Three nanostructured graphitic particles and their growth mechanisms from high-temperature carbon vapor confined by Ar gas

CO 2 laser vaporization of graphite was carried out in the presence of high pressure Ar gas up to 0.8 MPa. We compared transmission electron microscope images and Raman spectra of deposited particles and luminous laser plumes of vaporized and clustered carbon species. We discuss the growth mechanisms of three graphitic carbon particles, a single-wall carbon nanohorn aggregate, a platelet graphite particle, and a polyhedral graphite particle, grown depending on the confinement of the Ar atmosphere. The formation of graphitic sheet or shell structures, dependent on resident carbon densities and their temperature gradient, is thought to begin from supersaturated hot carbon vapor up to about 3000 °C and leads to the growth of the three graphitic particles.