Characterization and dispersion of carbon spheres modified by HNO3/H2O2 oxidization in water

Carbon spheres (CSs) were modified by a mixture of HNO3 and H2O2 with different volume ratios and concentrations to improve their dispersability in a liquid. The morphologies and microstructures of the modified CSs were characterized by field emission scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectrometry and acid–base titration. Results show that the amount and types of oxygen-containing groups can be tuned by the concentration and ratio of HNO3/H2O2.HNO3favors the formation of carboxyl and carbonyl groups while H2O2 introduces mainly hydroxyl. The amount of oxygen-containing functional groups increases with the concentration of the oxidants when the volume ratio of HNO3/H2O2 is 1, which is as high as 2.164 mmol/g when the concentrations of HNO3 and H2O2 are 16 and 8.8 M, respectively. The resulting CSs have a remarkable dispersability and stability in water. [New Carbon Materials 2013, 28(3): 228–234]