journal article·2017-05-01

High performance hybrid supercapacitors on flexible polyimide sheets using femtosecond laser 3D writing

Shutong Wang, Yongchao Yu, Delong Ma, Denzel Bridges, Guoying Feng, Anming Hu

Journal of Laser Applications· Volume 29· Issue 2
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Abstract

The authors successfully demonstrated flexible hybrid supercapacitors on polyimide sheets by integrating femtosecond laser direct writing, Au coating, and MnO2 electrodeposition. Scanning electron microscope images display that focused pulsed laser irradiation rapidly converts the polyimide surface into an electrically conductive porous carbon structure. After Au coating and thermal sintering of Au nanoparticles, these flexible supercapacitors achieved an enhanced rate capability. Compared to the in-plane supercapacitors, the specific capacitance of hybrid supercapacitors with MnO2 electrodeposition increase from 20 to 300 mF/cm2 at 0.5 mA/cm2 charge/discharge current. These high performance supercapacitors can be potentially integrated with applications for portable and wearable electronic devices, solar cells, chemical and biomedical sensors, display devices, and other on-chip level devices.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Sensor and Energy Harvesting Materials · Electrohydrodynamics and Fluid Dynamics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

The University of Tennessee Department of Mechanical, Aerospace and Biomedical Engineering, , 1512 Middle Drive, Knoxville, Tennessee 37996 and College of Electronics and Information Engineering, , No. 24 South Section 1, Yihuan Road, Chengdu 610065, China

Sichuan University Department of Mechanical, Aerospace and Biomedical Engineering, , 1512 Middle Drive, Knoxville, Tennessee 37996 and College of Electronics and Information Engineering, , No. 24 South Section 1, Yihuan Road, Chengdu 610065, China

The University of Tennessee Department of Mechanical, Aerospace and Biomedical Engineering, , 1512 Middle Drive, Knoxville, Tennessee 37996

Sichuan University College of Electronics and Information Engineering, , No. 24 South Section 1, Yihuan Road, Chengdu 610065, China

References (12)

Show source-provided references
1. Capacitive energy storage in micro-scale devices: Recent advances in design and fabrication of micro-supercapacitors10.1039/c3ee43526a ↗
2. Recent advances in graphene-based planar micro-supercapacitors for on-chip energy storage10.1093/nsr/nwt003 ↗
3. Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage10.1038/nnano.2014.93 ↗
4. Monolithic carbide-derived carbon films for micro-supercapacitors10.1126/science.1184126 ↗
5. Graphene-based in-plane micro-supercapacitors with high power and energy densities10.1038/ncomms3487 ↗
6. High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes10.1039/C5EE03637B ↗
7. Laser-induced porous graphene films from commercial polymers10.1038/ncomms6714 ↗
8. Facile fabrication of flexible all solid-state micro-supercapacitor by direct laser writing of porous carbon in polyimide10.1016/j.carbon.2014.11.017 ↗
9. Graphene oxide. Origin of acidity, its instability in water, and a new dynamic structural model10.1021/nn3047378 ↗
10. Development of a non-toxic electrolyte for soft gold electrodeposition: An overview of work at University of Newcastle upon Tyne10.1039/b301176n ↗
11. Low temperature sintering of Ag nanoparticles for flexible electronics packaging10.1063/1.3502604 ↗
12. High-performance pseudocapacitive microsupercapacitors from laser-induced graphene10.1002/adma.201503333 ↗