Changes in structure of coal liquefied pitch during liquid-phase carbonization process
Source abstract
Abstract
Coal liquefied pitch (CLP) was prepared by the method of solvent extraction–hot filtration–distillation with the coal liquefied residue as the raw material. As one of the preconceived raw material to produce high-quality coal-based carbon material, the changes of structure of CLP during liquid-phase carbonization process have been detailed investigated in this study. Actually, FTIR and curve-fitted method were used to quantitative analyze the aromaticity index (Iar), the ratio of CH3/CH2, and basic functional groups (C=C, C=O, and C–O) of CLP and its liquid-phase carbonization products. Polarizing microscope, XRD and curve-fitted methods were used to characterize the microstructures of CLP and derived products. The results show that, branched chain and C=O group are the active reaction point in liquid-phase carbonization process. What’s more, 450 °C is a critical temperature point on the severe thermal polycondensation of CLP. The XRD and curve-fitted analysis of CLP and its liquid-phase carbonization products shows that, the stacking height (Lc), parallel layers (N), and the numbers of aromatic ring in each layer (n) are gradually larger with the improve of liquid-phase carbonization temperature.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Fiber-reinforced polymer composites · Supercapacitor Materials and Fabrication · Lignin and Wood Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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