Preparation of petroleum-based mesophase pitch toward cost-competitive high-performance carbon fibers
Source abstract
Abstract
Spinnable mesophase pitch precursor containing more than 98% mesophase content was successfully prepared from FCC-DO (fluid catalytic cracking-decant oil) without hydrogenation or catalytic reaction. The preparation method involved thermal condensation, vacuum treatment, and annealing treatment. Petroleum mesophase pitch-based carbon fibers are produced by melt spinning of pitch precursors, followed by stabilization and carbonization. The resulting carbon fiber exhibited good mechanical performances up to tensile strength of 2.1 GPa and tensile modulus of 212 GPa, with strain-to-failure higher than 1.0%. These properties ensuring that the automotive grade carbon fibers can be successfully prepared from FCC-DO derived petroleum mesophase pitches through the cost-competitive processes.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Fiber-reinforced polymer composites · Mechanical Behavior of Composites · Natural Fiber Reinforced Composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (33)
Show source-provided references
1. Liu J, Shimanoe H, Nakabayashi K, Miyawaki J, Ko S, Jeon Y-P, Yoon S-H (2018) Preparation of isotropic pitch precursor for pitch-based carbon fiber through the co-carbonization of ethylene bottom oil and polyvinyl chloride. J Ind Eng Chem 67:276–283. https://doi.org/10.1016/j.jiec.2018.06.03910.1016/j.jiec.2018.06.039 ↗
2. Kil H-S, Oh K, Kim Y-J, Ko S, Jeon YP, Joh H-I, Kim Y-K, Lee S (2018) Structural evolution of pitch fibers during low temperature carbonization. J Anal Appl Pyrolysis 136:153–159. https://doi.org/10.1016/j.jaap.2018.10.01010.1016/j.jaap.2018.10.010 ↗
3. Jeon Y-P, Alway-Cooper R, Morales M, Ogale AA (2013) Chapter 2.8—carbon fibers. Academic Press, Oxford, pp 143–154
4. Frank E, Steudle LM, Ingildeev D, Spörl JM, Buchmeiser MR (2014) Carbon fibers: precursor systems, processing, structure, and properties. Angew Chem Int Ed 53:5262–5298. https://doi.org/10.1002/anie.20130612910.1002/anie.201306129 ↗
5. Ko S, Choi J-E, Lee CW, Jeon Y-P (2017) Modified oxidative thermal treatment for the preparation of isotropic pitch towards cost-competitive carbon fiber. J Ind Eng Chem 54:252–261. https://doi.org/10.1016/j.jiec.2017.05.03910.1016/j.jiec.2017.05.039 ↗
6. Ko S, Choi J-E, Yim H, Miyawaki J, Yoon S-H, Jeon Y-P (2019) Improved understanding of the molecular structure of pyrolysis fuel oil: towards its utilization as a raw material for mesophase pitch synthesis. Carbon Lett. https://doi.org/10.1007/s42823-019-00027-x10.1007/s42823-019-00027-x ↗
7. Kim JH, Kim JG, Lee KB, Im JS (2019) Effects of pressure-controlled reaction and blending of PFO and FCC-DO for mesophase pitch. Carbon Lett. https://doi.org/10.1007/s42823-019-00022-210.1007/s42823-019-00022-2 ↗
8. Choi J-E, Ko S, Kim JG, Jeon Y-P (2018) Effects of pressure during the synthesis of petroleum pitch precursors in open and closed systems. Carbon Lett 25:95–102. https://doi.org/10.5714/cl.2018.25.09510.5714/cl.2018.25.095 ↗
9. Yamada Y, Matsumoto S, Fukuda K, Honda H (1981) Optically anisotropic texture in tetrhydroqulnoline soluble matter of carbomceous mesophase. Tanso 1981:144–146. https://doi.org/10.7209/tanso.1981.14410.7209/tanso.1981.144 ↗
10. Mochida I, Kudo K, Fukuda N, Takeshita K, Takahashi R (1975) Carbonization of pitches—IV: Carbonization of polycyclic aromatic hydrocarbons under the presence of aluminum chloride catalyst. Carbon 13:135–139. https://doi.org/10.1016/0008-6223(75)90270-510.1016/0008-6223(75)90270-5 ↗
11. Kubo J, Higashi H, Ohmoto Y, Arao H (1996) Heavy oil hydroprocessing with the addition of hydrogen-donating hydrocarbons derived from petroleum. Energy Fuels 10:474–481. https://doi.org/10.1021/ef950132r10.1021/ef950132r ↗
12. Korai Y, Mochida I (1985) Preparation and properties of carbonaceous mesophase-i soluble mesophase produced from A240 and coal tar pitch. Carbon 23:97–103. https://doi.org/10.1016/0008-6223(85)90203-910.1016/0008-6223(85)90203-9 ↗
13. Obara T, Yokono T, Miyazawa K, Sanada Y (1981) Carbonization behavior of hydrogenated ethylene tar pitch. Carbon 19:263–267. https://doi.org/10.1016/0008-6223(81)90071-310.1016/0008-6223(81)90071-3 ↗
14. Azami K, Kato O, Takashima H, Yamamoto S, Sanada Y (1993) Effects of hydrogenation of petroleum pitch on mesophase formation. J Mater Sci 28:885–889. https://doi.org/10.1007/BF0040087010.1007/BF00400870 ↗
15. Zhang J, Guo S, Wang Y, Xie D, Liu D, Wang Z (2003) Effect of electrolytic systems on electrochemical hydrogenation of mesophase coal tar pitch. Fuel Process Technol 80:81–90. https://doi.org/10.1016/S0378-3820(02)00239-410.1016/S0378-3820(02)00239-4 ↗
16. Andrésen JM, Zhang Y, Burgess CE, Schobert HH (2004) Synthesis of pitch materials from hydrogenation of anthracite. Fuel Process Technol 85:1361–1372. https://doi.org/10.1016/S0378-3820(03)00195-410.1016/S0378-3820(03)00195-4 ↗
17. Mochida I, Okuma O, Yoon S-H (2014) Chemicals from direct coal liquefaction. Chem Rec 114:1637–1672. https://doi.org/10.1021/cr400288510.1021/cr4002885 ↗
18. Lee DH, Choi J, Oh YS, Kim YA, Yang KS, Ryu HJ, Kim YJ (2017) Catalytic hydrogenation-assisted preparation of melt spinnable pitches from petroleum residue for making mesophase pitch based carbon fibers. Carbon Lett. 24:28–35. https://doi.org/10.5714/CL.2017.24.02810.5714/CL.2017.24.028 ↗
19. Li M, Zhang Y, Yu S, Xie C, Liu D, Liu S, Zhao R, Bian B (2018) Preparation and characterization of petroleum-based mesophase pitch by thermal condensation with in-process hydrogenation. RSC Adv 8:30230–30238. https://doi.org/10.1039/C8RA04679D10.1039/C8RA04679D ↗
20. Korai Y, Yoon S-H, Oka H, Mochida I, Nakamura T, Kato I, Sakai Y (1998) The properties of Co-oligomerized mesophase pitch from methylnaphthalene and naphthalene catalyzed by HF/BF3. Carbon 36:369–375. https://doi.org/10.1016/S0008-6223(97)00181-410.1016/S0008-6223(97)00181-4 ↗
21. Kumar S, Srivastava M (2015) Catalyzing mesophase formation by transition metals. J Anal Appl Pyrolysis 112:192–200. https://doi.org/10.1016/j.jaap.2015.01.02910.1016/j.jaap.2015.01.029 ↗
22. Mochida I, Nakamura E-I, Maeda K, Takeshita K (1975) Carbonization of aromatic hydrocarbons—III: Carbonization catalyzed by alkali metals. Carbon 13:489–493. https://doi.org/10.1016/0008-6223(75)90050-010.1016/0008-6223(75)90050-0 ↗
23. Mochida I, Nakamura E-I, Maeda K, Takeshita K (1976) Carbonization of aromatic hydrocarbons—IV: Reaction path of carbonization catalyzed by alkali metals. Carbon 14:123–129. https://doi.org/10.1016/0008-6223(76)90121-410.1016/0008-6223(76)90121-4 ↗
24. Yang J, Nakabayashi K, Miyawaki J, Yoon S-H (2017) Preparation of isotropic spinnable pitch and carbon fiber by the bromination–dehydrobromination of biotar and ethylene bottom oil mixture. J Mater Sci 52:1165–1171. https://doi.org/10.1007/s10853-016-0412-810.1007/s10853-016-0412-8 ↗
25. Liu J, Shimanoe H, Choi J-E, Ko S, Jeon Y-P, Nakabayashi K, Miyawaki J, Yoon S-H (2019) Effect of the pre-treated pyrolysis fuel oil: coal tar pitch ratio on the spinnability and oxidation properties of isotropic pitch precursors and the mechanical properties of derived carbon fibers. Carbon Lett. https://doi.org/10.1007/s42823-019-00020-410.1007/s42823-019-00020-4 ↗
26. Bernhauer M, Braun M, Hüttinger KJ (1994) Kinetics of mesophase formation in a stirred tank reactor and properties of the products—V. Catalysis by ferrocene. Carbon 32:1073–1085. https://doi.org/10.1016/0008-6223(94)90217-810.1016/0008-6223(94)90217-8 ↗
27. Braun M, Kramer J, Hüttinger KJ (1995) Kinetics of mesophase formation in a stirred tank reactor and properties of the products—VI Catalysis by iron benzoate and naphthoate. Carbon 33:1359–1367. https://doi.org/10.1016/0008-6223(95)00064-K10.1016/0008-6223(95)00064-K ↗
28. Song H, Chen X, Chen X, Zhang S, Li H (2003) Influence of ferrocene addition on the morphology and structure of carbon from petroleum residue. Carbon 41:3037–3046. https://doi.org/10.1016/S0008-6223(03)00430-510.1016/S0008-6223(03)00430-5 ↗
29. Ge C, Yang H, Miyawaki J, Mochida I, Yoon S-H, Qiao W, Long D, Ling L (2015) Synthesis and characterization of high-softening-point methylene-bridged pitches by visible light irradiation assisted free-radical bromination. Carbon 95:780–788. https://doi.org/10.1016/j.carbon.2015.09.00310.1016/j.carbon.2015.09.003 ↗
30. Kim CJ, Ryu SK, Rhee BS (1993) Properties of coal tar pitch-based mesophase separated by high-temperature centrifugation. Carbon 31:833–838. https://doi.org/10.1016/0008-6223(93)90023-410.1016/0008-6223(93)90023-4 ↗
31. Feret RF (1998) Determination of the crystallinity of calcined and graphitic cokes by X-ray diffraction. Analyst 123:595–600. https://doi.org/10.1039/A707845E10.1039/A707845E ↗
32. Daniels H, Brydson R, Rand B, Brown A (2007) Investigating carbonization and graphitization using electron energy loss spectroscopy (EELS) in the transmission electron microscope (TEM). Phil Mag 87:4073–4092. https://doi.org/10.1080/1478643070139404110.1080/14786430701394041 ↗
33. Roch T, Lasagni A, Beyer E (2011) Nanosecond UV laser graphitization and delamination of thin tetrahedral amorphous carbon films with different sp3/sp2 content. Thin Solid Films 519:3756–3761. https://doi.org/10.1016/j.tsf.2011.01.33810.1016/j.tsf.2011.01.338 ↗