journal article·2019-04

Improvement of interlaminar properties of carbon fiber-reinforced epoxy composites using aluminum trihydroxide

Dong-Jun Kwon, Sung-Min Park, Il-Jun Kwon, Joung-Man Park, Euigyung Jeong

Carbon Letters· Volume 29· Issue 2
Publisher page

Abstract

This study provides an economical and effective method to improve the interlaminar properties of carbon fiber-reinforced polymers (CFRPs) using aluminum trihydroxide (ATH) microparticles. ATH microparticles are cheap and are expected to show good affinity to epoxies in the matrix and sizing agents of the carbon fibers owing to the presence of three hydroxyl groups. In addition, ATH particles are reported to improve the mechanical properties of polymers when used as the reinforcement. In this study, ATH microparticles of various sizes, 1.5, 10, and 20 µm, were used to improve the interlaminar properties of the CFRPs. ATH particles with a size of 1.5 μm improved the tensile properties of the ATH/epoxy resin and did not significantly alter the curing behavior. The interfacial adhesion between the carbon fiber and the epoxy resin was also improved, and the impregnation of the resin mixture remained similar to that of the neat resin, resulting in no significant void and defect formation. Considering the above results, the resulting 1.5 μm ATH-reinforced CFRP showed improved interlaminar properties compared to CFRP without ATH. However, 10 and 20 μm ATH-reinforced CFRPs showed deteriorated interlaminar properties due to the diminished tensile properties of the resin itself and resin impregnation, which resulted in more voids and defects, despite the interfacial adhesion between the fiber and the matrix resin.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fiber-reinforced polymer composites · Mechanical Behavior of Composites · Tribology and Wear Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Nie X, Boakye A, Jia Z, Ma P (2018) The mechanical properties of the multi-axial warp-knit/resin matrix composite containing powder waste. J Ind Text 47:741. https://doi.org/10.1177/152808371667031210.1177/1528083716670312 ↗
2. Haery HA, Zahari R, Kuntjoro W, Taib YM (2014) Tensile strength of notched woven fabric glass, carbon/epoxy composite laminates. J Ind Text 43:383. https://doi.org/10.1177/152808371245605510.1177/1528083712456055 ↗
3. Mittal G, Rhee KY, StankovićVM, and Hui D. Reinforcements in multi-scale polymer composites: Processing, properties, and applications. Compos Part B Eng, 138, 122 (2018). https://doi.org/10.1016/j.compositesb.2017.11.02810.1016/j.compositesb.2017.11.028 ↗
4. Bae JS, Bae J, Woo H, Lee B, Jeong E (2018) Novel thermoplastic toughening agents in epoxy matrix for vacuum infusion process manufactured composites. Carbon Lett 25:43. https://doi.org/10.5714/CL.2018.25.04310.5714/CL.2018.25.043 ↗
5. Moghadam AD, Omrani E, Menezes PL, Rohatgi PK (2015) Mechanical and tribological properties of self-lubricating metal matrix nanocomposites reinforced by carbon nanotubes (CNTs) and graphene – A review. Compos Part B Eng 77:402. https://doi.org/10.1016/j.compositesb.2015.03.01410.1016/j.compositesb.2015.03.014 ↗
6. Liao KH, Mishra DK, Chuang CM, and Ting JM. Large area vapor grown carbon fiber mat and its composite., Compos Part B Eng, 42, 1251 (2011). https://doi.org/10.1016/j.compositesb.2011.02.00710.1016/j.compositesb.2011.02.007 ↗
7. Yao SS, Jin FL, Rhee KY, Hui D, Park SJ (2018) Recent advances in carbon-fiber-reinforced thermoplastic composites: a review. Compos Part B Eng 142:241. https://doi.org/10.1016/j.compositesb.2017.12.00710.1016/j.compositesb.2017.12.007 ↗
8. Bücheler D, Kaiser A, Henning F (2016) Using Thermogravimetric Analysis to Determine Carbon Fiber Weight Percentage of Fiber-Reinforced Plastics. Compos Part B Eng 106:465. https://doi.org/10.1016/j.compositesb.2016.09.02810.1016/j.compositesb.2016.09.028 ↗
9. Yu B, Jiang Z, Yang J (2015) Long-term moisture effects on the interfacial shear strength between surface treated carbon fiber and epoxy matrix. Compos Part A Appl Sci Manuf 78:311. https://doi.org/10.1016/j.compositesa.2015.08.02710.1016/j.compositesa.2015.08.027 ↗
10. Nash NH, Young TM, Stanley WF (2016) The influence of a thermoplastic toughening interlayer and hydrothermal conditioning on the Mode-II interlaminar fracture toughness of Carbon/Benzoxazine composites. Compos Part A Appl Sci Manuf 81:111. https://doi.org/10.1016/j.compositesa.2015.11.01010.1016/j.compositesa.2015.11.010 ↗
11. Chaudhry MS, Czekanski A, Zhu ZH (2017) Characterization of carbon nanotube enhanced interlaminar fracture toughness of woven carbon fiber reinforced polymer composites. Int J Mech Sci 131–132:480. https://doi.org/10.1016/j.ijmecsci.2017.06.01610.1016/j.ijmecsci.2017.06.016 ↗
12. Chung DDL (2017) Processing-structure-property relationships of continuous carbon fiber polymer-matrix composites. Mater Sci Eng R Rep 113:1. https://doi.org/10.1016/j.mser.2017.01.00210.1016/j.mser.2017.01.002 ↗
13. Eskizeybek V, Yar A, Avci A (2018) CNT-PAN hybrid nanofibrous mat interleaved carbon/epoxy laminates with improved Mode I interlaminar fracture toughness. Compos Sci Technol 157:30. https://doi.org/10.1016/j.compscitech.2018.01.02110.1016/j.compscitech.2018.01.021 ↗
14. Srivastava VK, Gries T, Veit D, Quadflieg T, Mohr B, Kolloch M (2017) Effect of nanomaterial on mode I and mode II interlaminar fracture toughness of woven carbon fabric reinforced polymer composites. Eng Fract Mech 96:9. https://doi.org/10.1016/j.engfracmech.2017.05.03010.1016/j.engfracmech.2017.05.030 ↗
15. Ghazali H, Ye L, Zhang MQ (2017) Mode II interlaminar fracture toughness of CF/EP composite containing microencapsulated healing resins. Compos Sci Technol 142:275. https://doi.org/10.1016/j.compscitech.2017.02.01810.1016/j.compscitech.2017.02.018 ↗
16. Ramirez VA, Hogg PJ, Sampson WW (2015) The influence of the nonwoven veil architectures on interlaminar fracture toughness of interleaved composites. Compos Sci Technol 110:103. https://doi.org/10.1016/j.compscitech.2015.01.01610.1016/j.compscitech.2015.01.016 ↗
17. Zhou H, Li C, Zhang L, Crawford B, Milani AS, Ko FK (2018) Micro-XCT analysis of damage mechanisms in 3D circular braided composite tubes under transverse impact. Compos Sci Technol 155:91. https://doi.org/10.1016/j.compscitech.2017.11.02510.1016/j.compscitech.2017.11.025 ↗
18. Zheng Y, Sun Y, Li J, Limin L, Chen L, Liu J, Tian S (2017) Tensile response of carbon-aramid hybrid 3D braided composites. Mater Des 116:246. https://doi.org/10.1016/j.matdes.2016.11.08210.1016/j.matdes.2016.11.082 ↗
19. Zhal J, Cheng S, Zeng T, Wang Z, Jiang L (2018) Thermo-mechanical behavior analysis of 3D braided composites by multiscale finite element method. Compos Struct 183:550. https://doi.org/10.1016/j.compstruct.2017.05.06410.1016/j.compstruct.2017.06.037 ↗
20. Saleh MN, Yudhato A, Potluri P, Lubineau G, Soutis C (2016) Characterising the loading direction sensitivity of 3D woven composites: effect of z-binder architecture. Compos Part A Appl Sci Manuf 90:577. https://doi.org/10.1016/j.compositesa.2016.08.02810.1016/j.compositesa.2016.08.028 ↗
21. Cheng H, Hong C, Zhang X, Xue H (2015) Lightweight carbon-bonded carbon fiber composites with quasi-layered and network structure. Mater Des 85:156. https://doi.org/10.1016/j.matdes.2015.07.09110.1016/j.matdes.2015.07.091 ↗
22. Newcomb BA (2016) Processing, structure, and properties of carbon fibers. Compos Part A Appl Sci Manuf 91:262. https://doi.org/10.1016/j.compositesa.2016.10.01810.1016/j.compositesa.2016.10.018 ↗
23. Gao B, Zhang R, He M, Sun L, Wang C, Liu L, Zhao L, Cui H, Cao A (2016) Effect of a multiscale reinforcement by carbon fiber surface treatment with graphene oxide/carbon nanotubes on the mechanical properties of reinforced carbon/carbon composites. Compos Part A Appl Sci Manuf 90:433. https://doi.org/10.1016/j.compositesa.2016.08.01210.1016/j.compositesa.2016.08.012 ↗
24. Xu Z, Yang T, Nakamura M, Yang Y, Hamada H (2016) Effect of Carbon Powder Surface Treatment on Carbon Fiber Reinforced PA Composites. Enrgy Proced 89:15. https://doi.org/10.1016/j.egypro.2016.05.00310.1016/j.egypro.2016.05.003 ↗
25. Kafi A, Li Q, Chaffraix T, Khoo J, Gengenbach T, Magniez KJC (2018) Surface treatment of carbon fibres for interfacial property enhancement in composites via surface deposition of water soluble POSS nanowhiskers. Polymer 137:97. https://doi.org/10.1016/j.polymer.2018.01.01610.1016/j.polymer.2018.01.016 ↗
26. Hung PY, Lau KT, Fox B, Hameed N, Lee JH, Hui D (2015) Surface modification of carbon fibre using graphene–related materials for multifunctional composites. Compos Part B Eng 133:240. https://doi.org/10.1016/j.compositesb.2017.09.01010.1016/j.compositesb.2017.09.010 ↗
27. Tiwari S, Bijwe J (2014) Surface Treatment of Carbon Fibers - A Review. Proc Tech 14:505. https://doi.org/10.1016/j.protcy.2014.08.06410.1016/j.protcy.2014.08.064 ↗
28. Yao X, Gao X, Jiang J, Xu C, Deng C, Wang J (2018) Comparison of carbon nanotubes and graphene oxide coated carbon fiber for improving the interfacial properties of carbon fiber/epoxy composites. Compos Part B Eng 132:170. https://doi.org/10.1016/j.compositesb.2017.09.01210.1016/j.compositesb.2017.09.012 ↗
29. Kwon DJ, Shin PS, Kim JH, Baek YB, Park HS, DeVreis KL, Park JM (2017) Interfacial properties and thermal aging of glass fiber/epoxy composites reinforced with SiC and SiO2 nanoparticles. Compos Part B Eng 130:46. https://doi.org/10.1016/j.compositesb.2017.07.04510.1016/j.compositesb.2017.07.045 ↗
30. Kwon DJ, Shin PS, Kim JH, DeVries KL, Park JM (2016) Interfacial and wetting properties of carbon fiber reinforced epoxy composites with different hardeners by electrical resistance measurement. Polym Test 53:293. https://doi.org/10.1016/j.polymertesting.2016.06.01410.1016/j.polymertesting.2016.06.014 ↗