journal article·2024-01

Porous activated carbon derived from petroleum coke as a high-performance anodic electrode material for supercapacitors

Subir K. Pati, Yejin Hwang, Hye-Min Lee, Byung-Joo Kim, Sungjune Park

Carbon Letters· Volume 34· Issue 1
Publisher page

Abstract

In recent times, there has been a significant demand for supercapacitors in energy storage applications due to their rapid charging–discharging capabilities, high power density, and excellent stability. Nevertheless, the synthesis of electrode materials with a substantial surface area, exceptionally high porosity, and superior electrochemical performance is still challenging. Activated carbons with a distinctive porous structure and exceptional electrochemical properties emerged as promising electrode materials for supercapacitors. In this study, we used a porous activated carbon (PAC) derived from petroleum coke followed by KOH activation as an efficient anodic electrode material. The ultra-high Brunauer–Emmett–Teller surface area of 2105.6 m2 g−1 with stacked layers of carbon atoms arranged in a two-dimensional hexagonal structure makes the PAC an efficient candidate for a supercapacitor electrode. The PAC delivers a specific capacitance of 470 F g−1 at a current density of 0.5 A g−1 over a potential window of 0 to −1 V. The excellent cycling stability in a three-electrode setup with a capacitance retention of ⁓98% even at a high current density of 10 A g−1 makes the PAC a potential anodic electrode material for high-performance supercapacitor applications. Graphical abstract Petroleum coke-derived highly porous KOH-activated carbon providing an ultra-stable supercapacitor performance
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Wang Y, Liu Y, Wang D, Wang C, Guo L, Yi T (2020) Free-standing honeycomb-like N doped carbon foam derived from coal tar pitch for high-performance supercapacitor. Appl Surf Sci 506:145014. https://doi.org/10.1016/j.apsusc.2019.14501410.1016/j.apsusc.2019.145014 ↗
2. He X, Ma H, Wang J, Xie Y, Xiao N, Qiu J (2017) Porous carbon nanosheets from coal tar for high-performance supercapacitors. J Power Sources 357:41–46. https://doi.org/10.1016/j.jpowsour.2017.04.10810.1016/j.jpowsour.2017.04.108 ↗
3. Yang Y, Zuo P, Qu S (2022) Adjusting hydrophily and aromaticity strategy for pitch-based hierarchical porous carbon and its application in flexible supercapacitor. Fuel 311:122514. https://doi.org/10.1016/j.fuel.2021.12251410.1016/j.fuel.2021.122514 ↗
4. Zheng J, Wei F, Lv Y, Zhang W, Sun K (2021) 3D honeycomb-like carbons constructed by interconnected carbon nanosheets for supercapacitors. Mater Lett 291:129599. https://doi.org/10.1016/j.matlet.2021.12959910.1016/j.matlet.2021.129599 ↗
5. Wang G, Zhang L, Zhang J (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–828. https://doi.org/10.1039/C1CS15060J10.1039/C1CS15060J ↗
6. Yang X, Zhao S, Zhang Z, Chi Y, Yang C, Wang C, Zhen Y, Wang D, Fu F, Chi R (2022) Pore structure regulation of hierarchical porous carbon derived from coal tar pitch via pre-oxidation strategy for high-performance supercapacitor. J Colloid Interface Sci 614:298–309. https://doi.org/10.1016/j.jcis.2022.01.09310.1016/j.jcis.2022.01.093 ↗
7. Liu H, Song H, Hou W, Chang Y, Zhang Y, Li Y, Zhao Y, Han G (2021) Coal tar pitch-based hierarchical porous carbons prepared in molten salt for supercapacitors. Mater Chem Phys 265:124491. https://doi.org/10.1016/j.matchemphys.2021.12449110.1016/j.matchemphys.2021.124491 ↗
8. Jiang M, Sun N, Ali Soomro R, Xu B (2021) The recent progress of pitch-based carbon anodes in sodium-ion batteries. J Energy Chem 55:34–47. https://doi.org/10.1016/j.jechem.2020.07.00210.1016/j.jechem.2020.07.002 ↗
9. Daud WMAW, Ali WSW (2004) Comparison on pore development of activated carbon produced from palm shell and coconut shell. Biores Technol 93:63–69. https://doi.org/10.1016/j.biortech.2003.09.01510.1016/j.biortech.2003.09.015 ↗
10. Wang Q, Liu F, Jin Z, Qiao X, Huang H, Chu X, Xiong D, Zhang H, Liu Y, Yang W (2020) Hierarchically divacancy defect building dual-activated porous carbon fibers for high-performance energy-storage devices. Adv Func Mater 30:2002580. https://doi.org/10.1002/adfm.20200258010.1002/adfm.202002580 ↗
11. Zhang D, Zhao J, Feng C, Zhao R, Sun Y, Guan T, Han B, Tang N, Wang J, Li K, Qiao J, Zhang J (2017) Scalable synthesis of hierarchical macropore-rich activated carbon microspheres assembled by carbon nanoparticles for high rate performance supercapacitors. J Power Sources 342:363–370. https://doi.org/10.1016/j.jpowsour.2016.12.07210.1016/j.jpowsour.2016.12.072 ↗
12. Gao Z, Zhang Y, Song N, Li X (2017) Biomass-derived renewable carbon materials for electrochemical energy storage. Mater Res Lett 5:69–88. https://doi.org/10.1080/21663831.2016.125083410.1080/21663831.2016.1250834 ↗
13. Daud WMAW, Ali WSW, Sulaiman MZ (2000) The effects of carbonization temperature on pore development in palm-shell-based activated carbon. Carbon 38:1925–1932. https://doi.org/10.1016/S0008-6223(00)00028-210.1016/S0008-6223(00)00028-2 ↗
14. Ahmadpour A, Do DD (1996) The preparation of active carbons from coal by chemical and physical activation. Carbon 34:471–479. https://doi.org/10.1016/0008-6223(95)00204-910.1016/0008-6223(95)00204-9 ↗
15. Oginni O, Singh K, Oporto G, Dawson-Andoh B, McDonald L, Sabolsky E (2019) Influence of one-step and two-step KOH activation on activated carbon characteristics. Bioresour Technol Rep 7:100266. https://doi.org/10.1016/j.biteb.2019.10026610.1016/j.biteb.2019.100266 ↗
16. Rodríguez-Reinoso F, Molina-Sabio M, González MT (1995) The use of steam and CO2 as activating agents in the preparation of activated carbons. Carbon 33:15–23. https://doi.org/10.1016/0008-6223(94)00100-E10.1016/0008-6223(94)00100-E ↗
17. Hui TS, Zaini MAA (2015) Potassium hydroxide activation of activated carbon: a commentary. Carbon Lett 16:275–280. https://doi.org/10.5714/CL.2015.16.4.27510.5714/CL.2015.16.4.275 ↗
18. Elmouwahidi A, Bailón-García E, Pérez-Cadenas AF, Maldonado-Hódar FJ, Carrasco-Marín F (2017) Activated carbons from KOH and H3PO4-activation of olive residues and its application as supercapacitor electrodes. Electrochim Acta 229:219–228. https://doi.org/10.1016/j.electacta.2017.01.15210.1016/j.electacta.2017.01.152 ↗
19. Caturla F, Molina-Sabio M, Rodríguez-Reinoso F (1991) Preparation of activated carbon by chemical activation with ZnCl2. Carbon 29:999–1007. https://doi.org/10.1016/0008-6223(91)90179-M10.1016/0008-6223(91)90179-M ↗
20. Hayashi J, Kazehaya A, Muroyama K, Watkinson AP (2000) Preparation of activated carbon from lignin by chemical activation. Carbon 38:1873–1878. https://doi.org/10.1016/S0008-6223(00)00027-010.1016/S0008-6223(00)00027-0 ↗
21. Gao Y, Yue Q, Gao B, Li A (2020) Insight into activated carbon from different kinds of chemical activating agents: a review. Sci Total Environ 746:141094. https://doi.org/10.1016/j.scitotenv.2020.14109410.1016/j.scitotenv.2020.141094 ↗
22. Molina-Sabio M, Rodrı́guez-Reinoso F, (2004) Role of chemical activation in the development of carbon porosity. Colloids Surf A 241:15–25. https://doi.org/10.1016/j.colsurfa.2004.04.00710.1016/j.colsurfa.2004.04.007 ↗
23. Lillo-Ródenas MA, Juan-Juan J, Cazorla-Amorós D, Linares-Solano A (2004) About reactions occurring during chemical activation with hydroxides. Carbon 42:1371–1375. https://doi.org/10.1016/j.carbon.2004.01.00810.1016/j.carbon.2004.01.008 ↗
24. Lutfi M, Hanafi SB, Prasetyo J, Sandra PU (2021) Characteristics of activated carbon from coconut shell (Cocos nucifera) through chemical activation process. IOP Conf Ser: Earth Environ Sci 733:012134. https://doi.org/10.1088/1755-1315/733/1/01213410.1088/1755-1315/733/1/012134 ↗
25. Guan T, Zhao J, Zhang G, Zhang D, Han B, Tang N, Wang J, Li K (2018) Insight into controllability and predictability of pore structures in pitch-based activated carbons. Microporous Mesoporous Mater 271:118–127. https://doi.org/10.1016/j.micromeso.2018.05.03610.1016/j.micromeso.2018.05.036 ↗
26. Muduli S, Pati SK, Martha SK (2022) Bio-waste derived carbon nano-onions as an efficient electrode material for symmetric and lead-carbon hybrid ultracapacitors. Int J Energy Res 46:14074–14087. https://doi.org/10.1002/er.812310.1002/er.8123 ↗
27. Teo EYL, Muniandy L, Ng E-P, Adam F, Mohamed AR, Jose R, Chong KF (2016) High surface area activated carbon from rice husk as a high performance supercapacitor electrode. Electrochim Acta 192:110–119. https://doi.org/10.1016/j.electacta.2016.01.14010.1016/j.electacta.2016.01.140 ↗
28. Chandra TC, Mirna MM, Sunarso J, Sudaryanto Y, Ismadji S (2009) Activated carbon from durian shell: Preparation and characterization. J Taiwan Inst Chem Eng 40:457–462. https://doi.org/10.1016/j.jtice.2008.10.00210.1016/j.jtice.2008.10.002 ↗
29. Girgis BS, Yunis SS, Soliman AM (2002) Characteristics of activated carbon from peanut hulls in relation to conditions of preparation. Mater Lett 57:164–172. https://doi.org/10.1016/S0167-577X(02)00724-310.1016/S0167-577X(02)00724-3 ↗
30. Muduli S, Pati SK, Pani TK, Martha SK (2023) One pot synthesis of carbon decorated NiO nanorods as cathode materials for high-performance asymmetric supercapacitors. J Energy Stor 66:107339. https://doi.org/10.1016/j.est.2023.10733910.1016/j.est.2023.107339 ↗
31. Yuan M, Tong S, Zhao S, Jia CQ (2010) Adsorption of polycyclic aromatic hydrocarbons from water using petroleum coke-derived porous carbon. J Hazard Mater 181:1115–1120. https://doi.org/10.1016/j.jhazmat.2010.05.13010.1016/j.jhazmat.2010.05.130 ↗
32. Tan M, Li P, Zheng J, Noritatsu T, Wu M (2016) Preparation and modification of high performance porous carbons from petroleum coke for use as supercapacitor electrodes. New Carbon Mater 31:343–351. https://doi.org/10.1016/S1872-5805(16)60018-510.1016/S1872-5805(16)60018-5 ↗
33. Veluri PS, Katchala N, Anandan S, Pramanik M, NarayanSrinivasan K, Ravi B (2021) Petroleum coke as an efficient single carbon source for high-energy and high-power lithium-ion capacitors. Energy Fuels 35:9010–9016. https://doi.org/10.1021/acs.energyfuels.1c0066510.1021/acs.energyfuels.1c00665 ↗
34. Zhang Y, Li X, Huang J, Xing W, Yan Z (2016) Functionalization of petroleum coke-derived carbon for synergistically enhanced capacitive performance. Nanoscale Res Lett 11:163. https://doi.org/10.1186/s11671-016-1382-010.1186/s11671-016-1382-0 ↗
35. Zhang X, Tian X, Song Y, Wu J, Yang T, Liu Z (2022) Boosting Zn-ion storage capacity of pitch coke-based activated carbon via pre-oxidation assisted KOH activation strategy. Microporous Mesoporous Mater 333:111721. https://doi.org/10.1016/j.micromeso.2022.11172110.1016/j.micromeso.2022.111721 ↗
36. Xing Y, Dong Y, Zhao J, Zhang Z, Wang Y (2023) Heteroatom-doped porous carbon derived from covalent organic framework for high performance supercapacitor applications. Carbon Lett. https://doi.org/10.1007/s42823-023-00553-910.1007/s42823-023-00553-9 ↗
37. Cheng J, Lu Z, Zhao X, Chen X, Zhu Y, Chu H (2021) Electrochemical performance of porous carbons derived from needle coke with different textures for supercapacitor electrode materials. Carbon Lett 31:57–65. https://doi.org/10.1007/s42823-020-00149-710.1007/s42823-020-00149-7 ↗
38. Zhang G, Guan T, Cheng M, Wang Y, Xu N, Qiao J, Xu F, Wang Y, Wang J, Li K (2020) Harvesting honeycomb-like carbon nanosheets with tunable mesopores from mild-modified coal tar pitch for high-performance flexible all-solid-state supercapacitors. J Power Sources 448:227446. https://doi.org/10.1016/j.jpowsour.2019.22744610.1016/j.jpowsour.2019.227446 ↗
39. Lu Y, Zhao C, Qi X, Qi Y, Li H, Huang X, Chen L, Hu Y-S (2018) Pre-oxidation-tuned microstructures of carbon anodes derived from pitch for enhancing na storage performance. Adv Energy Mater 8:1800108. https://doi.org/10.1002/aenm.20180010810.1002/aenm.201800108 ↗
40. Muduli S, Pappu S, Bulusu SV, Rao TN, Martha SK (2022) Electrochemically exfoliated layered carbons as sustainable anode materials for lead carbon hybrid ultracapacitor. ChemElectroChem 9:e202200230. https://doi.org/10.1002/celc.20220023010.1002/celc.202200230 ↗
41. Bhattacharjee U, Bhar M, Bhowmik S, Martha SK (2023) Upcycling of spent lithium-ion battery graphite anodes for a dual carbon lithium-ion capacitor. Sustain Energy Fuels 7:2104–2116. https://doi.org/10.1039/D3SE00170A10.1039/D3SE00170A ↗
42. Hwang JU, Im JS, Lee JD (2023) Electrochemical property based on the structural control of pitch-based carbon anode. Kor J Chem Eng. https://doi.org/10.1007/s11814-023-1510-310.1007/s11814-023-1510-3 ↗
43. Byatarayappa G, Guna V, G RM, Venkatesh K, Zhao Y, N N, Reddy N, Nagaraju K, (2022) KOH-activated microstructured carbon derived from Asclepias syriaca floss for extraordinary 200k cycle stability in supercapacitors. Sustain Energy Fuels 6:4034–4047. https://doi.org/10.1039/D2SE00802E10.1039/D2SE00802E ↗
44. Zhu W, Shen D, Xie H (2023) Combination of chemical activation and nitrogen doping toward hierarchical porous carbon from houttuynia cordata for supercapacitors. J Energy Stor 60:106595. https://doi.org/10.1016/j.est.2022.10659510.1016/j.est.2022.106595 ↗
45. Lee J-Y, Lee H-M, Kim B-J (2023) Facile microwave treatment of activated carbons and its effects on hydrocarbon adsorption/desorption behaviors. Carbon Lett 33:1105–1114. https://doi.org/10.1007/s42823-023-00498-z10.1007/s42823-023-00498-z ↗
46. Silvestre-Albero A, Silvestre-Albero J, Martínez-Escandell M, Futamura R, Itoh T, Kaneko K, Rodríguez-Reinoso F (2014) Non-porous reference carbon for N2 (77.4K) and Ar (87.3K) adsorption. Carbon 66:699–704. https://doi.org/10.1016/j.carbon.2013.09.06810.1016/j.carbon.2013.09.068 ↗
47. Albers PW, Leich V, Ramirez-Cuesta AJ, Cheng Y, Hönig J, Parker SF (2022) The characterisation of commercial 2D carbons: graphene, graphene oxide and reduced graphene oxide. Mater Adv 3:2810–2826. https://doi.org/10.1039/D1MA01023A10.1039/D1MA01023A ↗
48. Mohapatra D, Badrayyana S, Parida S (2016) Facile wick-and-oil flame synthesis of high-quality hydrophilic onion-like carbon nanoparticles. Mater Chem Phys 174:112–119. https://doi.org/10.1016/j.matchemphys.2016.02.05710.1016/j.matchemphys.2016.02.057 ↗
49. Vargheese S, Gokila N, Kumar RS, Kumar RTR, Huh YS, Haldorai Y (2023) Covalent framework derived internal-doped porous carbon supported SnO2 composite: construction of a 10 V asymmetric supercapacitor and selective electrochemical determination of N-(4-Hydroxyphenyl) acetamide. J Alloy Compd 948:169726. https://doi.org/10.1016/j.jallcom.2023.16972610.1016/j.jallcom.2023.169726 ↗
50. Cheng J, Lu Z, Zhao X, Chen X, Liu Y (2021) Green needle coke-derived porous carbon for high-performance symmetric supercapacitor. J Power Sources 494:229770. https://doi.org/10.1016/j.jpowsour.2021.22977010.1016/j.jpowsour.2021.229770 ↗
51. Li X, Zhao L, He T, Zhang M, Wang Z, Zhang B, Weng X (2022) Highly conductive, hierarchical porous ultra-fine carbon fibers derived from polyacrylonitrile/polymethylmethacrylate/needle coke as binder-free electrodes for high-performance supercapacitors. J Power Sources 521:230943. https://doi.org/10.1016/j.jpowsour.2021.23094310.1016/j.jpowsour.2021.230943 ↗
52. Yusupov M, Bultinck E, Depla D, Bogaerts A (2011) Elucidating the asymmetric behavior of the discharge in a dual magnetron sputter deposition system. Appl Phys Lett 98:131502. https://doi.org/10.1063/1.357436510.1063/1.3574365 ↗
53. Muduli S, Pati SK, Swain S, Martha SK (2021) MoO3@ZnO Nanocomposite as an efficient anode material for supercapacitors: a cost effective synthesis approach. Energy Fuels 35:16850–16859. https://doi.org/10.1021/acs.energyfuels.1c0166510.1021/acs.energyfuels.1c01665 ↗
54. Jain A, Tripathi SK (2015) Nano-porous activated carbon from sugarcane waste for supercapacitor application. J Energy Stor 4:121–127. https://doi.org/10.1016/j.est.2015.09.01010.1016/j.est.2015.09.010 ↗