journal article·2021-12

Promising nature-based activated carbon derived from flowers of Borassus flabellifer for supercapacitor applications

Zaharaddeen S. Iro, C. Subramani, Jerome Rajendran, Ashok K. Sundramoorthy

Carbon Letters· Volume 31· Issue 6
Publisher page

Abstract

Recently, activated carbon derived from different agricultural by-products or bio-waste is receiving a great deal of attention due to its low or zero cost and environmental friendliness. In this work, flowers obtained from Borassus flabellifer (BFL) is used as a carbon source and potassium hydroxide (KOH) as activation precursor to produce activated carbon with high specific surface area and predominant micropore. The obtained carbon material was activated at 650 °C. The as-prepared sample had a specific surface area of 930.3 m2/g and pore size distribution of 1.96 nm. The carbon material exhibited high electrochemical performance with a specific capacitance of 247 F/g at 0.5 A/g in 1 M H2SO4 electrolyte and an excellent cycling stability of 94% after 2500 cycles. A specific energy of 101.1 Wh/kg and a specific power of 4500 kW/kg were obtained. Based on the electrochemical properties exhibited by BFL, it could be used as an excellent electrode material for supercapacitor applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Electrospun Nanofibers in Biomedical Applications · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (62)

Show source-provided references
1. Abioye AM, Ani FN (2015) Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: a review. Renew Sustain Energy Rev 52:1282–129310.1016/j.rser.2015.07.129 ↗
2. Conway BE (1991) Transition from “supercapacitor” to “battery” behavior in electrochemical energy storage. J Electrochem Soc 138(6):153910.1149/1.2085829 ↗
3. Chen S-M, Ramachandran R, Mani V, Saraswathi R (2014) Recent advancements in electrode materials for the high-performance electrochemical supercapacitors: a review. Int J Electrochem Sci 9(8):4072–408510.1016/S1452-3981(23)08076-8 ↗
4. Burke A (2000) Ultracapacitors: why, how, and where is the technology. J Power Sources 91(1):37–5010.1016/S0378-7753(00)00485-7 ↗
5. Pandolfo AG, Hollenkamp AF (2006) Carbon properties and their role in supercapacitors. J Power Sources 157(1):11–2710.1016/j.jpowsour.2006.02.065 ↗
6. Kiamahalleh MV, Zein SHS, Najafpour G, SataBuniran SAS (2012) Multiwalled carbon nanotubes based nanocomposites for supercapacitors: a review of electrode materials. NANO 7(02):123000210.1142/S1793292012300022 ↗
7. Choi H, Yoon H (2015) Nanostructured electrode materials for electrochemical capacitor applications. Nanomaterials 5(2):906–93610.3390/nano5020906 ↗
8. Halper MS, Ellenbogen JC (2006) Supercapacitors: a brief overview. The MITRE Corporation, McLean, Virginia, USA, pp 1–34
9. Li L, Hu ZA, An N, Yang YY, Li ZM, Wu HY (2014) Facile synthesis of MnO2/CNTs composite for supercapacitor electrodes with long cycle stability. J Phys Chem C 118(40):22865–2287210.1021/jp505744p ↗
10. Iro ZS, Subramani C, Dash S (2016) A brief review on electrode materials for supercapacitor. Int J Electrochem Sci 11:10628–1064310.20964/2016.12.50 ↗
11. Burke A, Zhao H (2015) Applications of supercapacitors in electric and hybrid vehicles. ITS
12. Somayajula D, Crow ML (2015) An integrated dynamic voltage restorer-ultracapacitor design for improving power quality of the distribution grid. IEEE Transac Sustain Energy 6(2):616–62410.1109/TSTE.2015.2402221 ↗
13. Fahmi M, Rajkumar R, Arelhi R, Isa D (2014) The performance of a solar PV system using supercapacitor and varying loads. 2014 IEEE student conference on research and development. IEEE, pp 1–5
14. Moreno-Fernandez G, Ibañez J, Rojo JM, Kunowsky M (2017) Activated Carbon Fiber Monoliths as Supercapacitor Electrodes. Advances in Materials Science and Engineering 2018:1–8. https://doi.org/10.1155/2017/362541410.1155/2017/3625414 ↗
15. Zhang LL, Zhao X (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38(9):2520–253110.1039/b813846j ↗
16. Li J (2012) Review of electrochemical capacitors based on carbon nanotubes and graphene. Graphene 1(01):110.4236/graphene.2012.11001 ↗
17. Genc R, Alas MO, Harputlu E, Repp S, Kremer N, Castellano M, Colak SG, Ocakoglu K, Erdem E (2017) High-capacitance hybrid supercapacitor based on multi-colored fluorescent carbon-dots. Scientific Reports 7(1):1122210.1038/s41598-017-11347-1 ↗
18. Candelaria SL, Shao Y, Zhou W, Li X, Xiao J, Zhang J-G, Wang Y, Liu J, Li J, Cao G (2012) Nanostructured carbon for energy storage and conversion. Nano energy 1(2):195–22010.1016/j.nanoen.2011.11.006 ↗
19. Li X, Wei B (2013) Supercapacitors based on nanostructured carbon. Nano Energy 2(2):159–17310.1016/j.nanoen.2012.09.008 ↗
20. Gao Z, Zhang Y, Song N, Li X (2017) Biomass-derived renewable carbon materials for electrochemical energy storage. Mater Res Lett 5(2):69–8810.1080/21663831.2016.1250834 ↗
21. Gao L, Lu H, Lin H, Sun X, Xu J, Liu D, Li Y (2014) KOH direct activation for preparing activated carbon fiber from polyacrylonitrile-based pre-oxidized fiber. Chem Res Chin Univ 30(3):441–44610.1007/s40242-014-4059-1 ↗
22. González-García P, Centeno T, Urones-Garrote E, Ávila-Brande D, Otero-Díaz L (2013) Microstructure and surface properties of lignocellulosic-based activated carbons. Appl Surf Sci 265:731–73710.1016/j.apsusc.2012.11.092 ↗
23. Marsh H, Reinoso FR (2006) Activated carbon. Elsevier10.1016/B978-008044463-5/50016-9 ↗
24. Farma R, Deraman M, Awitdrus A, Talib I, Taer E, Basri N, Manjunatha J, Ishak M, Dollah B, Hashmi S (2013) Preparation of highly porous binderless activated carbon electrodes from fibres of oil palm empty fruit bunches for application in supercapacitors. Biores Technol 132:254–26110.1016/j.biortech.2013.01.044 ↗
25. Njoku V, Foo K, Hameed B (2013) Microwave-assisted preparation of pumpkin seed hull activated carbon and its application for the adsorptive removal of 2,4-dichlorophenoxyacetic acid. Chem Eng J 215:383–38810.1016/j.cej.2012.10.068 ↗
26. Nabais JV, Laginhas C, Carrott MR, Carrott P, Amorós JC, Gisbert AN (2013) Surface and porous characterisation of activated carbons made from a novel biomass precursor, the esparto grass. Appl Surf Sci 265:919–92410.1016/j.apsusc.2012.11.164 ↗
27. Sych N, Trofymenko S, Poddubnaya O, Tsyba M, Sapsay V, Klymchuk D, Puziy A (2012) Porous structure and surface chemistry of phosphoric acid activated carbon from corncob. Appl Surf Sci 261:75–8210.1016/j.apsusc.2012.07.084 ↗
28. Sun L, Tian C, Li M, Meng X, Wang L, Wang R, Yin J, Fu H (2013) From coconut shell to porous graphene-like nanosheets for high-power supercapacitors. J Mater Chem A 1(21):6462–647010.1039/c3ta10897j ↗
29. Soleimani M, Kaghazchi T (2008) Adsorption of gold ions from industrial wastewater using activated carbon derived from hard shell of apricot stones—an agricultural waste. Biores Technol 99(13):5374–538310.1016/j.biortech.2007.11.021 ↗
30. Okman I, Karagöz S, Tay T, Erdem M (2014) Activated carbons from grape seeds by chemical activation with potassium carbonate and potassium hydroxide. Appl Surf Sci 293:138–14210.1016/j.apsusc.2013.12.117 ↗
31. Shang H, Lu Y, Zhao F, Chao C, Zhang B, Zhang H (2015) Preparing high surface area porous carbon from biomass by carbonization in a molten salt medium. RSC Advances 5(92):75728–7573410.1039/C5RA12406A ↗
32. Sevilla M, Mokaya R (2014) Energy storage applications of activated carbons: supercapacitors and hydrogen storage. Energy Environ Sci 7(4):1250–128010.1039/C3EE43525C ↗
33. Patil B, Kulkarni K (2012) Development of high surface area activated carbon from waste material. Int J Adv Eng Res Stud 1(2):109–113
34. Hirunpraditkoon S, Tunthong N, Ruangchai A, Nuithitiku K (2011) Adsorption capacities of activated carbons prepared from bamboo by KOH activation. World Acad Sci Eng Technol 78:711–715
35. Babel K, Jurewicz K (2004) KOH activated carbon fabrics as supercapacitor material. J Phys Chem Solids 65(2–3):275–28010.1016/j.jpcs.2003.08.023 ↗
36. Maciá-Agulló J, Moore B, Cazorla-Amorós D, Linares-Solano A (2004) Activation of coal tar pitch carbon fibres: physical activation vs. chemical activation. Carbon 42(7):1367–137010.1016/j.carbon.2004.01.013 ↗
37. Abechi S, Gimba C, Uzairu A, Dallatu Y (2013) Preparation and characterization of activated carbon from palm kernel shell by chemical activation. Res J Chem Sci 3(1):54–61
38. Hui TS, Zaini MAA (2015) Potassium hydroxide activation of activated carbon: a commentary. Carbon letters 16(4):275–28010.5714/CL.2015.16.4.275 ↗
39. Li X, Xing W, Zhuo S, Zhou J, Li F, Qiao S-Z, Lu G-Q (2011) Preparation of capacitor’s electrode from sunflower seed shell. Biores Technol 102(2):1118–112310.1016/j.biortech.2010.08.110 ↗
40. Li XF, Xu Q, Fu Y, Guo QX (2014) Preparation and characterization of activated carbon from Kraft lignin via KOH activation. Environ Progress Sustain Energy 33(2):519–52610.1002/ep.11794 ↗
41. Dineshkumar R, Murugan N, Rani JA, Arthanareeswari M, Kamaraj P, Devikala S, Duraisamy N, Sundramoorthy AK (2019) Synthesis of highly fluorescent carbon dots from Plectranthus amboinicus as a fluorescent sensor for Ag+ ion. Mater Res Express 6(10):10400610.1088/2053-1591/ab3a7b ↗
42. Murugan N, Prakash M, Jayakumar M, Sundaramurthy A, Sundramoorthy AK (2019) Green synthesis of fluorescent carbon quantum dots from Eleusine coracana and their application as a fluorescence ‘turn-off’sensor probe for selective detection of Cu2+. Appl Surf Sci 476:468–48010.1016/j.apsusc.2019.01.090 ↗
43. Murugan N, Sundramoorthy AK (2018) Green synthesis of fluorescent carbon dots from Borassus flabellifer flowers for label-free highly selective and sensitive detection of Fe 3+ ions. New J Chem 42(16):13297–1330710.1039/C8NJ01894D ↗
44. Elmouwahidi A, Zapata-Benabithe Z, Carrasco-Marín F, Moreno-Castilla C (2012) Activated carbons from KOH-activation of argan (Argania spinosa) seed shells as supercapacitor electrodes. Biores Technol 111:185–19010.1016/j.biortech.2012.02.010 ↗
45. Ruan C, Ai K, Lu L (2014) Biomass-derived carbon materials for high-performance supercapacitor electrodes. RSC Advances 4(58):30887–3089510.1039/C4RA04470C ↗
46. Xu B, Chen Y, Wei G, Cao G, Zhang H, Yang Y (2010) Activated carbon with high capacitance prepared by NaOH activation for supercapacitors. Mater Chem Phys 124(1):504–50910.1016/j.matchemphys.2010.07.002 ↗
47. Munaiah Y, Raj BGS, Kumar TP, Ragupathy P (2013) Facile synthesis of hollow sphere amorphous MnO2: the formation mechanism, morphology and effect of a bivalent cation-containing electrolyte on its supercapacitive behavior. J Mater Chem A 1(13):4300–430610.1039/c3ta01089a ↗
48. Muniandy L, Adam F, Mohamed AR, Ng E-P (2014) The synthesis and characterization of high purity mixed microporous/mesoporous activated carbon from rice husk using chemical activation with NaOH and KOH. Microporous Mesoporous Mater 197:316–32310.1016/j.micromeso.2014.06.020 ↗
49. Qie L, Chen WM, Wang ZH, Shao QG, Li X, Yuan LX, Hu XL, Zhang WX, Huang YH (2012) Nitrogen-doped porous carbon nanofiber webs as anodes for lithium ion batteries with a superhigh capacity and rate capability. Adv Mater 24(15):2047–205010.1002/adma.201104634 ↗
50. Nagarajan RD, Sundramoorthy AK (2019) One-pot electrosynthesis of silver nanorods/graphene nanocomposite using 4-sulphocalix [4] arene for selective detection of oxalic acid. Sensors and Actuators B: Chem 301:12713210.1016/j.snb.2019.127132 ↗
51. Nagarajan RD, Murugan P, Sundramoorthy AK (2020) Selective electrochemical sensing of NADH and NAD+ using graphene/tungstate nanocomposite modified electrode. ChemistrySelect 5(46):14643–1465110.1002/slct.202003554 ↗
52. Zhao H, Wang F, Ning Y, Zhao B, Yin F, Lai Y, Zheng J, Hu X, Fan T, Tang J (2013) Green “planting” nanostructured single crystal silver. Scientific Reports 3:151110.1038/srep01511 ↗
53. Wang K, Zhao N, Lei S, Yan R, Tian X, Wang J, Song Y, Xu D, Guo Q, Liu L (2015) Promising biomass-based activated carbons derived from willow catkins for high performance supercapacitors. Electrochim Acta 166:1–1110.1016/j.electacta.2015.03.048 ↗
54. Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC technical report). Pure Appl Chem 87(9–10):1051–106910.1515/pac-2014-1117 ↗
55. Chen L-F, Zhang X-D, Liang H-W, Kong M, Guan Q-F, Chen P, Wu Z-Y, Yu S-H (2012) Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. ACS Nano 6(8):7092–710210.1021/nn302147s ↗
56. Qu W-H, Xu Y-Y, Lu A-H, Zhang X-Q, Li W-C (2015) Converting biowaste corncob residue into high value added porous carbon for supercapacitor electrodes. Biores Technol 189:285–29110.1016/j.biortech.2015.04.005 ↗
57. Iro ZS, Subramani C, Kesavan T, Dash S, Sasidharan M, Sundramoorthy AK (2017) MnO2 nanorods/SiO2 sphere coated on single-wall carbon nanotubes as supercapacitor electrode for high energy storage applications. Mater Res Express 4(12):12400410.1088/2053-1591/aa9e12 ↗
58. Taberna P, Simon P, Fauvarque J-F (2003) Electrochemical characteristics and impedance spectroscopy studies of carbon-carbon supercapacitors. J Electrochem Soc 150(3):A292–A30010.1149/1.1543948 ↗
59. Yoon Y, Lee K, Baik C, Yoo H, Min M, Park Y, Lee SM, Lee H (2013) Anti-solvent derived non-stacked reduced graphene oxide for high performance supercapacitors. Adv Mater 25(32):4437–444410.1002/adma.201301230 ↗
60. Yan J, Liu J, Fan Z, Wei T, Zhang L (2012) High-performance supercapacitor electrodes based on highly corrugated graphene sheets. Carbon 50(6):2179–218810.1016/j.carbon.2012.01.028 ↗
61. Cheng Q, Tang J, Ma J, Zhang H, Shinya N, Qin L-C (2011) Graphene and carbon nanotube composite electrodes for supercapacitors with ultra-high energy density. Phys Chem Chem Phys 13(39):17615–1762410.1039/c1cp21910c ↗
62. Cheng Q, Tang J, Ma J, Zhang H, Shinya N, Qin L-C (2011) Graphene and nanostructured MnO2 composite electrodes for supercapacitors. Carbon 49(9):2917–292510.1016/j.carbon.2011.02.068 ↗