journal article·2024-03

Enhanced thermal conductivity of carbon fibers/silanized graphene/epoxy matrix composites

Shan-Shan Yao, Seul-Yi Lee, Hai-Long Li, Fan-Long Jin, Soo-Jin Park

Carbon Letters· Volume 34· Issue 2
Publisher page

Abstract

This study aimed to fabricate composites with high thermal conductivity using diglycidyl ether of bisphenol-A (DGEBA), incorporating carbon fiber cloth (CFC) and graphene as reinforcing agents. Notably, the dispersion of graphene within the DGEBA matrix was enhanced through surface modification via a silane coupling agent. The effects of CFC and graphene addition on the impact strength, thermal conductivity, and morphology of the composites were examined. The experimental results showed that the incorporation of 6 wt% CFC resulted in a substantial (16-fold) increase in impact strength. Furthermore, the introduction of 6 wt% CFCs along with 20 wt% graphene led to a remarkable enhancement in thermal conductivity to 5.7 W/(m K), which was approximately 22 and 4 times higher than the intrinsic thermal conductivities of pristine DGEBA and the CFC/DGEBA composite, respectively. The increased impact strength is ascribed to the incorporation of CFC and silane-modified graphene. Additionally, the gradual increase in thermal conductivity can be attributed to the enhanced interaction between the acidic silane-modified graphene and the basic epoxy–amine hardener within the system studied.
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Research context

OpenAlex topics: Thermal properties of materials · Tribology and Wear Analysis · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Park SJ, Jin FL (2015) Carbon fibers: Chapter 3. Matrices for carbon fiber composites. Springer Ser Mater Sci 210:67–10010.1007/978-94-017-9478-7_3 ↗
2. Ryu JH, Yang SM, Lee JU, Kim JH, Yang SJ (2022) Magnetic alignment of electrochemically exfoliated graphite in epoxy as a thermal interface material with high through-plane thermal conductivity. Carbon Lett 32:1433–143910.1007/s42823-022-00378-y ↗
3. Liu D, Chen Y, Huang H, Yang H, Jin H (2023) Three-dimensional insulating framework construction for achieving high thermal conductivity epoxy composites with superior dielectric properties. Mater Chem Phys 307:1282210.1016/j.matchemphys.2023.128229 ↗
4. Yan T, Cheng M, Liu J, Sun S, Hu S (2022) Catalytic graphene-mediated oxygen blocking and depletion for enhancing dual passive/active anticorrosion of epoxy coatings. Carbon Lett 32:1757–177010.1007/s42823-022-00384-0 ↗
5. Zhang C, Xu Z, Sui W, Zang J, Ao Y, Wang L, Shang L (2023) Synergistic effect of novel ionic liquid/graphene complex on the fame retardancy of epoxy nanocomposites. Carbon Lett 33:501–51610.1007/s42823-022-00440-9 ↗
6. Lian R, Ou M, Zhao Z, Gao Q, Liu X, Liu L, Chen X, Jiao C (2023) Facile fabrication of novel fire-safe MXene@IL-based epoxy nanocomposite coatings with enhanced thermal conductivity and mechanical properties. Prog Org Coat 183:10775010.1016/j.porgcoat.2023.107750 ↗
7. Tian F, Cao J, Ma W (2023) Enhanced thermal conductivity and rheological performance of epoxy and liquid crystal epoxy composites with filled Al2O3 compound. Polym Test 120:10794010.1016/j.polymertesting.2023.107940 ↗
8. Feng T, Cui J, Ou M, Li R, Zhao Z, Geng Y, Chen X, Jiao C (2023) 0D–2D nanohybrids based on binary transitional metal oxide decorated boron nitride enabled epoxy resin efficient flame retardant coupled with enhanced thermal conductivity at ultra-low additions. Compos Commun 41:10164910.1016/j.coco.2023.101649 ↗
9. Jin FL, Park SJ (2015) Preparation and characterization of carbon fiber-reinforced thermosetting composites: a review. Carbon Lett 16(2):67–7710.5714/CL.2015.16.2.067 ↗
10. Akar AO, Yildiz UH, Tirkes S, Tayfun U, Hacivelioglu F (2022) Influence of carbon nanotube inclusions to electrical, thermal, physical and mechanical behaviors of carbon-fiber-reinforced ABS composites. Carbon Lett 32:987–99810.1007/s42823-022-00332-y ↗
11. Yoo SH (2022) Short review of utilization of electron-beam irradiation for preparing polyacrylonitrile-based carbon fibers and improving properties of carbon-fiber-reinforced thermoplastics. Carbon Lett 32:413–42910.1007/s42823-021-00304-8 ↗
12. Sayam A, Rahman ANMM, Rahman MS, Smriti SA, Ahmed F, Rabbi MF, Hossain M, Faruque MO (2022) A review on carbon fiber-reinforced hierarchical composites: mechanical performance, manufacturing process, structural applications and allied challenges. Carbon Lett 32:1173–120510.1007/s42823-022-00358-2 ↗
13. Zhang L, Li X, Wang P, Wei X, Jing D, Zhang X, Zhang S (2023) Increasing the interlaminar fracture toughness and thermal conductivity of carbon fiber/epoxy composites interleaved with carbon nanotube/polyimide composite films. New Carbon Mater 38(3):566–57510.1016/S1872-5805(23)60738-3 ↗
14. Fan W, Li J, Zheng Y, Liu T, Tian X, Sun R (2016) Influence of thermo-oxidative aging on the thermal conductivity of carbon fiber fabric reinforced epoxy composites. Polym Degrad Stabil 123:162–16910.1016/j.polymdegradstab.2015.11.016 ↗
15. Han S, Lin JT, Yamada Y, Chung DDL (2008) Enhancing the thermal conductivity and compressive modulus of carbon fiber polymer–matrix composites in the through-thickness direction by nanostructuring the interlaminar interface with carbon black. Carbon 46:1060–107110.1016/j.carbon.2008.03.023 ↗
16. Wang F, Wang B, Zhang Y, Zhao F, Qiu Z, Zhou L, Chen S, Shi M, Huang Z (2022) Enhanced thermal and mechanical properties of carbon fiber/epoxy composites interleaved with graphene/SiCnw nanostructured films. Compos Part A Appl Sci 162:10712910.1016/j.compositesa.2022.107129 ↗
17. Quan G, Liu Y, Feng H, Li J, Yan Z, Yang C, Li D, Xiao L, Liu Y (2023) Layer-by-layer assembly of biomimetic fish scale structure on carbon fiber surfaces to improve thermal conductivity and mechanical properties of composites. Appl Surf Sci 615:15630810.1016/j.apsusc.2022.156308 ↗
18. Cheng C, Zhang M, Wang S, Li Y, Feng H, Bu D, Xu Z, Liu Y, Jin L, Xiao L, Ao Y (2021) Improving interfacial properties and thermal conductivity of carbon fiber/epoxy composites via the solvent-free GO@Fe3O4 nanofluid modified water-based sizing agent. Compos Sci Technol 209:10878810.1016/j.compscitech.2021.108788 ↗
19. Hao M, Qian X, Zhang Y, Yang J, Li C, Gong H, Wang X, Wang P, Liu L, Huang Y (2023) Thermal conductivity enhancement of carbon fiber/epoxy composites via constructing three-dimensionally aligned hybrid thermal conductive structures on fiber surfaces. Compos Sci Technol 231:10980010.1016/j.compscitech.2022.109800 ↗
20. Yao SS, Ma CL, Jin FL, Park SJ (2020) Fracture toughness enhancement of epoxy resin with graphene nanoplatelets and carbon nanotubes as reinforcing agents. Korean J Chem Eng 37(11):2075–208310.1007/s11814-020-0620-4 ↗
21. Liu J, Yu Q, Yu M, Li S, Zhao K, Xue B, Zu H (2018) Silane modification of titanium dioxide-decorated graphene oxide nanocomposite for enhancing anticorrosion performance of epoxy coatings on AA-2024. J Alloy Compd 744:728–73910.1016/j.jallcom.2018.01.267 ↗
22. Jin FL, Zhang H, Yao SS, Park SJ (2018) Effect of surface modification on impact strength and flexural strength of poly(lactic acid)/silicon carbide nanocomposites. Macromol Res 26(3):211–21410.1007/s13233-018-6028-x ↗
23. Liang X, Li X, Tang Y, Zhang X, Wei W, Liu X (2022) Hyperbranched epoxy resin-grafted graphene oxide for efficient and all-purpose epoxy resin modification. J Colloid Interf Sci 611:105–11710.1016/j.jcis.2021.12.068 ↗
24. Ryu SK, Park BJ, Park SJ (1999) XPS analysis of carbon fibers surfaces-anodized and interfacial effects in fiber-epoxy composites. J Colloid Interface Sci 215:167–16910.1006/jcis.1999.6240 ↗
25. Wu W, Xu Y, Wu H, Chen J, Li M, Chen T, Hong J, Dai L (2020) Synthesis of modified graphene oxide and its improvement on flame retardancy of epoxy resin. J Appl Polym Sci 137(1):4771010.1002/app.47710 ↗
26. Kang MJ, Jin FL, Park SJ (2018) Effect of ozone treatment on fracture toughness of single-walled carbon nanotubes-reinforced epoxy resin initiated by a thermal latent catalyst. Macromol Res 26(11):1048–105110.1007/s13233-018-6138-5 ↗
27. Lin X, Chen X, Zhao S, Dou B, Peng Q, Deng Z, Emori W, Gao X, Fang Z (2023) Effect of silane-modified fluorinated graphene on the anticorrosion property of epoxy coating. J Appl Polym Sci 140(12):e5363710.1002/app.53637 ↗
28. Yao SS, Gao MZ, Feng ZY, Jin FL, Park SJ (2022) Thermal and mechanical properties of poly(latic acid) reinforced with silanized basalt scales. Korean J Chem Eng 39(7):1952–195810.1007/s11814-021-1014-y ↗
29. Li YC, Tang KJ, Jin FL, Park SJ (2022) Enhanced thermal stability and impact strength of phenolic formaldehyde resin using acid-treated basalt scales. J Appl Polym Sci 139(37):e5282710.1002/app.52827 ↗
30. Jiang D, Chu N, Zhang Y, Wang WD, Jin FL, Park SJ (2023) Improved thermal conductivity of epoxy resins using silane coupling agent-modified expanded graphite. J Appl Polym Sci 140(5):e5341710.1002/app.53417 ↗
31. Jin FL, Zhang H, Yao SS, Park SJ (2017) Mechanical and electrical properties of epoxy resin/epoxidized castor oil/carbon fiber cloth composites. Carbon Lett 22:105–109
32. Jin FL, Ma CL, Guo BT, Park SJ (2019) Effect of surface modification on thermal stability, flexural properties, and impact strength of epoxy/graphene nanocomposites. Bull Korean Chem Soc 40(10):991–99610.1002/bkcs.11858 ↗
33. Zhang Y, Fan Y, Kamran U, Park SJ (2022) Improved thermal conductivity and mechanical property of mercapto group-activated boron nitride/elastomer composites for thermal management. Compos Part A Appl Sci 156:10686910.1016/j.compositesa.2022.106869 ↗
34. Guo L, Zhang Z, Li M, Kang R, Chen Y, Song G, Han ST, Lin CT, Jiang N, Yu J (2020) Extremely high thermal conductivity of carbon fiber/epoxy with synergistic effect of MXenes by freeze-drying. Compos Commun 19:134–14110.1016/j.coco.2020.03.009 ↗
35. Kim SH, Heo YJ, Park M, Min BG, Rhee KY, Park SJ (2018) Effect of hydrophilic graphite flake on thermal conductivity and fracture toughness of basalt fibers/epoxy composites. Compos Part B Eng 153:9–1610.1016/j.compositesb.2018.07.022 ↗
36. Zhang Y, Choi JR, Park SJ (2017) Thermal conductivity and thermo-physical properties of nanodiamond-attached exfoliated hexagonal boron nitride/epoxy nanocomposites for microelectronics. Compos Part A Appl Sci 101:227–23610.1016/j.compositesa.2017.06.019 ↗
37. Dong W, Zhao M, Jin FL, Park SJ (2022) Enhanced electrical conductivity and electromagnetic shielding efficiency of epoxy resin using grapheme nanoplatelets. Korean J Chem Eng 39(7):1968–197410.1007/s11814-021-1007-x ↗
38. Wu X, Shi S, Tang B, Chen J, Shan L, Gao Y, Wang Y, Jiang T, Sun K, Yang K, Yu J (2022) Achieving highly thermal conductivity of polymer composites by adding hybrid silver–carbon fiber fillers. Compos Commun 31:10112910.1016/j.coco.2022.101129 ↗
39. Lin S, Lai G, Chen M, Su L, Lan J, Zhong W, Zhang H (2022) Boosting both flame retardancy and mechanical properties of carbon fiber/epoxy composites via polycyclic phosphorus-nitrogen imidazole derivative. Chem Phys Lett 805:13994610.1016/j.cplett.2022.139946 ↗
40. Wazalwar R, Tripathi M, Raichur AM (2022) Curing behavior and mechanical properties of tetra-functional epoxy reinforced with polyethyleneimine-functionalized MXene. ACS Appl Polym Mater 4:2573–258410.1021/acsapm.1c01876 ↗
41. Kim SH, Rhee KY, Park SJ (2020) Amine-terminated chain-grafted nanodiamond/epoxy nanocomposites as interfacial materials: thermal conductivity and fracture resistance. Compos Part B Eng 192:10798310.1016/j.compositesb.2020.107983 ↗
42. Park SJ, Kim BJ, Seo DI, Rhee KY, Lyu YY (2009) Effects of a silane treatment on the mechanical interfacial properties of montmorillonite/epoxy nanocomposites. Mater Sci Eng A 526:74–7810.1016/j.msea.2009.07.023 ↗
43. Lee JH, Rhee KY, Park SJ (2011) Silane modification of carbon nanotubes and its effects on the material properties of carbon/CNT/epoxy three-phase composites. Compos Part A Appl Sci 42:478–48310.1016/j.compositesa.2011.01.004 ↗