journal article·2017-04

Exchange bias in graphitic C/Co composites

Hua-Shu Hsu, Yu-Ying Chang, Yi-Ying Chin, Hong-Ji Lin, Chien-Te Chen, Shih-Jye Sun, Sergey M. Zharkov, Chun-Rong Lin, Sergey G. Ovchinnikov

Carbon· Volume 114
Publisher page

Abstract

The exchange bias (EB) effect, which is the shift of the hysteresis loop of a ferromagnet in direct contact with an antiferromagnet, is highly advantageous for the development of spintronics applications. Carbon (C) has been considered as a potential material in next generation electronics production as well as spintronics devices beyond silicon. Here we show experimental evidence for an EB in C/Co composites. The significant EB needs thermal annealing to occur. X-ray absorption spectra and transmission electron microscopy data of these samples reveal that Co carbides in as grown samples decompose and form graphitic C/Co interfaces after annealing. Using x-ray magnetic circular dichroism we have detected the C spins that are responsible for the EB. These results inspire a theoretical model to investigate the magnetic interactions in graphitic C/Co interfaces and interpret the observed results.
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Research context

OpenAlex topics: Magnetic properties of thin films · Advancements in Battery Materials · Graphene research and applications

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References (54)

Show source-provided references
2. Exchange anisotropy-a review10.1016/S0304-8853(99)00453-9 ↗
3. Exchange bias effect of ferro-/antiferromagnetic heterostructures10.1007/978-3-540-73462-8_3 ↗
4. Enhanced magnetoresistance in layered magnetic structures with antiferromagnetic interlayer exchange10.1103/PhysRevB.39.4828 ↗
5. Perpendicular exchange bias in ferromagnetic spin valves10.1038/ncomms1728 ↗
6. Enhanced room-temperature positive magnetoresistance of a-C: Fe films10.1016/j.carbon.2007.05.005 ↗
7. A bias voltage dependent positive magnetoresistance in Cox–C1−x/Si heterostructure10.1063/1.3179152 ↗
8. Positive colossal magnetoresistance observed in Co doped amorphous carbon/silicon heterostructures10.1063/1.4765648 ↗
9. Observation of bias-dependent low field positive magneto-resistance in Co-doped amorphous carbon films10.1063/1.3467044 ↗
10. High spin polarization induced by the interface hybridization in Co/C composite films10.1016/j.carbon.2012.05.025 ↗
11. Graphene as a tunnel barrier: graphene-based magnetic tunnel junctions10.1021/nl3007616 ↗
12. Possible room-temperature ferromagnetism in hydrogenated carbon nanotubes10.1103/PhysRevB.81.115461 ↗
13. Homoepitaxial tunnel barriers with functionalized graphene-on-graphene for charge and spin transport10.1038/ncomms4161 ↗
14. Hydrogenated graphene as a homoepitaxial tunnel barrier for spin and charge transport in graphene10.1021/acsnano.5b02795 ↗
15. Theoretical prediction of perfect spin filtering at interfaces between close-packed surfaces of Ni or Co and graphite or graphene10.1103/PhysRevB.78.195419 ↗
16. Substrate effects: disappearance of adsorbate-induced magnetism in graphene10.1103/PhysRevB.89.035404 ↗
17. Electronic and magnetic properties of the graphene–ferromagnet interface
18. Atomic-scale interfacial magnetism in Fe/Graphene heterojunction
19. Spin-polarized electron transfer in ferromagnet/C60 interfaces10.1103/PhysRevB.90.125311 ↗
20. Room temperature ferromagnetism in Co-doped amorphous carbon composites from the spin polarized semiconductor band
21. Tunable interface magnetic-optical properties of Co doped amorphous carbon film induced by charge transfer after acid treatment10.1016/j.carbon.2014.05.043 ↗
22. Two interface effect: exchange bias and magnetic proximity10.1016/j.physrep.2013.10.002 ↗
23. Diamond like amorphous carbon10.1016/S0927-796X(02)00005-0 ↗
24. Magnetic thin film of cobalt nanocrystals encapsulated in graphite-like carbon10.1038/381772a0 ↗
25. Crystallization of amorphous carbon thin film in the presence of magnetic media10.1063/1.369334 ↗
26. Effect of annealing on the structure and magnetic properties of graphite encapsulated nickel and cobalt nanocrystals10.1063/1.366760 ↗
27. Metal-catalyzed crystallization of amorphous carbon to graphene10.1063/1.3318263 ↗
28. Highly stable carbon-protected cobalt nanoparticles and graphite shells10.1039/B414146F ↗
29. High pressure phases in nanocrystalline Co(C) films obtained by pulsed plasma vaporization10.1134/1.1328446 ↗
30. High coercivity cobalt carbide nanoparticles processed via polyol reaction: a new permanent magnet material10.1088/0022-3727/43/16/165003 ↗
31. Sizeable magnetic circular dichroism of artificially precipitated Co clusters in amorphous carbon
32. Connection between orbital moment enhancement and exchange bias in a [Ni80Fe20/Mn]3 multilayer
33. Magnetic properties of monodispersed Co/CoO clusters10.1103/PhysRevB.61.3103 ↗
34. Electronic structure and magnetic properties of graphene/Co composites10.1016/j.carbon.2015.04.086 ↗
35. Exchange-biased Py/CoO vortex structures: magnetization reversal, cooling-field dependence, and training10.1103/PhysRevB.94.134422 ↗
36. Bunker · 2010
37. Local structure of Co nanocrystals embedded in hydrogenated amorphous carbon: an x-ray absorption study10.1063/1.1513198 ↗
38. Spin and orbital magnetic moments in carbon-encapsulated Fe50Pt50 nanoparticles10.1103/PhysRevB.76.104421 ↗
39. Total electron yield soft X-ray absorption spectroscopy in the C K region of the mixtures of graphitic carbons and diamond for quantitative analysis of the sp2/sp3-hybridized carbon ratio
40. Local electronic structure and magnetic properties of LaMn0.5Co0.5O3 studied by x-ray absorption and magnetic circular dichroism spectroscopy10.1103/PhysRevB.77.125124 ↗
41. Experimental confirmation of the XMCD sum rules for iron and cobalt10.1103/PhysRevLett.75.152 ↗
42. Direct observation of rotatable uncompensated spins in the exchange bias system Co/CoO–MgO10.1039/c3nr02013d ↗
43. Ferromagnetism induced by clustered Co in Co-doped anatase TiO2 thin films
44. X-ray circular dichroism as a probe of orbital magnetization10.1103/PhysRevLett.68.1943 ↗
45. X-ray circular dichroism and local magnetic fields10.1103/PhysRevLett.70.694 ↗
46. Branching ratio in x-ray absorption spectroscopy10.1103/PhysRevB.38.3158 ↗
47. Linear relation between x-ray absorption branching ratio and valence-band spin-orbit expectation value10.1103/PhysRevA.38.1943 ↗
48. Local probe for spin-orbit interaction10.1103/PhysRevLett.60.1977 ↗
49. Temperature dependence of the interface moments in Co2MnSi thin films
50. Size dependence of L2,3 branching ratio and 2p core-hole screening in X-ray absorption of metal clusters10.1103/PhysRevLett.101.153401 ↗
51. Hybridization and magnetism in small FePt alloy clusters10.1088/1367-2630/14/12/123005 ↗
52. Investigation of thickness dependence on electronic structures of iron and nickel thin films by L-edge X-ray absorption spectroscopy10.1016/j.vacuum.2013.06.003 ↗
53. Diluted magnetic semiconductor at finite temperature10.1016/j.physleta.2004.04.026 ↗
54. Spin-wave relaxation in diluted magnetic semiconductors within the self-consistent Green's function approach