journal article·2024-01

Photocatalytic degradation of tetracycline with Fe3O4/g-C3N4/TiO2 catalyst under visible light

Rui Liu, Xin Zhang, Xue Han, Yuan Sun, Shuang Jin, Ri-jia Liu

Carbon Letters· Volume 34· Issue 1
Publisher page

Abstract

Fe3O4/g-C3N4/TiO2 catalyst has been fabricated using a simple ultrasonic method with high photocatalytic activity. The morphology, structure and optical properties of Fe3O4/g-C3N4/TiO2 were systematically investigated by a variety of characterization techniques. The optimum degradation conditions were investigated by degrading tetracycline (TC) under visible light irradiation. The results showed that the degradation efficiency was the highest when the initial TC concentration was 5.0 mg/L, the pH value was 11 and the catalyst dosage was 1.0 g/L. After 100 min of visible light irradiation, the degradation efficiency of TC achieved at 73.61%, which was 1.64 and 1.19 times that of g-C3N4 and Fe3O4/g-C3N4, respectively. Moreover, Fe3O4/g-C3N4/TiO2 had good stability and recyclability. The results of capture experiments showed that ‧O2− and ‧OH were the main active species during the photocatalytic process, and a possible photocatalytic reaction mechanism of Fe3O4/g-C3N4/TiO2 catalyst was proposed. This study provides a new way to improve the photocatalytic performance of g-C3N4, which has great potential in degrading pollutants such as antibiotics in wastewater.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Advanced Nanomaterials in Catalysis · TiO2 Photocatalysis and Solar Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Syed ARK, Pablo P, Zhang Y et al (2022) Environmental technology and wastewater treatment: strategies to achieve environmental sustainability. J Chemosphere 286:1–10
2. Awanthi W, Indika H, Iqbal MCM et al (2019) Mechanistic understanding of crystal violet dye sorption by woody biochar: implications for wastewater treatment. J Environ Geochem Hlth 41(4):1647–166110.1007/s10653-017-0013-8 ↗
3. Abirami B, Sri BKK, Chitra K (2020) Assessment on biodegradability prediction of tannery wastewater using EPI Suite BIOWIN model. J Environ Monit Assess 192(11):1–9
4. Oscar MR, Alain RP, Nelson B et al (2021) Electrochemical oxidation technology to treat textile wastewaters. J Curr Opin Electroche 19:29–42
5. Achisa CM, Martha NC (2020) Photocatalytic ozonation of wastewater: a review. J Environ Chem Lett 188(32):1–17
6. Xie XH, Liu N, Yang F et al (2018) Comparative study of antiestrogenic activity of two dyes after Fenton oxidation and biological degradation. J Ecotox Environ Safe 164:416–42410.1016/j.ecoenv.2018.08.012 ↗
7. Muhammad S, Majid M, Atta H et al (2021) Photocatalysis: an effective tool for photodegradation of dyes-a review. J Environ Sci Pollut R 132:293–311
8. Martin DJ, Reardon PJT, Moniz SJA et al (2014) Visible light-driven pure water splitting by a nature-inspired organic semiconductor-based system. J JACS 136(36):1568–1571
9. Anise A, Aziz HY (2016) Facile preparation of novel quaternary g-C3N4/Fe3O4/AgI/Bi2S3 nanocomposites: magnetically separable visible-light-driven photocatalysts with significantly enhanced activity. J RSC Adv 6(108):572–583
10. Zhang JS, Zhang MW, Lin S et al (2014) Molecular doping of carbon nitride photocatalysts with tunable band gap and enhanced activity. J J Catal 310:24–3010.1016/j.jcat.2013.01.008 ↗
11. Gong YT, Zhang PF, Xu X et al (2013) A novel catalyst Pd@ompg-C3N4 for highly chemoselective hydrogenation of quinoline under mild conditions. J J Catal 297:272–28010.1016/j.jcat.2012.10.018 ↗
12. Li XG, Bi WT, Zhang L et al (2016) Single-atom Pt as co-catalyst for enhanced photocatalytic H2 evolution. J Adv Mater 28:2427–243110.1002/adma.201505281 ↗
13. Mitra M, Aziz HY (2017) Novel magnetically separable g-C3N4/Fe3O4/Ag3PO4/Co3O4 nanocomposites: visible-light-driven photocatalysts with highly enhanced activity. J Adv Powder Technol 28:1540–155310.1016/j.apt.2017.03.025 ↗
14. Chen L, Ma W, Dai JD et al (2016) Facile synthesis of highly effiffifficient graphitic-C3N4/ZnFe2O4 heterostructures enhanced visible-light photocatalysis for spiramycin degradation. J J Photoch Photobio A 328:24–3210.1016/j.jphotochem.2016.04.026 ↗
15. Wei XN, Wang HL (2018) Preparation of magnetic g-C3N4/Fe3O4/TiO2 photocatalyst for visible light photocatalytic application. J J Alloy Compd 763:844–85310.1016/j.jallcom.2018.06.031 ↗
16. Lei J, Chen B, Lv W, Zhou L, Wang L, Liu Y, Zhang J (2019) An inverse opal TiO2/g-C3N4 composite with a heterojunction for enhanced visible light-driven photocatalytic activity. J Dalton Trans 48:3486–349510.1039/C8DT04496A ↗
17. Bashir H, Yi X, Yuan J et al (2019) Highly ordered TiO2 nanotube arrays embedded with g-C3N4 nanorods for enhanced photocatalytic activity. J J Photoch Photobio A 382:11193010.1016/j.jphotochem.2019.111930 ↗
18. Mei P, Wang H, Guo H, Zhang J et al (2020) The enhanced photodegradation of bisphenol A by TiO2/C3N4 composites. J Environ Res 182:10909010.1016/j.envres.2019.109090 ↗
19. Mitra M, Aziz HY (2016) Novel magnetically separable g-C3N4/Fe3O4/Ag3VO4/Ag2CrO4 nanocomposites as efficient visible-light-driven photocatalysts for degradation of water pollutants. J J Mater Sci-Mater El 27(8):8532–854510.1007/s10854-016-4870-1 ↗
20. Liu L, Liu J, Zhao L, Yang Z, Lv C, Xue J, Tang A (2019) Synthesis and characterization of magnetic Fe3O4@CaSiO3 composites and evaluation of their adsorption characteristics for heavy metal ions. J Environ Sci Pollut Res Int 26(9):8721–873610.1007/s11356-019-04352-6 ↗
21. Guan S, Wu H, Yang L, Wang Z, Wu J (2020) Use of a magnetic covalent organic framework material with a large specific surface area as an effective adsorbent for the extraction and determination of six fluoroquinolone antibiotics by HPLC in milk sample. J Sep Sci 43(19):3775–378410.1002/jssc.202000616 ↗
22. Ali A, Raza T, Ahmed A et al (2022) Facile synthesis of magnetically separable Fe3O4/GO/g-C3N4 composite for superior photocatalytic degradation of naphthalene. J Synthetic Met 287:11707210.1016/j.synthmet.2022.117072 ↗
23. Meng Z, Zhou B, Jian XU et al (2020) Heterostructured nitrogen and sulfur co-doped black TiO2/g-C3N4 photocatalyst with enhanced photocatalytic activity. J Chem Res Chin U 36(6):8
24. Mehmet LY, Necip A (2019) Development of molecular imprinted sensor including graphitic carbon nitride/N-doped carbon dots composite for novel recognition of epinephrine. J Compos Part B-Eng 175:113–127
25. Liu R, Han X, Liu RJ et al (2022) Highly selective photodegradation of ciprofloxacin by molecularly imprinted Fe3O4/g-C3N4. J Mater Lett 325:132–13610.1016/j.matlet.2022.132811 ↗
26. Chen T, Zhong L, Yang Z et al (2020) Enhanced visible-light photocatalytic activity of g-C3N4/nitrogen-doped graphene quantum dots/TiO2 ternary heterojunctions for ciprofloxacin degradation with narrow band gap and high charge carrier mobility. J Chem Res Chin U 36(6):8
27. Zhu Z, Tang X, Fan WQ et al (2019) Studying of Co-doped g-C3N4 and modified with Fe3O4 quantum dots on removing tetracycline. J Alloy Compd 775:248–25810.1016/j.jallcom.2018.10.056 ↗
28. Jiang W, Zong X, Wang X et al (2020) Transparent coating with TiO2 Nanorods for high-performance photocatalytic self-cleaning and environmental remediation. J Chem Res Chin U 36(6):1–5
29. Wang C, Hu L, Chai B et al (2018) Enhanced photocatalytic activity of electrospun nanofibrous TiO2 /g-C3N4 heterojunction photocatalyst under simulated solar light. J Appl Surf Sci 430:243–25210.1016/j.apsusc.2017.08.036 ↗
30. Cui Y, Briscoe J, Wang Y et al (2017) Enhanced photocatalytic activity of heterostructured ferroelectric BaTiO3/α-Fe2O3 and the significance of interface morphology control. J ACS Appl Mater Interfaces Acsami. https://doi.org/10.1021/acsami.7b0352310.1021/acsami.7b03523 ↗
31. Liu R, Bie Y, Qiao Y et al (2019) Design of g-C3N4/TiO2 nanotubes heterojunction for enhanced organic pollutants degradation in waste water. J Mater Lett 251(15):126–13010.1016/j.matlet.2019.05.065 ↗
32. Giovanni DL, Sergio T, Gianfranco P (2021) Z-Scheme versus type-II junction in g-C3N4/TiO2 and g-C3N4/SrTiO3/TiO2 heterostructures. J Catal Sci Technol 11(10):3589–359810.1039/D1CY00451D ↗
33. Liu R, Sun L, Qiao Y et al (2020) Efficient photocatalytic degradation of pharmaceutical pollutants using plasma-treated g-C3N4/TiO2. J Enegy Technol-Ger. https://doi.org/10.1002/ente.20200009510.1002/ente.202000095 ↗
34. Xu SN, Chen LG, Ma L (2018) Fluorometric determination of quercetin by using graphitic carbon nitride nanoparticles modified with a molecularly imprinted polymer. J Mikrochim Acta 185(10):1–9
35. Peng JY, Huang G (2019) Selective photocatalytic degradation of tetracycline by metal-free heterojunction surface imprinted photocatalyst based on magnetic fly ash J. Inorg Chem Commun 106:202–21010.1016/j.inoche.2019.06.012 ↗