journal article·2026-07

Synergistic dual-conduction networks enable superior ablation resistance and thermal management in C/C-(Zr0.25Hf0.25Ti0·25Ta0.25)C-SiC composites

Yixin Zhao, Xiaxiang Zhang, Lei Chen, Xiao Luo, Xin Yang, Qizhong Huang

Carbon· Volume 258
Publisher page

Abstract

The C/C-(Zr0.25Hf0.25Ti0.25Ta0.25)C (ZHTTC)-SiC composites with excellent thermal conductivities were designed and modified with mesophase pitch based carbon fiber (CFMP) and different carbon sources for matrix farbication. The carbon matrices and ZHTTC powders originated from mesophase pitch (MP) and polyimide (PI) carbon source respectively presented different microstructures. The dual-conduction network formed by CFMP and MP based matrix endowed the CMP/CMP-ZHTTCM-SiC composites with outstanding thermal conductivity, reaching 79.79 W/(m·K) in the in-plane (XY) direction. Remarkably, a surface temperature reduction of 100.3 °C was achieved during ablation, resulting in compact oxide layer formation and enhanced ablation resistance and a significantly reduced linear and mass ablation rate of 10.22 μm/s and 3.28 mg/s was achieved respectively.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Thermal properties of materials · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. The laser ablation property, microstructure and mechanism of C/C composites with smooth and rough laminar pyrocarbon in different direction
2. Research progress on ultrahigh-temperature ceramics modified C/C composites10.3390/ma18163891 ↗
3. Morphology-driven Cu gradient distribution induces varied anti-ablation performance in C/C–ZrC composites10.1016/j.carbon.2025.121063 ↗
4. Advanced anti-ablation C/C composites: structural design strategies and future perspective10.1016/j.mattod.2024.09.004 ↗
5. Materials design of silicon based ceramic coatings for high temperature oxidation protection
6. Local anti-ablation modification of uneven-density C/C composites with the ZrC-SiC composite ceramics
7. Si3N4 coatings as a novel alternative to SiC for oxidation protection of C/C composites10.1016/j.ceramint.2025.06.205 ↗
8. SiC/HfB2-based ceramic/SiC multilayer coating to protect C/C composites against oxidation at medium and high temperatures for long-life service10.1016/j.corsci.2022.110299 ↗
9. Ablation behavior of (ZrC/SiC)3 alternate coating prepared on sharp leading edge C/C composites by CVD10.1016/j.jmst.2021.10.049 ↗
10. (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics with low thermal conductivity10.1111/jace.15779 ↗
11. Pressureless sintering and properties of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics: the effect of pyrolytic carbon10.1016/j.jeurceramsoc.2021.01.048 ↗
12. Adjustable negative permittivity behavior of high entropy (Ti 0.25 Zr 0.25 Nb 0.25 Ta 0.25)C ceramics with different sintering temperatures10.1016/j.jeurceramsoc.2024.117178 ↗
13. Effect of carbon content on the microstructure and mechanical properties of high-entropy (Ti0.2Zr0.2Nb0.2Ta0.2Mo0.2)Cx ceramics10.1016/j.jeurceramsoc.2021.10.019 ↗
14. Stability, mechanical, and thermodynamic behaviors of (TiZrHfTaM)C (M = Nb, Mo, W, V, Cr) high-entropy carbide ceramics
15. In-situ preparation of high entropy ceramics joints for C/C composites by spark plasma sintering
16. Insights into high entropy ceramics under extreme conditions: ablation behavior and microstructure evolution of C/C-(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2) C composites10.1016/j.jeurceramsoc.2025.117616 ↗
17. Ablation-resistant Y2O3-modified (Hf0.2Ta0.2Zr0.2Ti0.2Nb0.2)C high entropy ceramics in oxyacetylene flame above 2100 °C10.1016/j.jeurceramsoc.2025.117723 ↗
18. Synthesis of ultra-fine hafnium carbide powder and its pressureless sintering10.1111/j.1551-2916.2009.03531.x ↗
19. Imperfection of carbon sublattice: effect on the properties of refractory carbides of transition metals10.1007/s11106-008-0004-5 ↗
20. Influence of novel carbon sources on microstructure and properties of (Ti0.2Zr0.2Hf0.2Ta0.2Nb0.2)C high-entropy carbide ceramic10.1016/j.jeurceramsoc.2023.11.023 ↗
21. ZrB2 powders prepared by boro/carbothermal reduction of ZrO2: the effects of carbon source and reaction atmosphere10.1016/j.powtec.2011.11.002 ↗
22. Preparation and thermal conductivity of C/C composites filled with diamond particles10.1016/j.diamond.2018.07.002 ↗
23. Study on the ablation performance of SiC-coated high thermal conductivity three-dimensional C/C composites10.1016/j.jeurceramsoc.2023.12.079 ↗
24. Graphene-modified C/C composites for enhanced directional thermal conductivity10.1016/j.jmrt.2025.04.089 ↗
25. A great leap in ablative protection of SiC-coated sharp leading edge: advanced 2.5D C/C composites with high thermal conductivity10.1016/j.jeurceramsoc.2025.117407 ↗
26. Development and properties of high thermal conductivity molybdenum carbide - graphite composites10.1016/j.carbon.2018.04.010 ↗
27. Enhanced thermal and structural performance of mesophase pitch-based C/C-SiC composites via pyrolytic graphite matrix modification10.1016/j.ceramint.2025.01.254 ↗
28. High-performance carbon/carbon composites with enhanced thermal conductivity via polyacrylonitrile fiber and pyrolytic carbon synergies
29. Development of the graphite crystal contributing to the thermal performance of high-thermal-conductive C/C composites10.1016/j.ceramint.2023.11.317 ↗
30. The improvement on ablative properties of 1D high thermal conductivity carbon/carbon composites by constructing heterogeneous layered preforms10.1016/j.ceramint.2025.09.285 ↗
31. Microstructure and property evolution of CMP/C composites dominated by ultra-high-temperature graphitization at 3000 °C
32. Ablative property and mechanism of pitch-based carbon fiber modified C/C composites with high thermal conductivity10.1016/j.ceramint.2024.10.147 ↗
33. Effect of high temperature treatment on the structure and thermal conductivity of 2D carbon/carbon composites with a high thermal conductivity10.1016/S1872-5805(14)60142-6 ↗
34. Structure evolution and degradation mechanism of compressive strength for (Zr0.25Hf0.25Ti0.25Ta0.25)C high-entropy ceramics with ultra-strength of 3.62 GPa10.1016/j.jallcom.2023.171484 ↗
35. Synthesis and characterization of in situ grown carbon nanofiber/nanotube reinforced carbon/carbon composites10.1016/j.carbon.2005.04.024 ↗
36. Three-dimensional carbon/carbon composites with vertically aligned carbon nanotubes: providing direct and indirect reinforcements to the pyrocarbon matrix10.1016/j.matdes.2015.12.036 ↗
37. Study on removal mechanism and edge breakage of C/C composites in orthogonal cutting10.1016/j.jmapro.2025.02.064 ↗
38. Laser ablation behavior of C/SiC composites subjected to transverse hypersonic airflow10.1016/j.corsci.2021.109345 ↗
39. Ablation behavior of Cf/ZrC-SiC-based composites fabricated by an improved reactive melt infiltration10.1016/j.jeurceramsoc.2019.07.007 ↗
40. Fabrication and performance of micro-diamond modified C/SiC composites via precursor impregnation and pyrolysis process10.1016/j.ceramint.2018.02.185 ↗
41. A new strategy to improve the ablation resistance of C/C-ZrC-SiC composites by using mesophase-pitch-based carbon fibers as heat transfer channels10.1016/j.ceramint.2024.12.441 ↗
42. Effect of (Ti, Zr, Hf)C medium-entropy and (Ti, Zr, Hf, Ta)C high-entropy modification on microstructure and ablative properties of C/C-SiC composites10.1016/j.matchar.2025.114952 ↗
43. Novel refractory high-entropy ceramics: transition metal carbonitrides with superior ablation resistance10.1016/j.corsci.2021.109359 ↗
44. Thermal conductivities of plain woven C/SiC composite: micromechanical model considering PyC interphase thermal conductance and manufacture-induced voids10.1016/j.compstruct.2018.03.030 ↗
45. Ablation resistance of SiC-modified ZrC coating prepared by SAPS for SiC-coated carbon/carbon composites10.1111/ijac.12645 ↗
46. Compound and solid-solution formation, phase equilibria and electrical properties in the ceramic system ZrO2-La2O3-Ta2O510.1039/JM9910100163 ↗
47. In situ determination of the HfO2-Ta2O5-temperature phase diagram up to 3000 °C
48. Advances in oxidation and ablation resistance of high and ultra-high temperature ceramics modified or coated carbon/carbon composites10.1016/j.jeurceramsoc.2017.08.013 ↗
49. Design, preparation and properties of carbon fiber reinforced ultra-high temperature ceramic composites for aerospace applications: a review10.1016/j.jmst.2016.08.004 ↗
50. The ZrO2-TiO2 phase diagram10.1007/s10853-005-1116-7 ↗