journal article·2021-02

Fabrication of porous carbon beads from polyacrylonitrile as electrode materials for electric double-layer capacitors

Byoung-Min Lee, Beom-Seok Choi, Jang-Yong Lee, Sung-Kwon Hong, Jung-Soo Lee, Jae-Hak Choi

Carbon Letters· Volume 31· Issue 1
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Abstract

In this study, we developed a facile and template-free strategy for the preparation of activated porous carbon beads (APCBs) from polyacrylonitrile. The chemical activation with KOH was found to enhance the pore properties, such as specific surface area (SSA), pore volume, and pore area. The APCBs exhibited a large SSA of 1147.99 m2/g and a pore area of 131.73 m2/g. The APCB-based electrodes showed a good specific capacitance of 112 F/g at 1 A/g in a 6 M KOH electrolyte, and excellent capacitance retention of 100% at a current density of 5 A/g after 1000 cycles. Therefore, the APCBs prepared in this study can be applied as electrode materials for electric double-layer capacitors.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Zhang LL, Zhao XS (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38:2520–253110.1039/b813846j ↗
2. Borenstein A, Hanna O, Attias R, Luski S, Brousse T, Aurbach D (2017) Carbon-based composite materials for supercapacitor electrodes: a review. J Mater Chem A 5:12653–1267210.1039/C7TA00863E ↗
3. Li D, Yu C, Wang M, Zhang Y, Pan C (2014) Synthesis of nitrogen doped graphene from graphene oxide within an ammonia flame for high performance supercapacitors. RSC Adv 4:55394–5539910.1039/C4RA10761F ↗
4. Shi K, Ren M, Zhitomirsky I (2014) Activated carbon-coated carbon nanotubes for energy storage in supercapacitors and capacitive water purification. ACS Sustain Chem Eng 2:1289–129810.1021/sc500118r ↗
5. Hasegawa G, Kanamori K, Kiyomura T, Kurata H, Abe T, Nakanishi K (2016) Hierarchically porous carbon monoliths comprising ordered mesoporous nanorod assemblies for high-voltage aqueous supercapacitors. Chem Mater 28:3944–395010.1021/acs.chemmater.6b01261 ↗
6. Chen G, Zhai W, Wang Z, Yu J, Wang F, Zhao Y, Li G (2015) Fabrication and supercapacitive properties of hierarchical porous carbon from polyacrylonitrile. Mater Res Bull 72:204–21010.1016/j.materresbull.2015.07.021 ↗
7. Shu Y, Maruyama J, Iwasaki S, Maruyama S, Shen Y, Uyama H (2017) Fabrication of N-doped and shape-controlled porous monolithic carbons from polyacrylonitrile for supercapacitors. RSC Adv 7:43172–4318010.1039/C7RA07003A ↗
8. Heo YJ, Lee HI, Lee JW, Park M, Rhee KY, Park SJ (2019) Optimization of the pore structure of PAN-based carbon fibers for enhanced supercapacitor performances via electrospinning. Compos B 161:10–1710.1016/j.compositesb.2018.10.026 ↗
9. Drisko GL, Kimling MC, Scales N, Ide A, Sizgek E, Caruso RA, Luca V (2010) One-pot preparation and uranyl adsorption properties of hierarchically porous zirconium titanium oxide beads using phase separation processes to vary macropore morphology. Langmuir 26:1758110.1021/la103177h ↗
10. Liu Y, Cao J, Jiang X, Yang Y, Yu L, Yan X (2018) Large scale production of polyacrylonitrile-based porous carbon nanospheres for asymmetric supercapacitors. J Mater Chem A 6:6891–690310.1039/C8TA01155A ↗
11. Zheng L, Li WB, Chen JL (2018) Nitrogen doped hierarchical activated carbons derived from polyacrylonitrile fibers for CO2 adsorption and supercapacitor electrodes. RSC Adv 8:29767–2977410.1039/C8RA04367A ↗
12. Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW (2015) Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem 87:1051–106910.1515/pac-2014-1117 ↗
13. Jeong DS, Yun JM, Kim KH (2017) Highly porous nitrogen-doped carbon for superior electric double-layer capacitors. RSC Adv 7:44735–4474210.1039/C7RA09272E ↗
14. Werber JR, Osuji CO, Elimelech M (2016) Materials for next-generation desalination and water purification membranes. Nat Rev Mater 1:1601810.1038/natrevmats.2016.18 ↗
15. Li L, Li B, Zhang J (2016) Dopamine-mediated fabrication of ultralight graphene aerogels with low volume shrinkage. J Mater Chem A 4:512–51810.1039/C5TA08829A ↗
16. Zhang F, Liu T, Li M, Yu M, Luo Y, Tong Y, Li Y (2017) Multiscale pore network boosts capacitance of carbon electrodes for ultrafast charging. Nano Lett 17:3097–310410.1021/acs.nanolett.7b00533 ↗
17. Wei X, Jiang X, Wei J, Gao S (2016) Effect of KOH activation on the formation of oxygen structure in activated carbons synthesized from polymeric precursor. Chem Mater 28:445–45810.1021/acs.chemmater.5b02336 ↗
18. Song LT, Wu ZY, Liang HW, Zhou F, Yu ZY, Xu L, Pan Z, Yu SH (2016) Macroscopic-scale synthesis of nitrogen-doped carbon nanofiber aerogels by template-directed hydrothermal carbonization of nitrogen-containing carbohydrates. Nano Energy 19:117–12710.1016/j.nanoen.2015.10.004 ↗
19. Peng L, Liang Y, Dong H, Hu H, Zhao X, Cai Y, Xiao Y, Liu Y, Zheng M (2018) Super-hierarchical porous carbons derived from mixed biomass wastes by a stepwise removal strategy for high-performance supercapacitors. J Power Sources 377:151–16010.1016/j.jpowsour.2017.12.012 ↗
20. Duan B, Gao X, Yao Y, Huang L, Zhou J, Zhang L (2016) Unique elastic N-doped carbon nanofibrous microspheres with hierarchical porosity derived from renewable chitin for high rate supercapacitors. Nano Energy 27:482–49110.1016/j.nanoen.2016.07.034 ↗
21. Ma G, Yang D, Nie J (2009) Preparation of porous ultrafine polyacrylonitrile (PAN) fibers by electrospinning. Polym Adv Technol 20:147–15010.1002/pat.1180 ↗
22. Wu M, Wang Q, Li K, Wu Y, Liu H (2012) Optimization of stabilization conditions for electrospun polyacrylonitrile nanofibers. Polym Degrad Stabil 97:1511–151910.1016/j.polymdegradstab.2012.05.001 ↗
23. Lee BM, Bui VT, Lee HS, Hong SK, Choi HS, Choi JH (2019) Fabrication of hexagonally arranged porous carbon films by proton beam irradiation and carbonization. Radiat Phys Chem 163:18–2110.1016/j.radphyschem.2019.05.006 ↗
24. Lee BM, Nam HG, Choi HY, Hong SK, Jeong YG, Choi JH (2018) Transparent electric heaters based on photoresist-derived carbon micropatterns on quartz plates. Macromol Mater Eng 303:180029610.1002/mame.201800296 ↗
25. Du J, Chen A, Yu Y, Zhang Y, Lv H, Liu L (2019) Mesoporous carbon sheets embedded with vesicles for enhanced supercapacitor performance. J Mater Chem A 7:15707–1571310.1039/C9TA02165E ↗
26. Zu G, Shen J, Zou L, Wang F, Wang X, Zhang Y, Yao X (2016) Nanocellulose-derived highly porous carbon aerogels for supercapacitors. Carbon 99:203–21110.1016/j.carbon.2015.11.079 ↗
27. Tanaka S, Doi A, Matsui T, Miyake Y (2013) Mass transport and electrolyte accessibility through hexagonally ordered channels of self-assembled mesoporous carbons. J Power Sources 228:24–3110.1016/j.jpowsour.2012.11.114 ↗
28. Kim M, Oh I, Kim J (2015) Superior electric double layer capacitors using micro- and mesoporous silicon carbide sphere. J Mater Chem A 3:3944–395110.1039/C4TA07110G ↗
29. Lee BM, Eom JJ, Baek GY, Hong SK, Jeun JP, Choi JH, Yun JM (2019) Cellulose non-woven fabric-derived porous carbon films as binder-free electrodes for supercapacitors. Cellulose 26:4529–4540
30. Wang C, O’Connell MJ, Chan CK (2015) Facile one-pot synthesis of highly porous carbon foams for high-performance supercapacitors using template-free direct pyrolysis. ACS Appl Mater Interfaces 7:8952–896010.1021/acsami.5b02453 ↗
31. Zhou M, Pu F, Wang Z, Guan S (2014) Nitrogen-doped porous carbons through KOH activation with superior performance in supercapacitors. Carbon 68:185–19410.1016/j.carbon.2013.10.079 ↗
32. Lai F, Feng J, Yan R, Wang GC, Antonietti M, Oschatz M (2018) Breaking the limits of ionic liquid-based supercapacitors: mesoporous carbon electrodes functionalized with manganese oxide nanosplotches for dense, stable, and wide-temperature energy storage. Adv Funct Mater 28:180129810.1002/adfm.201801298 ↗
33. Gao F, Shao G, Qu J, Lv S, Li Y, Wu M (2015) Tailoring of porous and nitrogen-rich carbons derived from hydrochar for high-performance supercapacitor electrodes. Electrochim Acta 155:201–20810.1016/j.electacta.2014.12.069 ↗
34. Ling Z, Wang Z, Zhang M, Yu C, Wang G, Dong Y, Liu S, Wang Y, Qiu J (2016) Sustainable synthesis and assembly of biomass-derived B/N co-doped carbon nanosheets with ultrahigh aspect ratio for high-performance supercapacitors. Adv Funct Mater 26(2016):111–11910.1002/adfm.201504004 ↗