journal article·2021-12

Heteroatom-doped mesoporous carbon prepared from a covalent organic framework/α-MnO2 composite for high-performance supercapacitor

Stella Vargheese, Dhanaprabhu Pattappan, K. V. Kavya, M. S. Sivaramkumar, Ramasamy Thangavelu Rajendra Kumar, Yuvaraj Haldorai

Carbon Letters· Volume 31· Issue 6
Publisher page

Abstract

In this report, we successfully prepared nitrogen-doped porous carbon (N-PC)/manganese dioxide (MnO2) composite for a high-performance supercapacitor. X-ray diffraction data revealed the α-MnO2 phase. Transmission electron microscopy confirmed that the nanostructured α-MnO2 nanoparticles were coated on the surface of N-PC. The N-PC/α-MnO2 composite delivered a capacitance of 525.7 F g−1 at the charging current of 1.0 A g−1. The higher capacitance of the composite could be owing to the synergy of MnO2 and N-PC. Besides, the electrode exhibited a 14.7% capacitance loss after 6000 charge–discharge cycles at 10 A g−1 indicating good electrochemical stability.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Covalent Organic Framework Applications · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Conway BE (1999) Electrochemical Supercapacitors: scientific fundamentals and technological applications. Kluwer Academic, New York10.1007/978-1-4757-3058-6 ↗
2. Chen T, Dai L (2014) Flexible supercapacitors based on carbon nanomaterials. J Mater Chem A 2:10756–1077510.1039/c4ta00567h ↗
3. Faraji S, Ani FN (2014) Microwave-assisted synthesis of metal oxide/hydroxide composite electrodes for high power supercapacitors-A review. J Power Sources 263:338–36010.1016/j.jpowsour.2014.03.144 ↗
4. Zhang LL, Zhao XS (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38:2520–253110.1039/b813846j ↗
5. Chen T, Dai L (2013) Carbon nanomaterials for high-performance supercapacitors. Mater Today 16:272–28010.1016/j.mattod.2013.07.002 ↗
6. Pan H, Li J, Feng YP (2010) Carbon nanotubes for supercapacitor. Nanoscale Res Lett 5:654–66810.1007/s11671-009-9508-2 ↗
7. Aval LF, Ghoranneviss B, Pour GB (2018) High-performance supercapacitors based on the carbon nanotubes, graphene and graphite nanoparticles electrodes. Heliyon 4:0086210.1016/j.heliyon.2018.e00862 ↗
8. Wang G, Zhang L, Zhang J (2015) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–82810.1039/C1CS15060J ↗
9. Shown I, Ganguly A, Chen LC, Chen KH (2015) Conducting polymer-based flexible supercapacitor. Energy Sci Eng 3:2–2610.1002/ese3.50 ↗
10. Borenstein A, Hanna O, Attias R, Luski S, Brousse T, Aurbach D (2017) Carbon-based composite materials for supercapacitor electrodes: a review. J Mater Chem A 5:12653–1267210.1039/C7TA00863E ↗
11. Liu Y, Shi Z, Gao Y, An W, Cao Z, Liu J (2016) Biomass-swelling assisted synthesis of hierarchical porous carbon fibers for supercapacitor electrodes. ACS Appl Mater Interfaces 8:28283–2829010.1021/acsami.5b11558 ↗
12. Shan D, Yang J, Liu W, Yan J, Fan Z (2016) Biomass-derived three-dimensional honeycomb-like hierarchical structured carbon for ultrahigh-energy-density asymmetric supercapacitors. J Mater Chem A 4:13589–1360210.1039/C6TA05406D ↗
13. Fan HL, Shen WZ (2016) Gelatin-based microporous carbon nanosheets as high-performance supercapacitor electrodes. ACS Sustain Chem Eng 4:1328–133710.1021/acssuschemeng.5b01354 ↗
14. Chen CJ, Zhang Y, Li YJ, Dai JQ, Song JW, Yao YG, Gong YH, Kierzewski I, Xie J, Hu LB (2017) All-wood, low tortuosity, aqueous, biodegradable supercapacitors with ultrahigh capacitance. Energy Environ Sci 10:538–54510.1039/C6EE03716J ↗
15. Abioye AM, Ani FN (2015) Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review. Renew Sust Energy Rev 52:1282–129310.1016/j.rser.2015.07.129 ↗
16. Ding SY, Wang W (2013) Covalent organic frameworks (COFs): from design to applications. Chem Soc Rev 42:548–56810.1039/C2CS35072F ↗
17. Xiang Z, Cao D, Dai L (2015) Well-defined two-dimensional covalent organic polymers: rational design, controlled syntheses, and potential applications. Polym Chem 6:1896–191110.1039/C4PY01383B ↗
18. Rengaraj A, Puthiaraj P, Haldorai Y, Heo NS, Hwang SK, Han YK, Kwon S, Ahn WS, Huh YS (2016) Porous covalent triazine polymer as a potential nanocargo for cancer therapy and imaging. ACS Appl Mater Interfaces 8:8947–895510.1021/acsami.6b00284 ↗
19. Huang M, Li F, Dong F, Zhang YX, Zhang LL (2015) MnO2-based nanostructures for high-performance supercapacitors. J Mater Chem A 3:21380–2142310.1039/C5TA05523G ↗
20. Singu BS, Yoon KR (2016) Porous manganese oxide nanospheres for pseudocapacitor applications. J Alloys Compd 695:771–77810.1016/j.jallcom.2016.08.239 ↗
21. Hu Y, Wu Y, Wang J (2018) Manganese-oxide-based electrode materials for energy storage applications: how close are we to the theoretical capacitance? Adv Mater 30:180256910.1002/adma.201802569 ↗
22. Huang ZH, Song Y, Feng DY, Sun Z, Sun X, Liu XX (2018) High mass loading MnO2 with hierarchical nanostructures for supercapacitors. ACS Nano 12:3557–356710.1021/acsnano.8b00621 ↗
23. Wang X, Chen S, Li D, Sun S, Peng Z, Komarneni S, Yang D (2018) Direct interfacial growth of MnO2 nanostructure on hierarchically porous carbon for high-performance asymmetric supercapacitors. ACS Sustain Chem Eng 6:633–64110.1021/acssuschemeng.7b02960 ↗
24. Shen H, Zhang Y, Song X, Liu Y, Wang H, Duan H, Kong H (2019) Facile hydrothermal synthesis of actiniaria-shaped α-MnO2/activated carbon and its electrochemical performances of supercapacitor. J Alloy Compd 770:926–93310.1016/j.jallcom.2018.08.228 ↗
25. Yang M, Kim DS, Hong SB, Sim JW, Kim J, Kim SS, Choi BG (2017) MnO2 nanowire/biomass-derived carbon from hemp stem for high-performance supercapacitors. Langmuir 33:5140–514710.1021/acs.langmuir.7b00589 ↗
26. Yang G, Park SJ (2018) MnO2 and biomass-derived 3D porous carbon composites electrodes for high-performance supercapacitor applications. J Alloy Compd 741:360–36710.1016/j.jallcom.2018.01.108 ↗
27. Sun L, Li N, Zhang S, Yu X, Liu C, Zhou Y, Han S, Wang W, Wang Z (2019) Nitrogen-containing porous carbon/α-MnO2 nanowires composite electrode towards supercapacitor applications. J Alloys Compd 789:910–91810.1016/j.jallcom.2019.03.100 ↗
28. Vargheese S, Muthu D, Pattappan D, Kavya KV, Rajendra Kumar RT, Haldorai Y (2020) Hierarchical flower-like MnO2@nitrogen-doped porous carbon composite for symmetric supercapacitor: Constructing a 9.0 V symmetric supercapacitor cell. Electrochim Acta 364:137291.10.1016/j.electacta.2020.137291 ↗
29. Vargheese S, Rajendra Kumar RT, Haldorai Y (2019) Synthesis of triazine-based porous organic polymer: a new material for double layer capacitor. Mater Lett 249:53–5610.1016/j.matlet.2019.04.062 ↗
30. Haldorai Y, Giribabu K, Hwang SK, Kwak CH, Huh YS, Han YK (2016) Facile synthesis of α-MnO2 nanorod/graphene nanocomposite paper electrodes using a 3D precursor for supercapacitors and sensing platform to detect 4-nitrophenol. Electrochim Acta 222:717–72710.1016/j.electacta.2016.11.028 ↗
31. Wang JW, Chen Y, Chen BZ (2015) A synthesis method of MnO2/activated carbon composite for electrochemical supercapacitors. J Electrochem Soc 162:A1654–A166110.1149/2.0031509jes ↗
32. Ramesh S, Kim HS, Haldorai Y, Han YK, Kim JH (2017) Fabrication of nanostructured MnO2/carbon nanotube composite from 3D precursor complex for high-performance supercapacitor. Mater Lett 196:132–13610.1016/j.matlet.2017.03.044 ↗
33. Yiting P, Zheng C, Jing W, Qiangfeng X, Ding W, Shiyu H, Hongbin G, Yunfeng L (2011) Hierarchical manganese oxide/carbon nanocomposites for supercapacitor electrodes. Nano Res 4:216–22510.1007/s12274-010-0072-y ↗
34. Mingxian L, Lihua G, Wei X, Zijie X, Dazhang Z, Longwu C (2014) Development of MnO2/porous carbon microspheres with a partially graphitic structure for high performance supercapacitor electrodes. J Mater Chem A 2:2555–256210.1039/C3TA14445C ↗
35. Chuanjun Y, Haibo L, Haiyan L, Endong X, Yusi Z, Bingyao X (2016) Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors. Appl Energy 178:260–26810.1016/j.apenergy.2016.06.057 ↗
36. Jingge J, Huijuan Z, Weimin K, Nana T, Nanping D, Bowen C (2016) Designing MnO2 & carbon composite porous nanofiber structure for supercapacitor applications. Electrochim acta 258:116–123
37. Xiaojing M, Praveen K, Yong Z, Alevtina LS, Hao F (2016) Electrospun lignin-derived carbon nanofiber mats surface-decorated with MnO2 nanowhiskers as binder-free supercapacitor electrodes with high performance. J Power Sources 325:541–54810.1016/j.jpowsour.2016.06.073 ↗
38. Peigong N, Xiaochuan D, Xiaokang J, Xiaoping L, Xiaobin T, Xi P, Taihong W, Qiuhong L (2016) Facile synthesis of carbon nanofibers/MnO2 nanosheets as high-performance electrodes for asymmetric supercapacitors. Electrochim Acta 210:754–76110.1016/j.electacta.2016.05.214 ↗