journal article·2021-10

Triazine-based 2D covalent organic framework-derived nitrogen-doped porous carbon for supercapacitor electrode

Stella Vargheese, Muthu Dinesh, K. V. Kavya, Dhanaprabhu Pattappan, Ramasamy Thangavelu Rajendra Kumar, Yuvaraj Haldorai

Carbon Letters· Volume 31· Issue 5
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Abstract

Doped porous carbon materials have attracted great interest owing to their excellent electrochemical performance toward energy storage applications. In this report, we described the synthesis of nitrogen-doped porous carbon (N-PC) via carbonization of a triazine-based covalent organic framework (COF) synthesized by Friedel–Crafts reaction. The as-synthesized COF and N-PC were confirmed by X-ray diffraction. The N-PC exhibited many merits including high surface area (711 m2 g−1), porosity, uniform pore size, and surface wettability due to the heteroatom-containing lone pair of electron. The N-PC showed a high specific capacitance of 112 F g−1 at a current density of 1.0 A g−1 and excellent cyclic stability with 10.6% capacitance loss after 5000 cycles at a current density of 2.0 A g−1. These results revealed that the COF materials are desirable for future research on energy storage devices.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Covalent Organic Framework Applications · Supercapacitor Materials and Fabrication · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Conway BE (1999) Electrochemical supercapacitors: scientific fundamentals and technological applications. Kluwer Academic, New York10.1007/978-1-4757-3058-6 ↗
2. Zheng S, Li X, Yan B, Hu Q, Xu Y, Xiao X, Xue H, Pang H (2017) Transition-metal (Fe Co, Ni) based metal-organic frameworks for electrochemical energy storage. Adv Energy Mater 7:1–27
3. Chuang CM, Huang CW, Teng H, Ting JM (2012) Hydrothermally synthesized RuO2/carbon nanofibers composites for use in high-rate supercapacitor electrodes. Compos Sci Technol 72:1524–152910.1016/j.compscitech.2012.05.024 ↗
4. Zhang LL, Zhao XS (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38:2520–253110.1039/b813846j ↗
5. Peng X, Peng L, Wu C, Xie Y (2014) Two dimensional nanomaterials for flexible supercapacitor. Chem Soc Rev 43:3303–332310.1039/c3cs60407a ↗
6. Dubey R, Guruviah V (2019) Review of carbon-based electrode materials for supercapacitor energy storage. Ionics 25:1419–144510.1007/s11581-019-02874-0 ↗
7. Liu Y, Shi Z, Gao Y, An W, Cao Z, Liu J (2016) Biomass-swelling assisted synthesis of hierarchical porous carbon fibers for supercapacitor electrodes. ACS Appl Mater Interfaces 8:28283–2829010.1021/acsami.5b11558 ↗
8. Shan D, Yang J, Liu W, Yan J, Fan Z (2016) Biomass-derived three-dimensional honeycomb-like hierarchical structured carbon for ultrahigh energy density asymmetric supercapacitors. J Mater Chem A 4:13589–1360210.1039/C6TA05406D ↗
9. Fan HL, Shen WZ (2016) Gelatin-based microporous carbon nanosheets as high performance supercapacitor electrodes. ACS Sustain Chem Eng 4:1328–133710.1021/acssuschemeng.5b01354 ↗
10. Chen CJ, Zhang Y, Li YJ, Dai JQ, Song JW, Yao YG, Gong YH, Kierzewski I, Xie J, Hu LB (2017) All-wood low tortuosity aqueous biodegradable supercapacitors with ultra-high capacitance. Energy Environ Sci 10:538–54510.1039/C6EE03716J ↗
11. Abioye AM, Ani FN (2015) Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: a review. Renew Sustain Energy Rev 52:1282–129310.1016/j.rser.2015.07.129 ↗
12. Xu Y, Zhang C, Zhou M, Fu Q, Zhao C, Wu M, Lei Y (2018) Highly nitrogen doped carbon nanofibers with superior rate capability and cyclability for potassium ion batteries. Nat Commun 9:172010.1038/s41467-018-04190-z ↗
13. Hu Y, Liu H, Ke Q, Wang J (2014) Effects of nitrogen doping on supercapacitor performance of a mesoporous carbon electrode produced by a hydrothermal soft-templating process. J Mater Chem A 2:11753–1175810.1039/C4TA01269K ↗
14. Khayum MA, Vijayakumar V, Karak S, Kandambeth S, Bhadra M, Suresh K, Acharambath N, Kurungot S, Banerjee R (2018) Convergent covalent organic framework thin sheets as flexible supercapacitor electrodes. ACS Appl Mater Interfaces 10:28139–2814610.1021/acsami.8b10486 ↗
15. Rengaraj A, Puthiaraj P, Haldorai Y, Heo NS, Hwang SK, Han YK, Kwon S, Ahn WS, Huh YS (2016) Porous covalent triazine polymer as a potential nanocargo for cancer therapy and imaging. ACS Appl Mater Interfaces 8:8947–895510.1021/acsami.6b00284 ↗
16. Zhang G, Hong YL, Nishiyama Y, Bai S, Kitagawa S, Horike S (2019) Accumulation of glassy poly(ethylene oxide) anchored in a covalent organic framework as a solid-state Li+ electrolyte. J Am Chem Soc 141:1227–123410.1021/jacs.8b07670 ↗
17. Baumann D, Lee C, Wan C, Sun H, Duan X (2019) Hierarchical porous carbon derived from covalent triazine frameworks for high mass loading supercapacitors. ACS Mater Lett 1:320–32610.1021/acsmaterialslett.9b00157 ↗
18. Xiang Z, Cao D, Dai L (2015) Well-define two dimensional covalent organic polymers: rational design, controlled syntheses, and potential applications. Polym Chem 6:1896–191110.1039/C4PY01383B ↗
19. DeBlase CR, Silberstein KE, Truong TT, Abruna HD, Dichtel WR (2013) β-Ketoenamine-linked covalent organic frameworks capable of pseudocapacitive energy storage. J Am Chem Soc 135:16821–2168210.1021/ja409421d ↗
20. Li L, Feng L, Rui X, Baolong M, Qi L, Ning W, Hui L, Wenqin Y, Hao G, Wu Y (2019) Ultrastable triazine-based covalent organic framework with an interlayer hydrogen bonding for supercapacitor applications. ACS Appl Mater Interfaces 29:26355–2636310.1021/acsami.9b06867 ↗
21. Vargheese S, Rajendra Kumar RT, Haldorai Y (2019) Synthesis of triazine-based porous organic polymer: a new material for double layer capacitor. Mater Lett 249:53–5610.1016/j.matlet.2019.04.062 ↗
22. Gomes R, Bhanja P, Bhaumik A (2015) A triazine-based covalent organic polymer for efficient CO2 adsorption. Chem Comm 51:10050–1005310.1039/C5CC02147B ↗
23. Rengaraj A, Haldorai Y, Puthiaraj P, Hwang SK, Ryu T, Shin J, Han YK, Ahn WS, Huh YS (2017) Covalent triazine polymer–Fe3O4 nanocomposite for strontium ion removal from seawater. Ind Eng Chem Res 56:4984–499210.1021/acs.iecr.7b00052 ↗
24. Jorge R, David R-S-M, Antonio R, Ruben M-B, Toribio FO, Ilse M, Fabiola L, Gonzalo A, Felix Z, Eugenio C (2017) Metal-functionalized covalent organic frameworks as precursors of supercapacitive porous N-doped graphene. J Mater Chem A 5:4343–435110.1039/C6TA09296A ↗
25. Youyu Z, Mingming C, Yangzhanga WZ, Chengyang W (2018) A biomass-derived nitrogen-doped porous carbon for high-energy supercapacitor. Carbon 140:404–41210.1016/j.carbon.2018.09.009 ↗
26. Xu B, Hou S, Cao G, Wu F, Yang Y (2012) Sustainable nitrogen-doped porous carbon with high surface areas prepared from gelatin for supercapacitors. J Mater Chem 22:19088–1909310.1039/c2jm32759g ↗
27. Li-Feng C, Xu-Dong Z, Hai-Wei L, Mingguang K, Qing-Fang G, Ping C, Zhen-Yu W, Shu-Hong Y (2012) Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. ACS Nano 8:7092–7102
28. Chaochao X, Fen X, Lixian S, Lizhi C, Fang Y, Huanzhi Z, Erhu Y, Hongliang P, Hailiang C, Yongjin Z (2019) A high-performance supercapacitor based on nitrogen-doped porous carbon derived from cycas leaves. Int J Electrochem Sci 14:1782–179310.20964/2019.02.26 ↗
29. Gong Y, Li D, Fu Q, Zhang Y, Pan C (2020) Nitrogen self-doped porous carbon for high-performance supercapacitors. ACS Appl Energy Mater 3:1585–159210.1021/acsaem.9b02077 ↗