Graphene quantum dots as game-changers in solar cell technology: a review of synthetic processes and performance enhancement
Source abstract
Abstract
Graphene quantum dots (GQDs) are zero-dimensional carbonous materials with exceptional physical and chemical properties such as a tuneable band gap, good conductivity, quantum confinement, and edge effect. The introduction of GQDs in various layers of solar cells (SCs) such as hole transport layer (HTL), electron transport materials (ETM), cathode interlayer (CIL), photoanode materials (PAM), counter electrode (CE), and transparent conducting electrode (TCE) could improve the solar energy (SE) harvesting, separation and transportation of electrons and hole, thus ultimately enhance the overall performance and stability of SCs. The incorporation of GQDs in various layers such as HTL, ETM, CIL, PAM, CE, and TCE achieved photo conversion efficiencies (PCEs) of 18.63, 21.1, 12.81, 9.41, 8.1, and 3.66%, respectively. Furthermore, GQDs improved stabilities such as resistance to degradation for HTL (up to 77%), ETM (80%), resistance to UV light for ETM (94%), resistance to temperature in ETM (90%), and bending stabilities after 1000 cycles for HTL (88%) and for TCE (90%). There are reviews focused on the utilization of different carbon-structured materials such as graphene, carbon nanotubes (CNT), fullerenes, and carbon dots in SCs applications. More specifically, the utilization of GQDs for SCs is limited and yet to be explored in greater detail. This review mainly focuses on the recent advancement of various techniques of production of GQDs synthesis, utilization of GQDs in various layers like HTL, ETM, CIL, PAM, CE, and TCE for the enhancement of PCE, and the stability of SCs. As a result, we believe that an exclusive study on GQDs-sensitized solar cells (GQDSSCs) could provide an in-depth analysis of the recent progress, achievements, and challenges. Graphical abstract
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon and Quantum Dots Applications · Quantum Dots Synthesis And Properties · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Kumar JCR, Majid MA (2020) Renewable energy for sustainable development in India: current status, future prospects, challenges, employment, and investment opportunities. Energy Sustain. https://doi.org/10.1186/s13705-019-0232-110.1186/s13705-019-0232-1 ↗
2. Sathish S, Aravind KJ, Prabu D, Annam RA, Karthikeyan M, Rajasimman M, Sang WJ, Yasser V, Chongqing W (2023) Latest avenues on solar light-driven photocatalytic hydrogen generation using surface modified nanomaterials towards sustainable environment and circular bioeconomy. Fuel. https://doi.org/10.1016/j.fuel.2023.12739810.1016/j.fuel.2023.127398 ↗
3. Dada M, Popoola P (2023) Recent advances in solar photovoltaic materials and systems for energy storage applications: a review. Beni-Suef Univ J Basic Appl Sci. https://doi.org/10.1186/s43088-023-00405-510.1186/s43088-023-00405-5 ↗
4. Paul B (2019) Solar power. In: Breeze P (ed) Power generation technologies, 3rd edn. Newnes, pp 293–32110.1016/B978-0-08-102631-1.00013-4 ↗
5. Amirreza N, Zulkurnain AM, Noor AA, Hesam K, Veeramuthu A, Chawalit N, Shreeshivadasan C (2020) Effect of COVID-19 virus on reducing GHG emission and increasing energy generated by renewable energy sources: a brief study in Malaysian context. Environ Technol Innov. https://doi.org/10.1016/j.eti.2020.10115110.1016/j.eti.2020.101151 ↗
6. Hesam K, Amirreza N, Mariye J, Aldrin A, Massoomeh HM (2022) Potential effect of SARS-CoV-2 on solar energy generation: environmental dynamics and implications. Sustain Energy Technol Assess. https://doi.org/10.1016/j.seta.2022.10202710.1016/j.seta.2022.102027 ↗
7. Lucio CA, Angelo B, Piotr K, Marco L, Lisa R (2019) Silicon solar cells: toward the efficiency limits. Adv Phys X. https://doi.org/10.1080/23746149.2018.154830510.1080/23746149.2018.1548305 ↗
8. Waseem M, Adel E, Laoucine K (2022) The global semiconductor chip shortage: causes, implications, and potential remedies. IFAC-PapersOnLine. https://doi.org/10.1016/j.ifacol.2022.09.43910.1016/j.ifacol.2022.09.439 ↗
9. Daniel O, Jian Z, Ehsan S (2022) An expert-based evaluation on end-of-life solar photovoltaic management: an application of Fuzzy Delphi Technique. Sustain Horiz. https://doi.org/10.1016/j.horiz.2022.10003610.1016/j.horiz.2022.100036 ↗
10. Markana JH, Prashant KR (2022) Review on the efficiency of quantum dot sensitized solar cell: insights into photoanodes and QD sensitizers. Dyes Pigm. https://doi.org/10.1016/j.dyepig.2022.11009410.1016/j.dyepig.2022.110094 ↗
11. Jiakai Z, Qian H, Ding Y, Guofu H, Zing Z (2021) Passivating contacts for high-efficiency silicon-based solar cells: from single-junction to tandem architecture. Nano Energy. https://doi.org/10.1016/j.nanoen.2021.10671210.1016/j.nanoen.2021.106712 ↗
12. Smith DD, Cousins PJ, Masad A et al (2012) Generation III high efficiency lower cost technology: transition to full scale manufacturing. In: Proc. 38th IEEE photovoltaic specialists conf. (PVSC), Austin, Texas. https://doi.org/10.1109/PVSC.2012.631789910.1109/PVSC.2012.6317899 ↗
13. Solanki CS (2019) Solar photovoltaics fundamentals, technologies and applications. Tenth edition PHI learning private limited, India
14. Tanaka M, Taguchi M, Matsuyama T, Sawada T, Tsuda S, Nakano S, Hanafusa H, Kuwano Y (1992) Development of new a-Si c-Si heterojunction solar-cells-ACJ-HIT (artificially constructed junction-heterojunction with intrinsic thin-layer). Jpn J Appl Phys. https://doi.org/10.1143/JJAP.31.351810.1143/JJAP.31.3518 ↗
15. John FG, Ryan MF, Kevin LS, Myles AS, Andrew GN, Harvey LG, Matthew RY, Tao S, Thomas M (2020) Six-junction III–V solar cells with 47.1% conversion efficiency under 143 Suns concentration. Nat Energy. https://doi.org/10.1038/s41560-020-0598-510.1038/s41560-020-0598-5 ↗
16. Kannan N, Vakeesan D (2016) Solar energy for future world: a review. Renew Sustain Energy Rev. https://doi.org/10.1016/j.rser.2016.05.02210.1016/j.rser.2016.05.022 ↗
17. Shockley W, Queisser HJ (1961). J Appl Phys. https://doi.org/10.1063/1.173603410.1063/1.1736034 ↗
18. Fahhad HA, Sabre K (2015) Theoretical limits of photovoltaics efficiency and possible improvements by intuitive approaches learned from photosynthesis and quantum coherence. Renew Sustain Energy Rev. https://doi.org/10.1016/j.rser.2014.11.10110.1016/j.rser.2014.11.101 ↗
19. Ashoori RC (1996) Electrons in artificial atoms. Nature. https://doi.org/10.1038/379413a010.1038/379413a0 ↗
20. Alferov ZI (1998) The history and future of semiconductor heterostructures. Semiconductors 10(1134/1):1187350
21. Mônica AC (2020) Quantum dots and their applications: what lies ahead? ACS Appl Nano Mater. https://doi.org/10.1021/acsanm.0c0138610.1021/acsanm.0c01386 ↗
22. Shanmuganathan V, I-Ting C, Hsisheng T, Yuh LL (2023) High-performance carbon black-based counter electrodes for copper (I)/(II)-mediated dye-sensitized solar cells. ACS Sustain Chem Eng. https://doi.org/10.1021/acssuschemeng.3c0361110.1021/acssuschemeng.3c03611 ↗
23. Vogel R, Pohl K, Weller H (1990) Sensitization of highly porous, polycrystalline TiO2 electrodes by quantum sized CdS. Chem Phys Lett. https://doi.org/10.1016/0009-2614(90)85339-E10.1016/0009-2614(90)85339-E ↗
24. Pelayo FGDEA, Dmitri VT, Victor IK, Yasuhiko A, Manfred B, Edward HS (2021) Semiconductor quantum dots: technological progress and future challenges. Science. https://doi.org/10.1126/science.aaz854110.1126/science.aaz8541 ↗
25. Iván MS (2020) Current challenges in the development of quantum dot sensitized solar cells. Adv Energy Mater. https://doi.org/10.1002/aenm.20200177410.1002/aenm.202001774 ↗
26. Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science. https://doi.org/10.1126/science.110289610.1126/science.1102896 ↗
27. Geim A, Novoselov K (2007) The rise of graphene. Nat Mater. https://doi.org/10.1038/nmat184910.1038/nmat1849 ↗
28. Zhang Y, Tang TT, Girit C, Hao Z, Martin MC, Zettl A, Crommie MF, Shen YR, Wang F (2009) Direct observation of a widely tunable bandgap in bilayer graphene. Nature. https://doi.org/10.1038/nature0810510.1038/nature08105 ↗
29. Nair RR, Blake P, Grigorenko AN, Novoselov KS, Booth TJ, Stauber T, Peres NM, Geim AK (2008) Fine structure constant defines visual transparency of graphene. Science. https://doi.org/10.1126/science.115696510.1126/science.1156965 ↗
30. Booth TJ, Blake P, Nair RR, Jiang D, Hill EW, Bangert U, Bleloch A, Gass M, Novoselov KS, Katsnelson MI, Geim AK (2008) Macroscopic graphene membranes and their extraordinary stiffness. Nano Lett. https://doi.org/10.1021/nl801412y10.1021/nl801412y ↗
31. Pradip K, Chetna D, Neeraj D, Shiv S, Raju K, Sarika V, Archana S, Manoj KG, Surender K, Rajeev K, Avanish KS (2022) Graphene quantum dots: a contemporary perspective on scope, opportunities, and sustainability. Renew Sustain Energy Rev. https://doi.org/10.1016/j.rser.2021.11199310.1016/j.rser.2021.111993 ↗
32. Tian P, Tang L, Teng KS, Lau SP (2018) Graphene quantum dots from chemistry to applications. Mater Today Chem. https://doi.org/10.1016/j.mtchem.2018.09.00710.1016/j.mtchem.2018.09.007 ↗
33. Gong L, Yang R, Liu R, Chen L, Yan Y, Feng Z (2019) Application of graphene quantum dots in energy storage devices. Prog Chem. https://doi.org/10.7536/PC18121010.7536/PC181210 ↗
34. Yan Y, Gong J, Chen J, Zeng Z, Huang W, Kanyi P, Liu J, Chen P (2019) Recent advances on graphene quantum dots: from chemistry and physics to applications. Adv Mater. https://doi.org/10.1002/adma.20180828310.1002/adma.201808283 ↗
35. Ran C, Wang M, Gao W, Yang Z, Shao J, Deng J, Song X (2014) A general route to enhance the fluorescence of graphene quantum dots by Ag nanoparticles. RSC Adv. https://doi.org/10.1039/C4RA03542A10.1039/C4RA03542A ↗
36. Zhang Z, Zhang J, Chen N, Qu L (2012) Graphene quantum dots: an emerging material for energy-related applications and beyond. Energy Environ Sci. https://doi.org/10.1039/C2EE22982J10.1039/C2EE22982J ↗
37. Liuk G, Zhang S, Xu L, Hu Y, Li X, Zhang S, Zeng H (2022) Recent advances of eco-friendly quantum dots light-emitting diodes for display. Prog Quantum Electron. https://doi.org/10.1016/j.pquantelec2022.10041510.1016/j.pquantelec2022.100415 ↗
38. Kim A, Moon SJ, Kim JH, Patel R (2022) Review on thin-film nanocomposite membranes with various quantum dots for water treatments. J Indus Eng Chem. https://doi.org/10.1016/j.jiec.2022.11.01710.1016/j.jiec.2022.11.017 ↗
39. Karagianni A, Tsierkezos NG, Prato M, Terrones M, Kordatos KV (2023) Application of carbon-based quantum dots in photodynamic therapy. Carbon. https://doi.org/10.1016/j.carbon.2022.11.02610.1016/j.carbon.2022.11.026 ↗
40. Yuhua L, Wei Z, Weitao Z (2022) Surface chemistry of MXene quantum dots: virus mechanism-inspired mini-lab for catalysis. Chin J Catal. https://doi.org/10.1016/S1872-2067(22)64167-610.1016/S1872-2067(22)64167-6 ↗
41. Mohammad SK, Sheikh A, Mohammed ASA, Neelima G, Prashant K (2023) Understanding the theranostic potential of quantum dots in cancer management. Mater Today Commun. https://doi.org/10.1016/j.mtcomm.2023.10642410.1016/j.mtcomm.2023.106424 ↗
42. Nithya S, Kennedy R, Gunasekaran V (2012) A short review of the kinetic parameters of carbon quantum dots for electrocatalytic hydrogen evolution reaction. Int J Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2022.10.20310.1016/j.ijhydene.2022.10.203 ↗
43. Semonin OE, Luther JM, Beard MC (2012) Quantum dots for next-generation photovoltaics. Mater Today. https://doi.org/10.1016/S1369-7021(12)70220-110.1016/S1369-7021(12)70220-1 ↗
44. Ruhle S, Shalom M, Zaban A (2010) Quantum-dot-sensitized solar cells. Chem Phys Chem. https://doi.org/10.1002/cphc.20100006910.1002/cphc.201000069 ↗
45. Zhou R, Yang Z, Xu J, Cao G (2018) Synergistic combination of semiconductor quantum dots and organic-inorganic halide perovskites for hybrid solar cells. Coord Chem Rev. https://doi.org/10.1016/j.ccr.2018.07.00910.1016/j.ccr.2018.07.009 ↗
46. Zhou Y, Yang J, Luo X, Li Y, Qiu Q, Xie T (2022) Selection, preparation and application of quantum dots in perovskite solar cells. Int J Mol Sci. https://doi.org/10.3390/ijms2316948210.3390/ijms23169482 ↗
47. Zhou Y, Luo X, Yang J, Qiu Q, Xie T, Liang (2022) Application of quantum dot interface modification layer in perovsksummarised cells. Prog Perspect Nanomater. https://doi.org/10.3390/nano1212210210.3390/nano12122102 ↗
48. Ye M, Biesold GM, Zhang M, Wang W, Bai T, Lin Z (2021) Multifunctional quantum dot materials for perovskite solar cells: charge transport, efficiency and stability. Nano Today. https://doi.org/10.1016/j.nantod.2021.10128610.1016/j.nantod.2021.101286 ↗
49. Guijarro N, Yao L, Formal FL, Wells R, Liu Y, Darwich BP, Navratilova L, Cho HH, Yum JH, Sivula K (2019) Lead halide perovskite quantum dots enhance the power conversion efficiency of organic solar cells. Angewandte Chemic. https://doi.org/10.1002/anie.20190680310.1002/anie.201906803 ↗
50. Chen M, Wang J, Yin F, Du Z, Belfiorec LA, Tanga J (2021) Strategically integrating quantum dots into organic and perovskite solar cells. J Mater Chem A. https://doi.org/10.1039/DOTA11336K10.1039/DOTA11336K ↗
51. Gao N, Huang L, Li T, Song J, Hu H, Liu Y, Ramakrishna S (2019) Application of carbon dots in dye-sensitized solar cells: a review. J Appl Polym Sci. https://doi.org/10.1002/app.4844310.1002/app.48443 ↗
52. Ghosh D, Sarkar K, Devi P, Kim KH, Kumar P (2021) Current and future perspectives of carbon and graphene quantum dots: from synthesis to strategy for building optoelectronic and energy devices. Renew Sustain Energy Rev. https://doi.org/10.1016/j.rser.2020.11039110.1016/j.rser.2020.110391 ↗
53. Zheng D, Shu S, Zhi T, Jun Y (2021) Graphene quantum dots-based heterogeneous catalysts. New Carbon Mater. https://doi.org/10.1016/S1872-5805(21)60036-710.1016/S1872-5805(21)60036-7 ↗
54. Shaker M, Shahalizade T, Mumtaz A, Saznaghi HM, Javanmardi S, Gaho MA, Cao W, Hu W, Jin Z, Ge Q, Ghazvin AAS (2023) A review on the role of graphene quantum dots and carbon quantum dots in secondary-ion battery electrodes. FlatChem. https://doi.org/10.1016/j.flatc.2023.10051610.1016/j.flatc.2023.100516 ↗
55. Li Q, Fu J, Chen W, Zhang F, Cao J, Liu X (2023) Synthesis of graphene quantum dots from organic dye for the biosensor application. Carbon lett. https://doi.org/10.1007/s42823-023-00479-210.1007/s42823-023-00479-2 ↗
56. Danial WH, Mohamed NAS, Majid ZA (2022) Recent advances on the preparation and application of graphene quantum dots for mercury detection: a systematic review. Carbon Lett. https://doi.org/10.1007/s42823-021-00278-710.1007/s42823-021-00278-7 ↗
57. Prabhu SA, Kavithayeni V, Suganthy R, Geetha K (2020) Graphene quantum dots synthesis and energy application: a review. Carbon Lett. https://doi.org/10.1007/s42823-020-00154-w10.1007/s42823-020-00154-w ↗
58. Mahalingam S, Manap A, Omar A, Low FW, Afandi NF, Chia CH, Nasrudin AR (2021) Functionalized graphene quantum dots for dye-sensitized solar cell: key challenges, recent developments and future prospects. Renew Sustain Energy Rev. https://doi.org/10.1016/j.rser.2021.11099910.1016/j.rser.2021.110999 ↗
59. Verduci R, Romano VB, G, Yaghoobi N, Di A, D’Angelo G, Ciminelli C, (2022) Solar energy in space applications: review and technology perspectives. Adv Energy Mater. https://doi.org/10.1002/aenm.20220012510.1002/aenm.202200125 ↗
60. Bagher M, Vahid MMA, Mohsen M (2015) Types of solar cells and application. Am J Opt Photon. https://doi.org/10.11648/j.ajop.20150305.1710.11648/j.ajop.20150305.17 ↗
61. Avrutin V, Izyumskaya N, Morkoç H (2011) Semiconductor solar cells: recent progress in terrestrial applications. Superlattices Microstruct. https://doi.org/10.1016/j.spmi.2010.12.01110.1016/j.spmi.2010.12.011 ↗
62. Li G, Zhu R, Yang Y (2012) Polymer solar cells. Nat Photon. https://doi.org/10.1038/nphoton.2012.1110.1038/nphoton.2012.11 ↗
63. Zhu H, Wei J, Wang K, Wu D (2009) Applications of carbon materials in photovoltaic solar cells. Sol Energy Mater Sol Cells. https://doi.org/10.1109/EIT.2013.663267610.1109/EIT.2013.6632676 ↗
64. Richhariya G, Kumar A, Tekasakul P, Gupta B (2017) Natural dyes for dye sensitized solar cell: a review. Renew Sustain Energy Rev. https://doi.org/10.1016/j.rser.2016.11.19810.1016/j.rser.2016.11.198 ↗
65. Research cell efficiency records. Available online: https://www.nrel.gov/pv/assets/pdfs/best-research-cell-efficiencies.pdf. Accessed on 11 Jan 2023
66. Choubey PC, Oudhia A, Dewangan R (2012) A review: solar cell current scenario and future trends. Recent Res Sci Technol. https://doi.org/10.4236/opj.2021.11701510.4236/opj.2021.117015 ↗
67. Castaner AL, Markvart T (2012) Solar cells: materials, manufacture and operation, 2nd edn. Elsevier Ltd., Oxford, pp 3–25
68. Peng J, Liu A, Wang M (2022) Evolution of silicon wafer dimensions. J Phys Conf Ser. https://doi.org/10.1088/1742-6596/2221/1/01202510.1088/1742-6596/2221/1/012025 ↗
69. Munzer KA, Holdermann KT, Schlosser RE, Sterk S (1999) Thin monocrystalline silicon solar cells. IEEE Trans Electron Devices. https://doi.org/10.1109/16.79199610.1109/16.791996 ↗
70. Deng X, Schiff EA (2003) Amorphous silicon based solar cells. In: Luque A, Hegedus S (eds) Handbook of photovoltaic science and engineering. Wiley, Chichester
71. Shah A, Torres P, Tscharner R, Wyrsch N, Keppner H (1999) Photovoltaic technology: the case for thin-film solar cells. Science. https://doi.org/10.1126/science.285.5428.69210.1126/science.285.5428.692 ↗
72. Jeyakumar R, Singh UP (2017) Copper indium gallium selenide based solar cells—a review. Energy Environ Sci. https://doi.org/10.1039/C7EE00826K10.1039/C7EE00826K ↗
73. Yan J, Saunders BR (2014) Third-generation solar cells: a review and comparison of polymer: fullerene, hybrid polymer and perovskite solar cells. RSC Adv. https://doi.org/10.1039/C4RA07064J10.1039/C4RA07064J ↗
74. Jung HS, Park NG (2015) Perovskite solar cells: from materials to devices. Small. https://doi.org/10.1002/smll.20140276710.1002/smll.201402767 ↗
75. O’Regan B, Gratzel M (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature. https://doi.org/10.1038/353737a010.1038/353737a0 ↗
76. Mandoc M, Veurman W, Koster L, de Boer B, Blom P (2007) Origin of the reduced fill factor and photocurrent in MDMO-PPV:PCNEPV all-polymer solar cells. Adv Funct Mater. https://doi.org/10.1002/adfm.20060111010.1002/adfm.200601110 ↗
77. Chatterjee S, Jinnai S, Ie Y (2021) Nonfullerene acceptors for P3HT-based organic solar cells. J Mater Chem A. https://doi.org/10.1039/D1TA03219D10.1039/D1TA03219D ↗
78. Lu L, Yu L (2014) Understanding low bandgap polymer PTB7 and optimizing polymer solar cells based on it. Adv Mater 26(2014):4413–4430. https://doi.org/10.1002/adma.20140038410.1002/adma.201400384 ↗
79. Valentini L, Bagnis D, Marrocchi A, Seri M, Taticchi A, Kenny JM (2008) Novel anthracene-core molecule for the development of efficient PCBM-based solar cells. Chem Mater. https://doi.org/10.1021/cm703011k10.1021/cm703011k ↗
80. Fu H, Li Y, Yu J, Wu Z, Fan Q, Lin F, Woo HY, Gao F, Zhu Z, Alex KYJ (2021) High efficiency (158%) all-polymer solar cells enabled by a regioregular narrow bandgap polymer acceptor. J Am Chem Soc. https://doi.org/10.1021/jacs.0c1252710.1021/jacs.0c12527 ↗
81. Hoppe H, Sariciftci NS (2004) Organic solar cells: an overview. J Mater Res. https://doi.org/10.1557/JMR.2004.025210.1557/JMR.2004.0252 ↗
82. Kim HS, Lee CR, Im JH et al (2012) Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci Rep. https://doi.org/10.1038/srep0059110.1038/srep00591 ↗
83. Lee JW, Seol DJ, Cho AN, Park NG (2014) High-efficiency perovskite solar cells based on the black polymorph of HC-(NH2)2PbI3. Adv Mater. https://doi.org/10.1002/adma.20140113710.1002/adma.201401137 ↗
84. Kojima A, Teshima K, Shirai Y, Miyasaka T (2009) Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J Am Chem Soc. https://doi.org/10.1021/ja809598r10.1021/ja809598r ↗
85. Sahli F, Werner J, Kamino BA et al (2018) Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency. Nat Mater. https://doi.org/10.1038/s41563-018-0115-410.1038/s41563-018-0115-4 ↗
86. Prabhagar VM, Kumar MP, Takahashi C, Kundu S, Narayanan TN, Pattanayak DK (2019) Boron-doped graphene quantum dots: an efficient photoanode for a dye sensitized solar cell. New J Chem. https://doi.org/10.1039/C9NJ00052F10.1039/C9NJ00052F ↗
87. Dinari M, Momeni MM, Goudarzirad M (2016) Dye-sensitized solar cells based on nanocomposite of polyaniline/graphene quantum dots. J Mater Sci. https://doi.org/10.1007/s10853-015-9605-910.1007/s10853-015-9605-9 ↗
88. Wu CS, Chang TW, Teng H, Lee YL (2016) High performance carbon black counter electrodes for dye-sensitized solar cells. Energy. https://doi.org/10.1016/j.energy.2016.09.05210.1016/j.energy.2016.09.052 ↗
89. Zhang J, Long H, Miralles SG, Bisquert J, Fabregat-Santiago F, Zhang M (2012) The combination of a polymer–carbon composite electrode with a high-absorptivity ruthenium dye achieves an efficient dye-sensitized solar cell based on a thiolate–disulfide redox couple. Phys Chem Chem Phys. https://doi.org/10.1039/C2CP40809K10.1039/C2CP40809K ↗
90. Lee KM, Chen PY, Hsu CY, Huang JH, Ho WH, Chen HC, Ho KC (2009) A high-performance counter electrode based on poly(3,4-alkylenedioxythiophene) for dye-sensitized solar cells. J Power Sources. https://doi.org/10.1016/j.jpowsour.2008.11.07510.1016/j.jpowsour.2008.11.075 ↗
91. Michael G (2003) Dye-sensitized solar cells. J Photochem Photobiol C Photochem Rev. https://doi.org/10.1016/S1389-5567(03)00026-110.1016/S1389-5567(03)00026-1 ↗
92. Takpire S Fourth generation polymer solar cells, chapter 10. Recent Research at the Intersection of Science & Technology. ISBN: 978-93-91768-30-0
93. Bacon M, Bradley SJ, Nann T (2014) Graphene quantum dots. Part Syst Charact 31:415–428. https://doi.org/10.1002/ppsc.20130025210.1002/ppsc.201300252 ↗
94. Danial WH, Norhisham NA, Noorden AFA, Majid ZA, Matsumura K, Iqbal A (2021) A short review on electrochemical exfoliation of graphene and graphene quantum dots. Carbon Lett. https://doi.org/10.1007/s42823-020-00212-310.1007/s42823-020-00212-3 ↗
95. Pan D, Zhang J, Li Z, Wu M (2010) Hydrothermal route for cutting graphene sheets into blue-luminescent graphene quantum dots. Adv Mater. https://doi.org/10.1002/adma.20090282510.1002/adma.200902825 ↗
96. Chong Y, Ma Y, Shen H, Tu X, Zhou X, Xu J, Dai J, Fan S, Zhang Z (2014) The in vitro and in vivo toxicity of graphene quantum dots. Biomaterials. https://doi.org/10.1016/j.biomaterials.2014.03.02110.1016/j.biomaterials.2014.03.021 ↗
97. Ponomarenko LA, Schedin F, Katsnelson MI, Yang R, Hill EW, Novoselov KS, Geim AK (2008) Chaotic dirac billiard in graphene quantum dots. Science. https://doi.org/10.1126/science.115466310.1126/science.1154663 ↗
98. Sun Y, Wang S, Li C, Luo P, Tao L, Wei Y, Shi G (2013) Large scale preparation of graphene quantum dots from graphite with tunable fluorescence properties. Phys Chem Chem Phys. https://doi.org/10.1039/C3CP50691F10.1039/C3CP50691F ↗
99. Dong Y, Chen C, Zheng X, Gao L, Cui Z, Yang H, Guo C, Chi Y, Li CM (2012) One-step and high yield simultaneous preparation of single- and multi-layer graphenequantum dots from CX-72 carbon black. J Mater Chem. https://doi.org/10.1039/C2JM30658A10.1039/C2JM30658A ↗
100. Peng J, Gao W, Gupta BK, Liu Z, Romero AR, Ge L, Song L, Alemany LB, Zhan X, Gao G, Vithayathil SA, Kaipparettu BA, Marti AA, Takuya H, Zhu JJ, Ajayan PM (2012) Graphene quantum dots derived from carbon fibers. Nano Lett. https://doi.org/10.1021/nl203897910.1021/nl2038979 ↗