A kinetic model of the first intercalation of graphite
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References (37)
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26. This assumption implies that the system does not progressively go through different stages on the way to a given stage. This implication is supported by X-ray diffraction results [25, 26] with bromine, which showed no evidence for any stage other than the saturated second stage and a virgin region in a sample undergoing vapor phase intercalation to a saturated compound. Marchand et al. [15] also came to the same conclusion from their study of the variation of the magnetic anisotrophy with temperature. However, this is known to be not true in the case of nitration [19,26], where a given stage is reached through a succession of higher stages. In our opinion, this characteristic of HNO3 intercalation complicates the description of the kinetics of intercalation in terms of simple diffusion.
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