journal article·2024-03

Reduced graphene oxide/polyurethane composite sponge fabricated by dual-templates method for piezoresistive pressure sensor

Jingwen Zhang, Lian Liu, Jiao Liu, Yanbin Zhu, Gang Kong, Zijing Ou, Delin Lai, Shuanghong Zhang, Chunshan Che

Carbon Letters· Volume 34· Issue 2
Publisher page

Abstract

Wearable sensors with highly flexible and sensitive characteristics have attracted research interests in the promising field of electronic skin, health monitoring, and soft robotics. However, the developing of high-performance piezoresistive sensor is full of challenges due to the expensive equipment and complex procedures. Herein, we fabricate a reduced graphene oxide/polyurethane composite sponge (GPCS) pressure sensor combining with dual-templates. The polyurethane (PU) sponge provides an elastic structure as solid template. Meanwhile, air bubbles as gas template are used to uniformly disperse graphene oxide (GO) sheets. The burst of air bubbles in the process of thermal treatment makes GO coating on the surface of PU skeleton, avoiding the aggregation of reduced graphene oxide. Therefore, the GPCS exhibits excellent compressibility and uniform coating structure. As a result, it also possesses high sensitivity (Gauge Factor = 3.00 in the range of 0–10% strain), fast response time (35 ms), and excellent cyclic piezoresistive stability (5000 loading–unloading cycles) when applied in the pressure sensor field. Moreover, the flexible wearable stress–strain sensor assembled by the GPCS can be easily adhered on the surface of human skin and precisely detect human movements such as elbow bending and finger bending. Such low-cost procedure and excellent sensing performance enable GPCS sensor to demonstrate tremendous application potential in the field of advanced wearable devices.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Conducting polymers and applications · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. Khan Y, Ostfeld AE, Lochner CM, Pierre A, Arias AC (2016) Monitoring of vital signs with flexible and wearable medical devices. Adv Mater 28:4373–4395. https://doi.org/10.1002/adma.20150436610.1002/adma.201504366 ↗
2. Zheng Q, Liu X, Xu H et al (2018) Sliced graphene foam films for dual-functional wearable strain sensors and switches. Nanoscale Horiz 3:35–44. https://doi.org/10.1039/C7NH00147A10.1039/C7NH00147A ↗
3. Liu L, Zhang J, Shi G, Zhang H, Wang B, Zhong L (2022) An elastic and lamellar piezoresistive graphene/MXene aerogel. J Mater Sci 57:11202–11214. https://doi.org/10.1007/s10853-022-07356-910.1007/s10853-022-07356-9 ↗
4. Dong X, Wei Y, Chen S, Lin Y, Liu L, Li J (2018) A linear and large-range pressure sensor based on a graphene/silver nanowires nanobiocomposites network and a hierarchical structural sponge. Compos Sci Technol 155:108–116. https://doi.org/10.1016/j.compscitech.2017.11.02810.1016/j.compscitech.2017.11.028 ↗
5. Hong X, Yu R, Hou M et al (2021) Smart fabric strain sensor comprising reduced graphene oxide with structure-based negative piezoresistivity. J Mater Sci 56:16946–16962. https://doi.org/10.1007/s10853-021-06365-410.1007/s10853-021-06365-4 ↗
6. Guan X, Wang Z, Zhao W et al (2020) Flexible piezoresistive sensors with wide-range pressure measurements based on a graded nest-like architecture. ACS Appl Mater Interfaces 12:26137–26144. https://doi.org/10.1021/acsami.0c0332610.1021/acsami.0c03326 ↗
7. Guo H, Hua T, Qin J et al (2022) A new strategy of 3D printing lightweight lamellar graphene aerogels for electromagnetic interference shielding and piezoresistive sensor applications. Adv Mater Technol. https://doi.org/10.1002/admt.20210169910.1002/admt.202101699 ↗
8. Zhan Z, Lin R, Tran VT et al (2017) Paper/carbon nanotube-based wearable pressure sensor for physiological signal acquisition and soft robotic skin. ACS Appl Mater Interfaces 9:37921–37928. https://doi.org/10.1021/acsami.7b1082010.1021/acsami.7b10820 ↗
9. Bolotin KI, Sikes KJ, Jiang Z et al (2008) Ultrahigh electron mobility in suspended graphene. Solid State Commun 146:351–355. https://doi.org/10.1016/j.ssc.2008.02.02410.1016/j.ssc.2008.02.024 ↗
10. Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321:385–388. https://doi.org/10.1126/science.115799610.1126/science.1157996 ↗
11. Zhu Y, Murali S, Cai W et al (2010) Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 22:3906–3924. https://doi.org/10.1002/adma.20100106810.1002/adma.201001068 ↗
12. Wang T, Li J, Zhang Y et al (2019) Highly ordered 3D porous graphene sponge for wearable piezoresistive pressure sensor applications. Chem Eur J 25:6378–6384. https://doi.org/10.1002/chem.20190001410.1002/chem.201900014 ↗
13. Zhang T, Wang T, Guo Y et al (2018) Highly pressure-sensitive graphene sponge fabricated by γ-ray irradiation reduction. Sci China Mater 61:1596–1604. https://doi.org/10.1007/s40843-018-9280-y10.1007/s40843-018-9280-y ↗
14. Pang Y, Tian H, Tao L et al (2016) Flexible, highly sensitive, and wearable pressure and strain sensors with graphene porous network structure. ACS Appl Mater Interfaces 8:26458–26462. https://doi.org/10.1021/acsami.6b0817210.1021/acsami.6b08172 ↗
15. Zhong W, Ding X, Li W et al (2019) Facile fabrication of conductive graphene/polyurethane foam composite and its application on flexible piezo-resistive sensors. Polymers 11:1289. https://doi.org/10.3390/polym1108128910.3390/polym11081289 ↗
16. Yao HB, Ge J, Wang CF et al (2013) A flexible and highly pressure-sensitive graphene–polyurethane sponge based on fractured microstructure design. Adv Mater 25:6692–6698. https://doi.org/10.1002/adma.20130304110.1002/adma.201303041 ↗
17. Kovtyukhova NI, Ollivier PJ, Martin BR et al (1999) Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations. Chem Mater 11:771–778. https://doi.org/10.1021/cm981085u10.1021/cm981085u ↗
18. Huang Z, Su M, Yang Q et al (2017) A general patterning approach by manipulating the evolution of two-dimensional liquid foams. Nat Commun 8:1–9. https://doi.org/10.1038/ncomms1411010.1038/ncomms14110 ↗
19. Yang H, Jin X, Sun G et al (2020) Retarding Ostwald ripening to directly cast 3D porous graphene oxide bulks at open ambient conditions. ACS Nano 14:6249–6257. https://doi.org/10.1021/acsnano.0c0237910.1021/acsnano.0c02379 ↗
20. Cançado LG, Takai K, Enoki T et al (2006) General equation for the determination of the crystallite size L a of nanographite by Raman spectroscopy. Appl Phys Lett 88:163106. https://doi.org/10.1063/1.219605710.1063/1.2196057 ↗
21. Chen CM, Huang JQ, Zhang Q et al (2012) Annealing a graphene oxide film to produce a free standing high conductive graphene film. Carbon 50:659–667. https://doi.org/10.1016/j.carbon.2011.09.02210.1016/j.carbon.2011.09.022 ↗
22. Rattana CS, Witit-anun N et al (2012) Preparation and characterization of graphene oxide nanosheets. Procedia Eng 32:759–764. https://doi.org/10.1016/j.proeng.2012.02.00910.1016/j.proeng.2012.02.009 ↗
23. De Silva KKH, Huang HH, Yoshimura M (2018) Progress of reduction of graphene oxide by ascorbic acid. Appl Surf Sci 447:338–346. https://doi.org/10.1016/j.apsusc.2018.03.24310.1016/j.apsusc.2018.03.243 ↗
24. Li D, Müller MB, Gilje S, Kaner RB, Wallace GG (2008) Processable aqueous dispersions of graphene nanosheets. Nat Nanotech 3:101–105. https://doi.org/10.1038/nnano.2007.45110.1038/nnano.2007.451 ↗
25. Pei S, Cheng HM (2012) The reduction of graphene oxide. Carbon 50:3210–3228. https://doi.org/10.1016/j.carbon.2011.11.01010.1016/j.carbon.2011.11.010 ↗
26. Qin Y, Peng Q, Ding Y et al (2015) Lightweight, superelastic, and mechanically flexible graphene/polyimide nanocomposite foam for strain sensor application. ACS Nano 9:8933–8941. https://doi.org/10.1021/acsnano.5b0278110.1021/acsnano.5b02781 ↗
27. Huang J, Liu X, Yang Z, Wu X, Wang J, Yang S (2019) Extremely elastic and conductive N-doped graphene sponge for monitoring human motions. Nanoscale 11:1159–1168. https://doi.org/10.1039/C8NR05102J10.1039/C8NR05102J ↗
28. Wu X, Li Z, Zhu Y, Wang J, Yang S (20121) Ultralight GO-hybridized CNTs aerogels with enhanced electronic and mechanical properties for piezoresistive sensors. ACS Appl Mater Interfaces 13: 26352-26361. https://doi.org/10.1021/acsami.1c0408010.1021/acsami.1c04080 ↗
29. Huang K, Dong S, Yang J et al (2019) Three-dimensional printing of a tunable graphene-based elastomer for strain sensors with ultrahigh sensitivity. Carbon 143:63–72. https://doi.org/10.1016/j.carbon.2018.11.00810.1016/j.carbon.2018.11.008 ↗
30. Xiong Y, Zhu Y, Liu X, Zhu P, Hu Y, Sun R, Wong CP (2020) A flexible pressure sensor based on melamine foam capped by copper nanowires and reduced graphene oxide. Mater Today Commun 24:100970. https://doi.org/10.1016/j.mtcomm.2020.10097010.1016/j.mtcomm.2020.100970 ↗
31. Yang H, Shang JC, Wang WF, Yang YF, Yuan YN, Lei HS, Fang DN (2022) Polyurethane sponges-based ultrasensitive pressure sensor via bioinspired microstructure generated by pre-strain strategy. Compos Sci Technol 221:109308. https://doi.org/10.1016/j.compscitech.2022.10930810.1016/j.compscitech.2022.109308 ↗