journal article·2021-06

Vertically aligned carbon nanotubes-coated aluminium foil as flexible supercapacitor electrode for high power applications

Viney Ghai, Kingshuk Chatterjee, Prabhat K. Agnihotri

Carbon Letters· Volume 31· Issue 3
Publisher page

Abstract

Vertically Aligned Carbon Nanotubes (VACNTs)-coated flexible aluminium (Al) foil is studied as an electrode for supercapacitor applications. VACNTs are grown on Al foil inside thermal Chemical Vapor Deposition (CVD) reactor. 20 nm thick layer of Fe is used as a catalyst while Ar, H2 and C2H2 are used as precursor gases. The effect of growth temperature on the structure of CNTs is studied by varying the temperature of CVD reactor from 550 °C to 625 °C. Better alignment of VACNTs arrays on Al foil is recorded at 600 °C growth temperature in comparison to other processing temperatures. Cyclic voltammetry results shows that VACNTs-coated Al foil has a specific capacitance of ~ 3.01 F/g at a scan rate of 50 mV/s. The direct growth of VACNT array results in better contact with Al foil and thus low ESR values observed in impedance spectroscopy analysis. This leads to a fast charge–discharge cycle as well as a very high value of power density (187.79 kW/kg) suitable for high power applications. Moreover, wettability study shows that the fabricated VACNT electrode has a contact angle of more than 152° which signifies that it is a superhydrophobic surface and hence shows lower specific capacitance in comparison to reported values for VACNT array. Therefore, it is necessary to develop suitable post-processing strategies to make VACNTs hydrophilic to realize their full potential in supercapacitor applications.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Li L, Wu Z, Yuan S, Zhang X-B (2014) Advances and challenges for flexible energy storage and conversion devices and systems. Energy Environ Sci 7:2101. https://doi.org/10.1039/c4ee00318g10.1039/c4ee00318g ↗
2. Ostfeld AE, Gaikwad AM, Khan Y, Arias AC (2016) High-performance flexible energy storage and harvesting system for wearable electronics. Sci Rep 6:4. https://doi.org/10.1038/srep2612210.1038/srep26122 ↗
3. Chen T, Dai L (2014) Flexible supercapacitors based on carbon nanomaterials. J Mater Chem A 2:10756. https://doi.org/10.1039/c4ta00567h10.1039/c4ta00567h ↗
4. Balamurugan J, Nguyen TT, Aravindan V, Kim NH, Lee SH, Lee JH (2019) All ternary metal selenide nanostructures for high energy flexible charge storage devices. Nano Energy 65:103999. https://doi.org/10.1016/j.nanoen.2019.10399910.1016/j.nanoen.2019.103999 ↗
5. Ghai V, Baranwal A, Singh H, Agnihotri PK (2019) Design and fabrication of a multifunctional flexible absorber (Flexorb) in the UV–Vis–NIR wavelength range. Adv Mater Technol 1:1900513. https://doi.org/10.1002/admt.20190051310.1002/admt.201900513 ↗
6. Li H, Tang Z, Liu Z, Zhi C (2019) Evaluating flexibility and wearability of flexible energy storage devices. Joule 3:613–619. https://doi.org/10.1016/j.joule.2019.01.01310.1016/j.joule.2019.01.013 ↗
7. Jin L, Wei K, Xia Y, Liu B, Zhang K, Gao H et al (2019) Tree leaves-derived three-dimensional porous networks as separators for graphene-based supercapacitors. Mater Today Energy 14:100348. https://doi.org/10.1016/j.mtener.2019.10034810.1016/j.mtener.2019.100348 ↗
8. Helseth LE (2019) Modelling supercapacitors using a dynamic equivalent circuit with a distribution of relaxation times. J Energy Storage 25:100912. https://doi.org/10.1016/j.est.2019.10091210.1016/j.est.2019.100912 ↗
9. Afif A, Rahman SM, Tasfiah Azad A, Zaini J, Islan MA, Azad AK (2019) Advanced materials and technologies for hybrid supercapacitors for energy storage – a review. J Energy Storage 25:100852. https://doi.org/10.1016/j.est.2019.10085210.1016/j.est.2019.100852 ↗
10. Li J, Qiao J, Lian K (2019) Hydroxide ion conducting polymer electrolytes and their applications in solid supercapacitors: a review. Energy Storage Mater. https://doi.org/10.1016/j.ensm.2019.08.01210.1016/j.ensm.2019.08.012 ↗
11. Cossutta M, Vretenar V, Centeno TA, Kotrusz P, McKechnie J, Pickering SJ (2020) A comparative life cycle assessment of graphene and activated carbon in a supercapacitor application. J Cleaner Prod 242:118468. https://doi.org/10.1016/j.jclepro.2019.11846810.1016/j.jclepro.2019.118468 ↗
12. Cao J, Mei Q, Wu R, Wang W (2019) Flower-like nickel–cobalt layered hydroxide nanostructures for super long-life asymmetrical supercapacitors. Electrochim Acta 321:134711. https://doi.org/10.1016/j.electacta.2019.13471110.1016/j.electacta.2019.134711 ↗
13. Winter M, Brodd RJ (2004) What are batteries, fuel cells, and supercapacitors? Chem Rev 104:424510.1021/cr020730k ↗
14. Zhu Z, Wang G, Sun M, Li X, Li C (2011) Fabrication and electrochemical characterization of polyaniline nanorods modified with sulfonated carbon nanotubes for supercapacitor applications. Electrochim Acta 56:1366–137210.1016/j.electacta.2010.10.070 ↗
15. Xu X, Li J, Li Y, Ni B, Liu X, Pan L (2018) Selection of Carbon Electrode Materials. In: Ahualli S, Delgado ÁV (eds) Interface Science and Technology. Elsevier, London
16. Lück J, Latz A (2018) Modeling of the electrochemical double layer and its impact on intercalation reactions. Phys Chem Chem Phys 20:27804–27821. https://doi.org/10.1039/C8CP05113E10.1039/C8CP05113E ↗
17. Favaro M, Jeong B, Ross PN, Yano J, Hussain Z, Liu Z et al (2016) Unravelling the electrochemical double layer by direct probing of the solid/liquid interface. Nat Commun 7:1–8. https://doi.org/10.1038/ncomms1269510.1038/ncomms12695 ↗
18. Chen T, Dai L (2013) Carbon nanomaterials for high-performance supercapacitors. Mater Today 16:272–280. https://doi.org/10.1016/j.mattod.2013.07.00210.1016/j.mattod.2013.07.002 ↗
19. Wang Y, Zhang K, Zou J, Wang X, Sun L, Wang T et al (2017) Functionalized horizontally aligned CNT array and random CNT network for CO2 sensing. Carbon 117:263–270. https://doi.org/10.1016/j.carbon.2017.03.01210.1016/j.carbon.2017.03.012 ↗
20. Lee CY, Tsai HM, Chuang HJ, Li SY, Lin P, Tseng TY (2005) Characteristics and electrochemical performance of supercapacitors with manganese oxide-carbon nanotube nanocomposite electrodes. J Electrochem Soc 152:A716–A72010.1149/1.1870793 ↗
21. Wang X, Lu X, Liu B, Chen D, Tong Y, Shen G (2014) Flexible energy-storage devices: design consideration and recent progress. Adv Mater 26:4763–4782. https://doi.org/10.1002/adma.20140091010.1002/adma.201400910 ↗
22. Ghai V, Singh H, Agnihotri PK (2019) Dandelion-like carbon nanotubes for near perfect black surfaces. ACS Appl Nano Mater. https://doi.org/10.1021/acsanm.9b0195010.1021/acsanm.9b01950 ↗
23. Ghai V, Singh H, Agnihotri PK (2019) Near perfect thin film flexible broadband optical absorber with high thermal/electrical conductivity. J Appl Poly Sci 1:48855. https://doi.org/10.1002/app.4885510.1002/app.48855 ↗
24. Ghai V, Bedi HS, Bhinder J, Chauhan A, Singh H, Agnihotri PK (2020) Catalytic-free growth of VACNTs for energy harvesting. Full Nano Carbon Nanostruct 28(11):907–912. https://doi.org/10.1080/1536383X.2020.178325210.1080/1536383X.2020.1783252 ↗
25. Li WZ, Wen JG, Ren ZF (2002) Effect of temperature on growth and structure of carbon nanotubes by chemical vapor deposition. Appl Phys A Mater Sci Process 74:397–402. https://doi.org/10.1007/s00339020128410.1007/s003390201284 ↗
26. Xiang R, Luo G, Yang Z, Zhang Q, Qian W, Wei F (2007) Temperature effect on the substrate selectivity of carbon nanotube growth in floating chemical vapor deposition. Nanotechnology 18:415703. https://doi.org/10.1088/0957-4484/18/41/41570310.1088/0957-4484/18/41/415703 ↗
27. Pham QN, Larkin LS, Lisboa CC, Saltonstall CB, Qiu L, Schuler JD et al (2017) Effect of growth temperature on the synthesis of carbon nanotube arrays and amorphous carbon for thermal applications. Physica Status Solidi (A) 214:160085210.1002/pssa.201600852 ↗
28. Aksak M, Kir S, Selamet Y (2009) Effect of the growth temperature on carbon nanotubes grown by thermal chemical vapor deposition method. J Optoelectron Adv Mater 1:281–248
29. Yang Z-P, Ci L, Bur JA, Lin S-Y, Ajayan PM (2008) Experimental observation of an extremely dark material made by a low-density nanotube array. Nano Lett 8:446–451. https://doi.org/10.1021/nl072369t10.1021/nl072369t ↗
30. Kyung SJ, Lee YH, Kim CW, Lee JH, Yeom GY (2006) Field emission properties of carbon nanotubessynthesized by capillary type atmospheric pressure plasmaenhanced chamical vapor deposition at low temperature. Carbon 44:1530–153410.1016/j.carbon.2005.12.020 ↗
31. Phokaratkul D, Mensing JP, Jaruwongrangsee K, Lomas T, Tuantranont A, Wisitsoraat A (2015) Novel 3D graphene foam Polyaniline Carbon nanotubes Supercapacitor Prepared by Electropolymerization. Proceedings of the 15th International Conference on Nanotechnology. IEEE, Rome
32. Dogru IB, Durukan MB, Turel O, Unalan HE (2016) Flexible supercapacitor electrodes with vertically aligned carbon nanotubes grown on aluminum foils. Prog Nat Sci Mater Internat 26:232–236. https://doi.org/10.1016/j.pnsc.2016.05.01110.1016/j.pnsc.2016.05.011 ↗
33. Mizuno K, Ishii J, Kishida H, Hayamizu Y, Yasuda S, Futaba DN et al (2009) A black body absorber from vertically aligned single-walled carbon nanotubes. Proc Natl Acad Sci 106:6044–6047. https://doi.org/10.1073/pnas.090015510610.1073/pnas.0900155106 ↗
34. Belhachemi Raël Davat (2000) A physical based model of power electric double-layer supercapacitors. IEEE Trans Indu Appl 1:3069–3076
35. Conway BE (1999) Electrochemical supercapacitors: scientific fundamentals and technological applications. Kluwer Academic/Plenum Publishers, BA10.1007/978-1-4757-3058-6 ↗
36. Kulal PM, Dubal DP, Lokhande CD, Fulari VJ (2011) Chemical synthesis of Fe2O3 thin films for supercapacitor application. J Alloy Compd 509:2567–2571. https://doi.org/10.1016/j.jallcom.2010.11.09110.1016/j.jallcom.2010.11.091 ↗
37. Aval LF, Ghoranneviss M, Pour GB (2018) High-performance supercapacitors based on the carbon nanotubes, graphene and graphite nanoparticles electrodes. Heliyon 4:e00862. https://doi.org/10.1016/j.heliyon.2018.e0086210.1016/j.heliyon.2018.e00862 ↗
38. Rose MF, Merryman SA (1996) Electrochemical capacitor technology for actuator applications. IEEE 1:245–250
39. Saghafi M, Mahboubi F, Mohajerzadeh S, Holze R (2014) Preparation of vertically aligned carbon nanotubes and their electrochemical performance in supercapacitors. Synth Met 195:252–259. https://doi.org/10.1016/j.synthmet.2014.06.01210.1016/j.synthmet.2014.06.012 ↗
40. Hsia B, Marschewski J, Wang S, In JB, Carraro C, Poulikakos D et al (2014) Highly flexible, all solid-state micro-supercapacitors from vertically aligned carbon nanotubes. Nanotechnology 25:055401. https://doi.org/10.1088/0957-4484/25/5/05540110.1088/0957-4484/25/5/055401 ↗
41. Cui K, Wardle BL (2019) Breakdown of native oxide enables multifunctional, free-form carbon nanotube-metal hierarchical architectures. ACS Appl Mater Interface 11:35212–35220. https://doi.org/10.1021/acsami.9b0829010.1021/acsami.9b08290 ↗
42. Taberna PL, Simon P, Fauverque JF (2003) Electrochemical characteristics and impedance spectroscopy studies of carbon-carbon supercapacitors. J Electrochem Soc 150:A292–A30010.1149/1.1543948 ↗
43. Raza W, Ali F, Raza N, Luo Y, Kim KH, Yang J, Kumar S, Mehmood A, Kwon EE (2018) Recent advancements in supercapacitor technology. Nano Energy 52:441–47310.1016/j.nanoen.2018.08.013 ↗
44. Dörfler S, Felhösi I, Marek T, Thieme S, Althues H, Nyikos L et al (2013) High power supercap electrodes based on vertical aligned carbon nanotubes on aluminum. J Power Sources 227:218–228. https://doi.org/10.1016/j.jpowsour.2012.11.06810.1016/j.jpowsour.2012.11.068 ↗
45. Kavian R, Vicenzo A, Bestetti M (2011) Growth of carbon nanotubes on aluminium foil for supercapacitors electrodes. J Mater Sci 46:1487–1493. https://doi.org/10.1007/s10853-010-4950-110.1007/s10853-010-4950-1 ↗
46. Reit R, Nguyen J, Ready WJ (2013) Growth time performance dependence of vertically aligned carbon nanotube supercapacitors grown on aluminum substrates. Electrochim Acta 91:96–100. https://doi.org/10.1016/j.electacta.2012.12.05810.1016/j.electacta.2012.12.058 ↗
47. Karumuri AK, He L, Mukhopadhyay SM (2015) Tuning the surface wettability of carbon nanotube carpets in multiscale hierarchical solids. Appl Surf Sci 327:122–130. https://doi.org/10.1016/j.apsusc.2014.10.15410.1016/j.apsusc.2014.10.154 ↗