-light responsive photocatalytic fuel cell with gas-diffusion g-C3N4/TiO2 heterojunction photoanode for simultaneously degrading VOCs and generating electricity. J Environ Chem Eng 12(5):114087
64. Muhammad T (2024) Well-designed V2AlC MAX supported g-C3N4/TiO2 Z-scheme heterojunction for photocatalytic CO2 reduction through bi-reforming to produce CO and CH4. Energy 310:133231
65. Xu YF, Li Y, Wei YJ, Liang HO, Xu T, Sun YH, Bai J (2024) Facile synthesis of Pd loaded g-C3N4/TiO2 heterojunction catalyst with enhanced photothermal catalytic performance in Suzuki coupling under moderate condition. Colloid Surface A 690:133751
66. Liang SR, An MZ, Xia SN, Zhang BB, Xue B, Xu GM (2023) Enhanced photocatalytic degradation of methyl orange by TiO2/biochar composites under simulated sunlight irradiation. Opt Mater 142:11410510.1016/j.optmat.2023.114105 ↗
67. Jiang X, Jiang H, Tang YM, Zhang HZ, Yang LB, Wang XW, Zhao B (2024) g-C3N4/TiO2 − X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chem Lett 35(10):109415
68. Li SJ, Wang XQ, Xue B, Feng DJ, Liu YP, Jiang W (2026) Flower-like Ag/Ag2O/Bi12O17Cl2 heterojunction for photocatalytic removal of antibiotics: synergetic effect of plasmonic effect and p–n heterojunction. J Mater Sci Technol 246:237–24610.1016/j.jmst.2024.12.088 ↗
69. Li SJ, Zhao YQ, Zhang XL, Liu YP, Liu T, Li WY, Hou YP, Jiang W, Zhang B (2025) Floatable S-scheme Bi4O5Br2/C3N4/carbon fiber cloth with robust internal electric field for efcient photocatalytic antibiotic decontamination. Adv Fiber Mater 7:2032–204710.1007/s42765-025-00601-1 ↗
70. Bui TK, Le HV, Nguyen HT, Pham VV (2025) Non-binder synthesis of g-C3N4 decorated on TiO2 nanotube arrays toward photo/electrochemical water splitting. Mol Catal 577:114960
71. Rani S, Singh S, Pal B (2025) Superior photocatalytic activity of g-C3N4@Cu-TiO2 core-shell structure for hydrogen production from H2O splitting and C2H5OH dehydrogenation under solar light. Renew Energ 253:12363410.1016/j.renene.2025.123634 ↗
72. Yang XN, Ren LT, Chen ZH, Li HQ, Yuan YP (2025) Constructing an active sulfur-vacancy-rich surface for selective *CH3-CH3 coupling in CO2-to-C2H6 conversion with 92% selectivity. Adv Mater 37:2412299
73. Yu Q, Sun SH, Jin XM, Yan RQ, He BJ, Sirotkin N, Agafonov A, Xiong XQ, Lv KL (2025) Type-I heterojunction photocatalysis: enhanced activity via ZnIn2S4/MnCo2O4.5 interfacial electric ffelds. Chin J Struct Chem 44:100620