Pyrrolic nitrogen-rich carbon quantum dots as anchoring sites for stable and efficient platinum catalysts in proton exchange membrane fuel cells
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OpenAlex topics: Electrocatalysts for Energy Conversion · Carbon and Quantum Dots Applications · Advanced Photocatalysis Techniques
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References (59)
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1. Intergovernmental Panel on Climate Change (IPCC) (2023) Climate Change 2021 – The Physical Science Basis. Cambridge University Press10.1017/9781009157896 ↗
2. Cavicchioli R, Ripple WJ, Timmis KN et al (2019) Scientists’ warning to humanity: microorganisms and climate change. Nat Rev Microbiol 17:569–586. https://doi.org/10.1038/s41579-019-0222-510.1038/s41579-019-0222-5 ↗
3. Jewell J, McCollum D, Emmerling J et al (2018) Limited emission reductions from fuel subsidy removal except in energy-exporting regions. Nat 554:229–233. https://doi.org/10.1038/nature2546710.1038/nature25467 ↗
4. Mutezo G, Mulopo J (2021) A review of Africa’s transition from fossil fuels to renewable energy using circular economy principles. Renew Sustain Energy Rev 137:110609. https://doi.org/10.1016/J.RSER.2020.11060910.1016/J.RSER.2020.110609 ↗
5. Aminudin MA, Kamarudin SK, Lim BH et al (2023) An overview: Current progress on hydrogen fuel cell vehicles. Int J Hydrogen Energy 48:4371–4388. https://doi.org/10.1016/J.IJHYDENE.2022.10.15610.1016/J.IJHYDENE.2022.10.156 ↗
6. Pramuanjaroenkij A, Kakaç S (2023) The fuel cell electric vehicles: The highlight review. Int J Hydrogen Energy 48:9401–9425. https://doi.org/10.1016/J.IJHYDENE.2022.11.10310.1016/J.IJHYDENE.2022.11.103 ↗
7. Singla MK, Nijhawan P, Oberoi AS (2021) Hydrogen fuel and fuel cell technology for cleaner future: a review. Environ Sci Pollut Res 28:15607–15626. https://doi.org/10.1007/s11356-020-12231-8/Published10.1007/s11356-020-12231-8/Published ↗
8. Fan L, Tu Z, Chan SH (2021) Recent development of hydrogen and fuel cell technologies: A review. Energy Rep 7:8421–8446. https://doi.org/10.1016/J.EGYR.2021.08.00310.1016/J.EGYR.2021.08.003 ↗
9. Zhao W, Xu G, Dong W et al (2023) Progress and perspective for in situ studies of oxygen reduction reaction in proton exchange membrane fuel cells. Adv Sci 10:46. https://doi.org/10.1002/advs.20230055010.1002/advs.202300550 ↗
10. Jiao K, Xuan J, Du Q et al (2021) Designing the next generation of proton-exchange membrane fuel cells. Nat 595:361–369. https://doi.org/10.1038/s41586-021-03482-710.1038/s41586-021-03482-7 ↗
11. Che Ramli ZA, Pasupuleti J, Nik Zaiman NFH et al (2025) Evaluating electrocatalytic activities of Pt, Pd, Au and Ag-based catalyst on PEMFC performance: A review. Int J Hydrogen Energy 104:463–486. https://doi.org/10.1016/J.IJHYDENE.2024.04.17710.1016/J.IJHYDENE.2024.04.177 ↗
12. Staffell I, Scamman D, Velazquez Abad A et al (2019) The role of hydrogen and fuel cells in the global energy system. Energy Environ Sci 12:463–491. https://doi.org/10.1039/C8EE01157E10.1039/C8EE01157E ↗
13. Haque MA, Kawawaki T, Negishi Y (2024) Navigating challenges and possibilities for improving polymer electrolyte membrane fuel cells via Pt electrocatalyst, support and ionomer advancements. Int J Hydrogen Energy 85:30–47. https://doi.org/10.1016/J.IJHYDENE.2024.08.32310.1016/J.IJHYDENE.2024.08.323 ↗
14. Wang X, Li Z, Qu Y et al (2019) Review of metal catalysts for oxygen reduction reaction: from nanoscale engineering to atomic design. Chem 5:1486–1511. https://doi.org/10.1016/j.chempr.2019.03.00210.1016/j.chempr.2019.03.002 ↗
15. Brouzgou A, Song SQ, Tsiakaras P (2012) Low and non-platinum electrocatalysts for PEMFCs: Current status, challenges and prospects. Appl Catal B 127:371–388. https://doi.org/10.1016/J.APCATB.2012.08.03110.1016/J.APCATB.2012.08.031 ↗
16. Othman R, Dicks AL, Zhu Z (2012) Non precious metal catalysts for the PEM fuel cell cathode. Int J Hydrogen Energy 37:357–372. https://doi.org/10.1016/J.IJHYDENE.2011.08.09510.1016/J.IJHYDENE.2011.08.095 ↗
17. Yu P, Pemberton M, Plasse P (2005) PtCo/C cathode catalyst for improved durability in PEMFCs. J Power Sources 144:11–20. https://doi.org/10.1016/J.JPOWSOUR.2004.11.06710.1016/J.JPOWSOUR.2004.11.067 ↗
18. Shao Y, Yin G, Gao Y (2007) Understanding and approaches for the durability issues of Pt-based catalysts for PEM fuel cell. J Power Sources 171:558–566. https://doi.org/10.1016/J.JPOWSOUR.2007.07.00410.1016/J.JPOWSOUR.2007.07.004 ↗
19. Yu X, Ye S (2007) Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC: Part II: Degradation mechanism and durability enhancement of carbon supported platinum catalyst. J Power Sources 172:145–154. https://doi.org/10.1016/J.JPOWSOUR.2007.07.04810.1016/J.JPOWSOUR.2007.07.048 ↗
20. Wu J, Yang H (2013) Platinum-based oxygen reduction electrocatalysts. Acc Chem Res 46:1848–1857. https://doi.org/10.1021/ar300359w10.1021/ar300359w ↗
21. Huang L, Zaman S, Tian X et al (2021) Advanced Platinum-Based Oxygen Reduction Electrocatalysts for Fuel Cells. Acc Chem Res 54:311–322. https://doi.org/10.1021/acs.accounts.0c0048810.1021/acs.accounts.0c00488 ↗
22. Liu J, Jiao M, Lu L et al (2017) High performance platinum single atom electrocatalyst for oxygen reduction reaction. Nat Commun 8:15938. https://doi.org/10.1038/ncomms1593810.1038/ncomms15938 ↗
23. Morozan A, Jousselme B, Palacin S (2011) Low-platinum and platinum-free catalysts for the oxygen reduction reaction at fuel cell cathodes. Energy Environ Sci 4:1238–1254. https://doi.org/10.1039/C0EE00601G10.1039/C0EE00601G ↗
24. Kamai R, Kamiya K, Hashimoto K, Nakanishi S (2016) Oxygen-tolerant electrodes with platinum-loaded covalent triazine frameworks for the hydrogen oxidation reaction. Angew Chem Int Ed 128:13378–13382. https://doi.org/10.1002/ange.20160774110.1002/ange.201607741 ↗
25. Li M, Duanmu K, Wan C et al (2019) Single-atom tailoring of platinum nanocatalysts for high-performance multifunctional electrocatalysis. Nat Catal 2:495–503. https://doi.org/10.1038/s41929-019-0279-610.1038/s41929-019-0279-6 ↗
26. Lee SY, Kim MK, Son UH et al (2024) Recent progress of low-loaded platinum on well-functionalized carbon electrocatalysts for oxygen reduction reaction. Carbon Lett 35:107–127. https://doi.org/10.1007/s42823-024-00822-110.1007/s42823-024-00822-1 ↗
27. Lee HR, Han S, Lee JY et al (2023) Effect of pre-annealing on chemical configuration and heteroatom doping of highly active carbon catalysts for the oxygen reduction reaction. J Ind Eng Chem 128:542–549. https://doi.org/10.1016/J.JIEC.2023.08.01910.1016/J.JIEC.2023.08.019 ↗
28. Zhao X, Hayashi A, Noda Z et al (2013) Evaluation of change in nanostructure through the heat treatment of carbon materials and their durability for the start/stop operation of polymer electrolyte fuel cells. Electrochim Acta 97:33–41. https://doi.org/10.1016/j.electacta.2013.02.06210.1016/j.electacta.2013.02.062 ↗
29. Chen Y, Huang J, Chen Z et al (2022) Molecular Engineering toward High-Crystallinity Yet High-Surface-Area Porous Carbon Nanosheets for Enhanced Electrocatalytic Oxygen Reduction. Adv Sci 9:2103477. https://doi.org/10.1002/advs.20210347710.1002/advs.202103477 ↗
30. Colón-Mercado HR, Popov BN (2006) Stability of platinum based alloy cathode catalysts in PEM fuel cells. J Power Sources 155:253–263. https://doi.org/10.1016/j.jpowsour.2005.05.01110.1016/j.jpowsour.2005.05.011 ↗
31. Kim JH, Cheon JY, Shin TJ et al (2016) Effect of surface oxygen functionalization of carbon support on the activity and durability of Pt/C catalysts for the oxygen reduction reaction. Carbon 101:449–457. https://doi.org/10.1016/J.CARBON.2016.02.01410.1016/J.CARBON.2016.02.014 ↗
32. Shu Q, Zhang J, Hu B et al (2022) Rational Design of a High-Durability Pt-Based ORR Catalyst Supported on Mn/N Codoped Carbon Sheets for PEMFCs. Energy Fuels 36:1707–1715. https://doi.org/10.1021/acs.energyfuels.1c0430610.1021/acs.energyfuels.1c04306 ↗
33. Antolini E (2009) Carbon supports for low-temperature fuel cell catalysts. Appl Catal B 88:1–24. https://doi.org/10.1016/J.APCATB.2008.09.03010.1016/J.APCATB.2008.09.030 ↗
34. Shahgaldi S, Hamelin J (2015) Improved carbon nanostructures as a novel catalyst support in the cathode side of PEMFC: a critical review. Carbon 94:705–728. https://doi.org/10.1016/J.CARBON.2015.07.05510.1016/J.CARBON.2015.07.055 ↗
35. Xing Z, Gao N, Qi Y et al (2017) Influence of enhanced carbon crystallinity of nanoporous graphite on the cathode performance of microbial fuel cells. Carbon 115:271–278. https://doi.org/10.1016/J.CARBON.2017.01.01410.1016/J.CARBON.2017.01.014 ↗
36. Datta KKR, Balasubramanian VV, Ariga K et al (2011) Highly crystalline and conductive nitrogen-doped mesoporous carbon with graphitic walls and its electrochemical performance. Chem Eur J 17:3390–3397. https://doi.org/10.1002/chem.20100241910.1002/chem.201002419 ↗
37. Wissler M (2006) Graphite and carbon powders for electrochemical applications. J Power Sources 156:142–150. https://doi.org/10.1016/J.JPOWSOUR.2006.02.06410.1016/J.JPOWSOUR.2006.02.064 ↗
38. Shokrani Havigh R, Mahmoudi Chenari H (2022) A comprehensive study on the effect of carbonization temperature on the physical and chemical properties of carbon fibers. Sci Rep 12:10704. https://doi.org/10.1038/s41598-022-15085-x10.1038/s41598-022-15085-x ↗
39. Kong L, Zhong M, Shuang W et al (2020) Electrochemically active sites inside crystalline porous materials for energy storage and conversion. Chem Soc Rev 49:2378–2407. https://doi.org/10.1039/C9CS00880B10.1039/C9CS00880B ↗
40. Yin H, Yuan J, Wang J et al (2025) Crystalline nitrogen-doped-carbon anchored well-dispersed Fe3O4 nanoparticles for real-time scalable neutral H2O2 electrosynthesis. Energy Environ Sci. https://doi.org/10.1039/d4ee05796a10.1039/d4ee05796a ↗
41. Wang Y, Hu A (2014) Carbon quantum dots: Synthesis, properties and applications. J Mater Chem C Mater 2:6921–6939. https://doi.org/10.1039/c4tc00988f10.1039/c4tc00988f ↗
42. Jang HW, Kang GS, Lee JY et al (2023) Single atomic Fe-based honeycomb catalysts with hierarchically ordered meso- and macropore for the oxygen reduction reaction. J Chem Eng 474:145464. https://doi.org/10.1016/j.cej.2023.14546410.1016/j.cej.2023.145464 ↗
43. Lee SY, Lee JY, Jang HW et al (2023) Aging effect on the structure formation of active sites in single-atomic catalysts and their electrochemical properties for oxygen reduction reaction. J Ind Eng Chem 117:434–441. https://doi.org/10.1016/j.jiec.2022.10.031rds10.1016/j.jiec.2022.10.031rds ↗
44. Kang GS, Jang JH, Son SY et al (2022) Pyrrolic N wrapping strategy to maximize the number of single-atomic Fe-Nx sites for oxygen reduction reaction. J Power Sources 520:230904. https://doi.org/10.1016/J.JPOWSOUR.2021.23090410.1016/J.JPOWSOUR.2021.230904 ↗
45. Lee HR, Kim YS, Lee SY et al (2024) Bifunctional effects of nitrogen-doped carbon quantum dots on CoS2/mesoporous carbon composites for high-performance lithium-ion batteries. Appl Surf Sci 664:160228. https://doi.org/10.1016/J.APSUSC.2024.16022810.1016/J.APSUSC.2024.160228 ↗
46. Coccato A, Jehlicka J, Moens L, Vandenabeele P (2015) Raman spectroscopy for the investigation of carbon-based black pigments. J Raman Spectrosc 46:1003–1015. https://doi.org/10.1002/jrs.471510.1002/jrs.4715 ↗
47. Caņado LG, Takai K, Enoki T et al (2006) General equation for the determination of the crystallite size la of nanographite by Raman spectroscopy. Appl Phys Lett 88:163106. https://doi.org/10.1063/1.219605710.1063/1.2196057 ↗
48. Tauster SJ (1987) Strong metal-support interactions. Acc Chem Res 20:389–394. https://doi.org/10.1021/ar00143a00110.1021/ar00143a001 ↗
49. Yu W, Huang H, Qin Y et al (2022) The Synergistic Effect of Pyrrolic-N and Pyridinic-N with Pt under strong metal-support interaction to achieve high-performance alkaline hydrogen evolution. Adv Energy Mater 12:2200110. https://doi.org/10.1002/aenm.20220011010.1002/aenm.202200110 ↗
50. Shao M, Peles A, Shoemaker K (2011) Electrocatalysis on platinum nanoparticles: Particle size effect on oxygen reduction reaction activity. Nano Lett 11:3714–3719. https://doi.org/10.1021/nl201745910.1021/nl2017459 ↗
51. Nesselberger M, Ashton S, Meier JC et al (2011) The particle size effect on the oxygen reduction reaction activity of Pt catalysts: Influence of electrolyte and relation to single crystal models. J Am Chem Soc 133:17428–17433. https://doi.org/10.1021/ja207016u10.1021/ja207016u ↗
52. Schmitt N, Schmidt M, Mueller JE et al (2023) Which insights can gas diffusion electrode half-cell experiments give into activity trends and transport phenomena of membrane electrode assemblies? Energy Advances 2:854–863. https://doi.org/10.1039/d3ya00055a10.1039/d3ya00055a ↗
53. Li B, Wang J, Gao X et al (2019) High performance octahedral PtNi/C catalysts investigated from rotating disk electrode to membrane electrode assembly. Nano Res 12:281–287. https://doi.org/10.1007/s12274-018-2211-910.1007/s12274-018-2211-9 ↗
54. Wang Y, Pang Y, Xu H et al (2022) PEM Fuel cell and electrolysis cell technologies and hydrogen infrastructure development - a review. Energy Environ Sci 15:2288–2328. https://doi.org/10.1039/D2EE00790H10.1039/D2EE00790H ↗
55. Kim OH, Ahn CY, Kang SY et al (2019) From Half-Cells to Membrane-Electrode Assemblies: a Comparison of Oxygen Reduction Reaction Catalyst Performance Characteristics. Fuel Cells 19:695–707. https://doi.org/10.1002/fuce.20190012010.1002/fuce.201900120 ↗
56. Wang H, Gao Z, Sun B, Mu S, Dang F, Guo X, Ma D, Shi C (2023) Engineering metal-support interaction to construct catalytic interfaces and redisperse metal nanoparticles. Chem Catalysis 3(10):100768. https://doi.org/10.1016/j.checat.2023.10076810.1016/j.checat.2023.100768 ↗
57. Yang C, Li Y, Wang X, Zheng L, Liang H-P (2023) Oxygen reduction catalyzed by pt nanoparticles confined in mesoporous carbon supports doped with single Fe atoms. ACS Applied Nano Materials 6(17):16016–16023. https://doi.org/10.1021/acsanm.3c0301610.1021/acsanm.3c03016 ↗
58. Jayabal S, Saranya G, Geng D, Lin L-Y, Meng X (2020) Insight into the correlation of Pt–support interactions with electrocatalytic activity and durability in fuel cells. J Mater Chem A 8(19):9420–9446. https://doi.org/10.1039/D0TA01530J10.1039/D0TA01530J ↗
59. Lee JY, Park H-Y, Hwang SY, Lee GW, Park GG, Hupp JT, Jang JH, Joh H-I (2025) Effect of electro-sprayed porous electrodes on the performance and stability of water electrolysis. ACS Appl Mater Interfaces 17(16):24547–24555. https://doi.org/10.1021/acsami.4c2190110.1021/acsami.4c21901 ↗