Cu₂O/Cu Hollow Spherical Heterojunction Photocatalysts Prepared by Wet Chemical Approach

1. SINGHA A, KAISHYOP J, KHAN T S, et al. Visible-light-driven toluene oxidation to benzaldehyde over WO3 nanostructures. ACS Applied Nano Materials, 2023, 6(23):21818.10.1021/acsanm.3c04012 ↗

2. JIAN L, ZHAO H, DONG Y M, et al. Graphite carbon ring modified carbon nitride with a strong built-in electric field for high photocatalysis-self-Fenton performance. Catalysis Science & Technology, 2022, 12(24):7379.10.1039/D2CY01709A ↗

3. TOE C Y, LAMERS M, DITTRICH T, et al. Facet-dependent carrier dynamics of cuprous oxide regulating the photocatalytic hydrogen generation. Materials Advances, 2022, 3(4): 2200.10.1039/D1MA00934F ↗

4. ONG W J, TAN L L, CHAI S P, et al. Highly reactive {001} facets of TiO2-based composites: synthesis, formation mechanism and characterization. Nanoscale, 2014, 6(4): 1946.10.1039/c3nr04655a ↗

5. YANG C, LIU Z L, SU Z L, et al. Combined effect of oxygen vacancies and mesopore sizes in ZnO/SiO2 adsorbents on boosting the H2S removal efficiency in moist conditions. Advanced Functional Materials, 2024, 34(49):2409214.10.1002/adfm.202409214 ↗

6. LI W J, DA P M, ZHANG Y Y, et al. WO3 nanoflakes for enhanced photoelectrochemical conversion. ACS Nano, 2014, 8(11):11770.10.1021/nn5053684 ↗

7. BANIAMERIAN H, SHOKROLLAHZADEH S, SAFAVI M, et al. Visible-light-activated Fe2O3-TiO2 nanoparticles enhance biofouling resistance of polyethersulfone ultrafiltration membranes against marine algae Chlorella vulgaris. Scientific Reports, 2024, 14: 24831.10.1038/s41598-024-76201-7 ↗

8. XIONG L K, ZHANG X, CHEN L, et al. Geometric modulation of local CO flux in Ag@Cu2O nanoreactors for steering the CO2RR pathway toward high-efficacy methane production. Advanced Materials, 2021, 33(32):2101741.10.1002/adma.202101741 ↗

9. LIU W Q, BAI P Y, WEI S L, et al. Electron-rich Cu0-Cu2O heterogeneous interface constructed via controllable electrochemical reconstruction for a single CO2 deep-reduction product ethylene. Applied Catalysis B: Environment and Energy, 2024, 348: 123831.10.1016/j.apcatb.2024.123831 ↗

10. KIM H E, WI D H, LEE J S, et al. Photoelectrochemical nitrate and nitrite reduction using Cu2O photocathodes. ACS Energy Letters, 2024, 9(5): 1993.10.1021/acsenergylett.4c00256 ↗

11. WU E T, HUANG M H. Photocatalytic oxidative amine coupling with 4-nitrophenylacetylene-modified Cu2O polyhedra. ACS Catalysis, 2023, 13(22):14746.10.1021/acscatal.3c04091 ↗

12. CHEN B H, KUMAR G, WEI Y J, et al. Experimental revelation of surface and bulk lattices in faceted Cu2O crystals. Small, 2023, 19(44):2303491.10.1002/smll.202303491 ↗

13. ZHANG Y Y, CHEN Y X, WANG X W, et al. Low-coordinated copper facilitates the *CH2CO affinity at enhanced rectifying interface of Cu/Cu2O for efficient CO2-to-multicarbon alcohols conversion. Nature Communications, 2024, 15: 5172.10.1038/s41467-024-49247-4 ↗

14. ZHANG Z H, SONG R, YU Z Y, et al. Crystal-plane effect of Cu2O templates on compositions, structures and catalytic performance of Ag/Cu2O nanocomposites. CrystEngComm, 2019, 21(12): 2002.10.1039/C8CE02164C ↗

15. ZHU M Y, CHENG Y K, LUO Q, et al. A review of synthetic approaches to hollow nanostructures. Materials Chemistry Frontiers, 2021, 5(6):2552.10.1039/D0QM00879F ↗

16. ZHANG F, LIU T Y, LI M Y, et al. Multiscale pore network boosts capacitance of carbon electrodes for ultrafast charging. Nano Letters, 2017, 17(5):3097.10.1021/acs.nanolett.7b00533 ↗

17. POOLAKKANDY R R, MENAMPARAMBATH M M. Soft- template-assisted synthesis: a promising approach for the fabrication of transition metal oxides. Nanoscale Advances, 2020, 2(11):5015.10.1039/D0NA00599A ↗

18. CUI L L, WANG C C, ZHANG H W, et al. Facile one-step dialysis strategy for fabrication of hollow complex nanoparticles. Chemical Communications, 2019, 55(62):9120.10.1039/C9CC04618F ↗

19. FANG Y J, YU X Y, LOU X W. Formation of hierarchical Cu-doped CoSe2 microboxes via sequential ion exchange for high-performance sodium-ion batteries. Advanced Materials, 2018, 30(21):1706668.10.1002/adma.201706668 ↗

20. DONG Y L, TAO F F, WANG L X, et al. One-pot preparation of hierarchical Cu2O hollow spheres for improved visible-light photocatalytic properties. RSC Advances, 2020, 10(38):22387.10.1039/D0RA02460K ↗

21. LV T T, XING H Z, YANG H M, et al. Rapid synthesis of Cu2O hollow spheres at low temperature and their catalytic performance for the decomposition of ammonium perchlorate. CrystEngComm, 2021, 23(45):7985.10.1039/D1CE00663K ↗

22. LIU B Q, YAO X, ZHANG Z J, et al. Synthesis of Cu2O nanostructures with tunable crystal facets for electrochemical CO2 reduction to alcohols. ACS Applied Materials & Interfaces, 2021, 13(33):39165.10.1021/acsami.1c03850 ↗

23. ZHOU B, LIU Z G, ZHANG H J, et al. One-pot synthesis of Cu2O/Cu self-assembled hollow nanospheres with enhanced photocatalytic performance. Journal of Nanomaterials, 2014, 2014: 291964.10.1155/2014/291964 ↗

24. CHANG J Y, BAO Q W, ZHANG C, et al. Rapid preparation and photocatalytic properties of octahedral Cu2O@Cu powders. Advanced Powder Technology, 2021, 32(1):144.10.1016/j.apt.2020.11.025 ↗

25. CHANG Y, TEO J J, ZENG H C. Formation of colloidal CuO nanocrystallites and their spherical aggregation and reductive transformation to hollow Cu2O nanospheres. Langmuir, 2005, 21(3):1074.10.1021/la047671l ↗

26. ZHU S C, CHEN Z Y, LIU Z P, et al. Thermodynamics and catalytic activity of the reduced Cu on a Cu2O surface from machine learning atomic simulation. ACS Materials Letters, 2024, 6(8):3690.10.1021/acsmaterialslett.4c00852 ↗

27. YUE Y M, ZHANG P X, WANG W, et al. Enhanced dark adsorption and visible-light-driven photocatalytic properties of narrower-band-gap Cu2S decorated Cu2O nanocomposites for efficient removal of organic pollutants. Journal of Hazardous Materials, 2020, 384: 121302.10.1016/j.jhazmat.2019.121302 ↗

28. BAO Y C, CHEN K Z. A novel Z-scheme visible light driven Cu2O/Cu/g-C3N4 photocatalyst using metallic copper as a charge transfer mediator. Molecular Catalysis, 2017, 432: 187.10.1016/j.mcat.2017.01.008 ↗

29. SARAEV A A, KURENKOVA A Y, MISHCHENKO D D, et al. Cu/TiO2 photocatalysts for CO2 reduction: structure and evolution of the cocatalyst active form. Transactions of Tianjin University, 2024, 30(2):140.10.1007/s12209-024-00384-3 ↗

30. XU B G, WANG B, ZHANG H Y, et al. Z-scheme Cu2O nanoparticle/graphite carbon nitride nanosheet heterojunctions for photocatalytic hydrogen evolution. ACS Applied Nano Materials, 2022, 5(6):8475.10.1021/acsanm.2c01616 ↗

31. LI Z J, WANG M Z, JIA Y Y, et al. CeO2/Cu2O/Cu tandem interfaces for efficient water-gas shift reaction catalysis. ACS Applied Materials & Interfaces, 2023, 15(26):31584.10.1021/acsami.3c06386 ↗

32. LI D Y, ZAN J, WU L P, et al. Heterojunction tuning and catalytic efficiency of g-C3N4-Cu2O with glutamate. Industrial & Engineering Chemistry Research, 2019, 58(10):4000.10.1021/acs.iecr.8b04581 ↗

33. ZHANG Z J, WANG W Z, GAO E P, et al. Photocatalysis coupled with thermal effect induced by SPR on Ag-loaded Bi2WO6 with enhanced photocatalytic activity. The Journal of Physical Chemistry C, 2012, 116(49):25898.10.1021/jp309719q ↗

34. WANG Y B, ZHAO X, CAO D, et al. Peroxymonosulfate enhanced visible light photocatalytic degradation bisphenol A by single-atom dispersed Ag mesoporous g-C3N4 hybrid. Applied Catalysis B: Environmental, 2017, 211: 79.10.1016/j.apcatb.2017.03.079 ↗

35. MEI W D, LI D Y, XU H M, et al. Effect of electronic migration of MIL-53(Fe) on the activation of peroxymonosulfate under visible light. Chemical Physics Letters, 2018, 706: 694.10.1016/j.cplett.2018.07.020 ↗

36. ZHANG H, DIAO J F, LIU Y H, et al. In situ-grown Cu dendrites plasmonically enhance electrocatalytic hydrogen evolution on facet-engineered Cu2O. Advanced Materials, 2023, 35(42):2305742.10.1002/adma.202305742 ↗