Research Progress of High-entropy Carbide Ultra-high Temperature Ceramics
Source abstract
Abstract
The development of high-speed flight technology has put forward an urgent demand for high-performance thermal structure materials.High-entropy carbides (HECs) are a fast-emerging family of materials that combine the excellent properties of high-entropy ceramics and ultra-high temperature ceramics.HECs have a broad application prospect in extreme service environments, which has received extensive attention from scholars in recent years.Compared with traditional ultra-high temperature carbides containing only one or two transition metal elements, HECs have a greater potential for development because of their improved comprehensive performance and greater designability of composition and properties.After successive exploration of HECs in recent years, researchers have obtained many interesting results, developed a variety of preparation methods for HECs, and gained comprehensive understanding of the microstructure and properties of HECs.The basic theories of HECs and the laws obtained from the experimental process are reviewed in this paper.The preparation methods of HECs including powders, blocks, coatings and films, as well as fiber-reinforced HECs-based composites are summarized.And the progress of the research on the properties of HECs, such as the mechanical properties, thermal properties, and especially the oxidation and ablation resistance related to high-temperature applications, are reviewed and discussed.Finally, the scientific problems that need to be further explored in the research of HECs are emphasized, and the prospect of HECs is proposed.
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Research context
OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Advanced ceramic materials synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. CHEN B W, NI D W, BAO W C, et al. Engineering Cf/ZrB2- SiC-Y2O3 for thermal structures of hypersonic vehicles with excellent long-term ultrahigh temperature ablation resistance. Adv. Sci., 2023, 10: 202304254.10.1002/advs.202304254 ↗
2. BINNER J, PORTER M, BAKER B, et al. Selection, processing, properties and applications of ultra-high temperature ceramic matrix composites, UHTCMCs—a review. Int. Mater. Rev., 2019, 65(7):389.10.1080/09506608.2019.1652006 ↗
3. NI D W, CHENG Y, ZHANG J P, et al. Advances in ultra-high temperature ceramics, composites, and coatings. J. Adv. Ceram., 2022, 11(1):1.10.1007/s40145-021-0550-6 ↗
4. OSES C, TOHER C, CURTAROLO S. High-entropy ceramics. Nat. Rev. Mater., 2020, 5(4):295.10.1038/s41578-019-0170-8 ↗
5. WYATT B C, NEMANI S K, HILMAS G E, et al. Ultra-high temperature ceramics for extreme environments. Nat. Rev. Mater., 2023, https://doi.org/10.1038/s41578-023-00619-0.10.1038/s41578-023-00619-0 ↗
6. ZENG Y, WANG D N, XIONG X, et al. Ablation-resistant carbide Zr0.8Ti0.2C0.74B0.26 for oxidizing environments up to 3,000 ℃. Nat. Commun., 2017, 8: 15836.10.1038/ncomms15836 ↗
7. WANG H X, WANG Y G, LIU Q M. Research progress of high entropy transition metal carbide ceramics. J. Inorg. Mater., 2021, 36(4):355.10.15541/jim20200366 ↗
8. XIANG H M, XING Y, DAI F Z, et al. High-entropy ceramics: present status, challenges, and a look forward. J. Adv. Ceram., 2021, 10(3):385.10.1007/s40145-021-0477-y ↗
9. WRIGHT A J, LUO J. A step forward from high-entropy ceramics to compositionally complex ceramics: a new perspective. J. Mater. Sci., 2020, 55(23):9812.10.1007/s10853-020-04583-w ↗
10. KAUFMANN K, MARYANOVSKY D, MELLOR W M, et al. Discovery of high-entropy ceramics via machine learning. npj Comput. Mater., 2020, 6: 42.10.1038/s41524-020-0317-6 ↗
11. GILD J, ZHANG Y, HARRINGTON T, et al. High-entropy metal diborides: a new class of high-entropy materials and a new type of ultrahigh temperature ceramics. Sci. Rep., 2016, 6: 37946.10.1038/srep37946 ↗
12. ZHANG R Z, REECE M J. Review of high entropy ceramics: design, synthesis, structure and properties. J. Mater. Chem. A, 2019, 7(39):22148.10.1039/C9TA05698J ↗
13. 顾俊峰, 邹冀, 张帆, 等. 高熵陶瓷研究进展. 中国材料进展, 2019, 38(9):855.
14. CHEN L, WANG K, SU W T, et al. Research progress of transition metal non-oxide high-entropy ceramics. J. Inorg. Mater., 2019, 35(7):748.
15. WANG Y C. Processing and properties of high entropy carbides. Adv. Appl. Ceram., 2022, 121(2):57.10.1080/17436753.2021.2014277 ↗
16. CAI F Y, NI D W, CHEN B W, et al. Fabrication and properties of Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC high-entropy ceramic matrix composites via precursor infiltration and pyrolysis. J. Eur. Ceram. Soc., 2021, 41(12):5863.10.1016/j.jeurceramsoc.2021.05.026 ↗
17. YU D, YIN J, ZHANG B H, et al. Recent development of high- entropy transitional carbides: a review. J. Ceram. Soc. Jpn., 2020, 128(7):329.10.2109/jcersj2.19242 ↗
18. CASTLE E, CSANADI T, GRASSO S, et al. Processing and properties of high-entropy ultra-high temperature carbides. Sci. Rep., 2018, 8: 8609.10.1038/s41598-018-26827-1 ↗
19. PENG C, GAO X, WANG M Z, et al. Diffusion-controlled alloying of single-phase multi-principal transition metal carbides with high toughness and low thermal diffusivity. Appl. Phys. Lett., 2019, 114(1):011905.10.1063/1.5054954 ↗
20. WANG Y C, CSANADI T, ZHANG H F, et al. Enhanced hardness in high-entropy carbides through atomic randomness. Adv. Theory Simul., 2020, 3(9):2000111.10.1002/adts.202000111 ↗
21. YEH J W, CHEN S K, LIN S J, et al. Nanostructured high- entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv. Eng. Mater., 2004, 6(5):299.10.1002/adem.200300567 ↗
22. CANTOR B, CHANG I T H, KNIGHT P, et al. Microstructural development in equiatomic multicomponent alloys. Mater. Sci. Eng. A Struct. Mater., 2004, 375-377: 213.10.1016/j.msea.2003.10.257 ↗
23. ROST C M, SACHET E, BORMAN T, et al. Entropy-stabilized oxides. Nat. Commun., 2015, 6: 8485.10.1038/ncomms9485 ↗
24. WANG Y J, ZHANG G J. Non-order is the new order: high- entropy ceramics. J. Inorg. Mater., 2021, 36(4):337.10.15541/jim20200900 ↗
25. ZHANG W R, LIAW P K, ZHANG Y. Science and technology in high-entropy alloys. Sci. China-Mater., 2018, 61(1):2.10.1007/s40843-017-9195-8 ↗
26. MIRACLE D B, SENKOV O N. A critical review of high entropy alloys and related concepts. Acta Mater., 2017, 122: 448.10.1016/j.actamat.2016.08.081 ↗
27. HARRINGTON T J, GILD J, SARKER P, et al. Phase stability and mechanical properties of novel high entropy transition metal carbides. Acta Mater., 2019, 166: 271.10.1016/j.actamat.2018.12.054 ↗
28. YEH J W. Recent progress in high-entropy alloys. Ann. Chim-Sci. Mat., 2006, 31(6):633.10.3166/acsm.31.633-648 ↗
29. TSAI M H, YEH J W. High-entropy alloys: a critical review. Mater. Res. Lett., 2014, 2(3):107.10.1080/21663831.2014.912690 ↗
30. YE B L, WEN T Q, HUANG K H, et al. First-principles study, fabrication, and characterization of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high- entropy ceramic. J. Am. Ceram. Soc., 2019, 102(7):4344.10.1111/jace.16295 ↗
31. SARKER P, HARRINGTON T, TOHER C, et al. High-entropy high-hardness metal carbides discovered by entropy descriptors. Nat. Commun., 2018, 9: 4980.10.1038/s41467-018-07160-7 ↗
32. CHICARDI E, GARCÍA-GARRIDO C, HERNÁNDEZ-SAZ J, et al. Synthesis of all equiatomic five-transition metals high entropy carbides of the IVB (Ti, Zr, Hf) and VB (V, Nb, Ta) groups by a low temperature route. Ceram. Int., 2020, 46(13):21421.10.1016/j.ceramint.2020.05.240 ↗
33. CHICARDI E, GARCíA-GARRIDO C, GOTOR F J. Low temperature synthesis of an equiatomic (TiZrHfVNb)C5 high entropy carbide by a mechanically-induced carbon diffusion route. Ceram. Int., 2019, 45(17):21858.10.1016/j.ceramint.2019.07.195 ↗
34. FENG L, FAHRENHOLTZ W G, HILMAS G E, et al. Synthesis of single-phase high-entropy carbide powders. Scr. Mater., 2019, 162: 90.10.1016/j.scriptamat.2018.10.049 ↗
35. YE B L, NING S S, LIU D, et al. One-step synthesis of coral-like high-entropy metal carbide powders. J. Am. Ceram. Soc., 2019, 102(10):6372.10.1111/jace.16514 ↗
36. NING S S, WEN T Q, YE B L, et al. Low-temperature molten salt synthesis of high-entropy carbide nanopowders. J. Am. Ceram. Soc., 2019, 103(3):2244.10.1111/jace.16896 ↗
37. LI F, LU Y, WANG X G, et al. Liquid precursor-derived high- entropy carbide nanopowders. Ceram. Int., 2019, 45(17):22437.10.1016/j.ceramint.2019.07.244 ↗
38. ZHAO T, LIU W, HAN W J, et al. Synthesis of high entropy carbide nano powders via liquid polymer precursor route. J. Inorg. Mater., 2021, 36(4):393.10.15541/jim20200391 ↗
39. ZHOU J Y, ZHANG J Y, ZHANG F, et al. High-entropy carbide: a novel class of multicomponent ceramics. Ceram. Int., 2018, 44(17):22014.10.1016/j.ceramint.2018.08.100 ↗
40. SEDEGOV A, VOROTILO S, TSYBULIN V, et al. Synthesis and study of high-entropy ceramics based on the carbides of refractory metals. IOP Conf. Ser. Mater. Sci. Eng., 2019, 558(1):012043.10.1088/1757-899X/558/1/012043 ↗
41. DU B, LIU H H, CHU Y H. Fabrication and characterization of polymer-derived high-entropy carbide ceramic powders. J. Am. Ceram. Soc., 2020, 103(8):4063.10.1111/jace.17134 ↗
42. ŠOLCOVÁ P, NIŽŇANSKÝ M, SCHULZ J, et al. Preparation of high-entropy (Ti, Zr, Hf, Ta, Nb) carbide powder via solution chemistry. Inorg. Chem., 2021, 60(11):7617.10.1021/acs.inorgchem.1c00776 ↗
43. SUN Y N, CHEN F H, QIU W F, et al. Synthesis of rare earth containing single-phase multicomponent metal carbides via liquid polymer precursor route. J. Am. Ceram. Soc., 2020, 103(11):6081.10.1111/jace.17332 ↗
44. CSANÁDI T, VOJTKO M, DANKHÁZI Z, et al. Small scale fracture and strength of high-entropy carbide grains during microcantilever bending experiments. J. Eur. Ceram. Soc., 2020, 40(14):4774.10.1016/j.jeurceramsoc.2020.04.023 ↗
45. ZHANG H Z, AKHTAR F. Processing and characterization of refractory quaternary and quinary high-entropy carbide composite. Entropy, 2019, 21(5):474.10.3390/e21050474 ↗
46. DEMIRSKYI D, SUZUKI T S, YOSHIMI K, et al. Synthesis and high-temperature properties of medium-entropy (Ti,Ta,Zr,Nb)C using the spark plasma consolidation of carbide powders. Open Ceram., 2020, 2: 100015.10.1016/j.oceram.2020.100015 ↗
47. WANG F, YAN X L, WANG T Y, et al. Irradiation damage in (Zr0.25Ta0.25Nb0.25Ti0.25)C high-entropy carbide ceramics. Acta Mater., 2020, 195: 739.10.1016/j.actamat.2020.06.011 ↗
48. WANG F, ZHANG X, YAN X L, et al. The effect of submicron grain size on thermal stability and mechanical properties of high- entropy carbide ceramics. J. Am. Ceram. Soc., 2020, 103(8):4463.10.1111/jace.17103 ↗
49. LIU D Q, ZHANG A J, JIA J G, et al. Phase evolution and properties of (VNbTaMoW)C high entropy carbide prepared by reaction synthesis. J. Eur. Ceram. Soc., 2020, 40(8):2746.10.1016/j.jeurceramsoc.2020.03.020 ↗
50. LU K, LIU J X, WEI X F, et al. Microstructures and mechanical properties of high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C ceramics with the addition of SiC secondary phase. J. Eur. Ceram. Soc., 2020, 40(5): 1839.10.1016/j.jeurceramsoc.2019.12.056 ↗
51. DUSZA J, CSANáDI T, MEDVEĎ D, et al. Nanoindentation and tribology of a (Hf-Ta-Zr-Nb-Ti)C high-entropy carbide. J. Eur. Ceram. Soc., 2021, 41(11):5417.10.1016/j.jeurceramsoc.2021.05.002 ↗
52. YE B L, WEN T Q, NGUYEN M C, et al. First-principles study, fabrication and characterization of (Zr0.25Nb0.25Ti0.25V0.25)C high- entropy ceramics. Acta Mater., 2019, 170: 15.10.1016/j.actamat.2019.03.021 ↗
53. FENG L, FAHRENHOLTZ W G, HILMAS G E. Low-temperature sintering of single-phase, high-entropy carbide ceramics. J. Am. Ceram. Soc., 2019, 102(12):7217.10.1111/jace.16672 ↗
54. FENG L, CHEN W T, FAHRENHOLTZ W G, et al. Strength of single-phase high-entropy carbide ceramics up to 2300 ℃. J. Am. Ceram. Soc., 2020, 104(1):419.10.1111/jace.17443 ↗
55. WANG K, CHEN L, XU C G, et al. Microstructure and mechanical properties of (TiZrNbTaMo)C high-entropy ceramic. J. Mater. Sci. Technol., 2020, 39: 99.10.1016/j.jmst.2019.07.056 ↗
56. NI N, DING Q, SHI Y C, et al. Ablation behavior of high-entropy carbides ceramics (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C upon exposition to an oxyacetylene torch at 2000 ℃. J. Eur. Ceram. Soc., 2023, 43(6):2306.10.1016/j.jeurceramsoc.2023.01.017 ↗
57. LU W Y, CHEN L, ZHANG W, et al. Single-phase formation and mechanical properties of (TiZrNbTaMo)C high-entropy ceramics: first-principles prediction and experimental study. J. Eur. Ceram. Soc., 2022, 42(5): 2021.10.1016/j.jeurceramsoc.2021.12.058 ↗
58. PÖTSCHKE J, DAHAL M, HERRMANN M, et al. Preparation of high-entropy carbides by different sintering techniques. J. Mater. Sci., 2021, 56(19):11237.10.1007/s10853-021-06004-y ↗
59. YU D, YIN J, ZHANG B H, et al. Pressureless sintering and properties of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics: the effect of pyrolytic carbon. J. Eur. Ceram. Soc., 2021, 41(6):3823.10.1016/j.jeurceramsoc.2021.01.048 ↗
60. CHEN L, ZHANG W, TAN Y Q, et al. Influence of vanadium content on the microstructural evolution and mechanical properties of (TiZrHfVNbTa)C high-entropy carbides processed by pressureless sintering. J. Eur. Ceram. Soc., 2021, 41(16):60.10.1016/j.jeurceramsoc.2021.09.011 ↗
61. BRAIC M, BRAIC V, BALACEANU M, et al. Characteristics of (TiAlCrNbY)C films deposited by reactive magnetron sputtering. Surf. Coat. Technol., 2010, 204(12/13): 2010.10.1016/j.surfcoat.2009.10.049 ↗
62. BRAIC V, VLADESCU A, BALACEANU M, et al. Nanostructured multi-element (TiZrNbHfTa)N and (TiZrNbHfTa)C hard coatings. Surf. Coat. Technol., 2012, 211: 117.10.1016/j.surfcoat.2011.09.033 ↗
63. BRAIC V, PARAU A C, PANA I, et al. Effects of substrate temperature and carbon content on the structure and properties of (CrCuNbTiY)C multicomponent coatings. Surf. Coat. Technol., 2014, 258: 996.10.1016/j.surfcoat.2014.07.044 ↗
64. YAN X L, CONSTANTIN L, LU Y F, et al. (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics with low thermal conductivity. J. Am. Ceram. Soc., 2018, 101(10):4486.10.1111/jace.15779 ↗
65. DUSZA J, ŠVEC P, GIRMAN V, et al. Microstructure of (Hf-Ta-Zr-Nb)C high-entropy carbide at micro and nano/atomic level. J. Eur. Ceram. Soc., 2018, 38(12):4303.10.1016/j.jeurceramsoc.2018.05.006 ↗
66. WEI X F, QIN Y, LIU J X, et al. Gradient microstructure development and grain growth inhibition in high-entropy carbide ceramics prepared by reactive spark plasma sintering. J. Eur. Ceram. Soc., 2020, 40(4):935.10.1016/j.jeurceramsoc.2019.12.034 ↗
67. WEI X F, LIU J X, LI F, et al. High entropy carbide ceramics from different starting materials. J. Eur. Ceram. Soc., 2019, 39(10):2989.10.1016/j.jeurceramsoc.2019.04.006 ↗
68. GILD J, KAUFMANN K, VECCHIO K, et al. Reactive flash spark plasma sintering of high-entropy ultrahigh temperature ceramics. Scr. Mater., 2019, 170: 106.10.1016/j.scriptamat.2019.05.039 ↗
69. ZHANG W, CHEN L, XU C G, et al. Densification, microstructure and mechanical properties of multicomponent (TiZrHfNbTaMo)C ceramic prepared by pressureless sintering. J. Mater. Sci. Technol., 2021, 72: 23.10.1016/j.jmst.2020.07.019 ↗
70. YU D, ZHANG B H, YIN J, et al. Densifying (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics by two-step pressureless sintering. J. Am. Ceram. Soc., 2022, 105(1):76.10.1111/jace.18116 ↗
71. MALINOVSKIS P, FRITZE S, RIEKEHR L, et al. Synthesis and characterization of multicomponent (CrNbTaTiW)C films for increased hardness and corrosion resistance. Mater. Des., 2018, 149: 51.10.1016/j.matdes.2018.03.068 ↗
72. MUKHERJEE A, VLADESCU A, TITORENCU I, et al. In vitro biocompatibility of Si alloyed multi-principal element carbide coatings. PLOS ONE, 2016, 11(8):e0161151.10.1371/journal.pone.0161151 ↗
73. BRAIC V, BALACEANU M, BRAIC M, et al. Characterization of multi-principal-element (TiZrNbHfTa)N and (TiZrNbHfTa)C coatings for biomedical applications. J. Mech. Behav. Biomed. Mater., 2012, 10: 197.10.1016/j.jmbbm.2012.02.020 ↗
74. BRAIC M, BALACEANU M, VLADESCU A, et al. Deposition and characterization of multi-principal-element (CuSiTiYZr)C coatings. Appl. Surf. Sci., 2013, 284: 671.10.1016/j.apsusc.2013.07.152 ↗
75. LIANG S C, TSAI D C, CHANG Z C, et al. Structural and mechanical properties of multi-element (TiVCrZrHf)N coatings by reactive magnetron sputtering. Appl. Surf. Sci., 2011, 258(1):399.10.1016/j.apsusc.2011.09.006 ↗
76. PEI Y T, CHEN C Q, SHAHA K P, et al. Microstructural control of TiC/a-C nanocomposite coatings with pulsed magnetron sputtering. Acta Mater., 2008, 56(4):696.10.1016/j.actamat.2007.10.025 ↗
77. ROST C M, BORMAN T, HOSSAIN M D, et al. Electron and phonon thermal conductivity in high entropy carbides with variable carbon content. Acta Mater., 2020, 196: 231.10.1016/j.actamat.2020.06.005 ↗
78. GORBAN’ V F, ANDREYEV A A, KARTMAZOV G N, et al. Production and mechanical properties of high-entropic carbide based on the TiZrHfVNbTa multicomponent alloy. J. Phys. Chem., 2017, 39(3):166.10.3103/S1063457617030030 ↗
79. KAO W H, SU Y L, HORNG J H, et al. Mechanical, tribological, anti-corrosion and anti-glass sticking properties of high-entropy TaNbSiZrCr carbide coatings prepared using radio-frequency magnetron sputtering. Mater. Chem. Phys., 2021, 268: 124741.10.1016/j.matchemphys.2021.124741 ↗
80. JHONG Y S, HUANG C W, LIN S J. Effects of CH4 flow ratio on the structure and properties of reactively sputtered (CrNbSiTiZr) Cx coatings. Mater. Chem. Phys., 2018, 210: 348.10.1016/j.matchemphys.2017.08.002 ↗
81. LIN S Y, CHANG S Y, HUANG Y C, et al. Mechanical performance and nanoindenting deformation of (AlCrTaTiZr)NCy multi-component coatings co-sputtered with bias. Surf. Coat. Technol., 2012, 206(24):5096.10.1016/j.surfcoat.2012.06.035 ↗
82. XU W J, JIA B S, LIU X H, et al. Structural evolution and mechanical properties of multi-element (TiCrZrVNb)C high entropy ceramics films by multi-arc ion plating. Ceram. Int., 2022, 48(13):19191.10.1016/j.ceramint.2022.03.211 ↗
83. WANG J, ZHANG H, YU X, et al. Insight into the structure and tribological and corrosion performance of high entropy (CrNbSiTiZr) C films: first-principles and experimental study. Surf. Coat. Technol., 2021, 421: 127468.10.1016/j.surfcoat.2021.127468 ↗
84. LI J C, ZHANG Y L, ZHAO Y X, et al. A novel (Hf1/3Zr1/3Ti1/3)C medium-entropy carbide coating with excellent long-life ablation resistance applied above 2100 ℃. Compos. B Eng., 2023, 251: 110467.10.1016/j.compositesb.2022.110467 ↗
85. CAI F Y, NI D W, CHEN B W, et al. Efficient fabrication and properties of 2D Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiC high-entropy ceramic matrix composites via slurry infiltration lamination combined with precursor infiltration and pyrolysis. J. Eur. Ceram. Soc., 2023, 43(16):7403.10.1016/j.jeurceramsoc.2023.07.080 ↗
86. ZHANG L, WANG W Q, ZHOU N P, et al. Low temperature fabrication of Cf/BNi/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C-SiCm high entropy ceramic matrix composite by slurry coating and laminating combined with precursor infiltration and pyrolysis. J. Eur. Ceram. Soc., 2022, 42(7):3099.10.1016/j.jeurceramsoc.2022.02.021 ↗
87. GUO W J, HU J, FANG W, et al. A novel strategy for rapid fabrication of continuous carbon fiber reinforced (TiZrHfNbTa)C high-entropy ceramic composites: high-entropy alloy in-situ reactive melt infiltration. J. Eur. Ceram. Soc., 2023, 43(6):2295.10.1016/j.jeurceramsoc.2023.01.019 ↗
88. BAO W C, WANG X G, DING H J, et al. High-entropy M2AlC-MC (M=Ti, Zr, Hf, Nb, Ta) composite: synthesis and microstructures. Scr. Mater., 2020, 183: 33.10.1016/j.scriptamat.2020.03.015 ↗
89. CHEN L, LI Y B, CHEN K, et al. Synthesis and characterization of medium-/high-entropy M2SnC (M = Ti/V/Nb/Zr/Hf) MAX phases. Small Struct., 2023, 4: 2200161.10.1002/sstr.202200161 ↗
90. NEMANI S K, ZHANG B, WYATT B C, et al. High-entropy 2D carbide MXenes: TiVNbMoC3 and TiVCrMoC3. ACS Nano, 2021, 15(8):12815.10.1021/acsnano.1c02775 ↗
91. CHEN L, LI Y B, LIANG K, et al. Two-dimensional MXenes derived from medium/high-entropy MAX phases M2GaC (M = Ti/V/Nb/Ta/Mo) and their electrochemical performance. Small Methods, 2023, 7(8):230005410.1002/smtd.202300054 ↗
92. DU Z G, WU C, CHEN Y C, et al. High-entropy atomic layers of transition-metal carbides (MXenes). Adv. Mater., 2021, 33(39):2101473.10.1002/adma.202101473 ↗
93. LIU J B, XIONG J, GUO Z X, et al. Preparation of high-entropy (Zr0.25Hf0.25Ta0.25Ti0.25)C-Ni-Co composite by spark plasma sintering. Metall. Mater. Trans. A, 2020, 51(12):6706.10.1007/s11661-020-06034-2 ↗
94. WANG Y C, YU D, YIN J, et al. Ablation behavior of (Hf-Ta-Zr-Nb-Ti)C high-entropy carbide and (Hf-Ta-Zr-Nb-Ti)C- xSiC composites. J. Am. Ceram. Soc., 2022, 105(10):6395.10.1111/jace.18620 ↗
95. WANG H X, WANG S Y, CAO Y J, et al. Oxidation behaviors of (Hf0.25Zr0.25Ta0.25Nb0.25)C and (Hf0.25Zr0.25Ta0.25Nb0.25)C-SiC at 1300-1500 ℃. J. Mater. Sci. Technol., 2021, 60: 147.10.1016/j.jmst.2020.05.037 ↗
96. NAUGHTON-DUSZOVÁ A, ŠVEC P, KOVALČÍKOVÁ A, et al. On the phase and grain boundaries in dual phase carbide/boride ceramics from micro to atomic level. J. Eur. Ceram. Soc., 2023, 43(15):6765.10.1016/j.jeurceramsoc.2023.07.034 ↗
97. QIN M D, GILD J, HU C Z, et al. Dual-phase high-entropy ultra- high temperature ceramics. J. Eur. Ceram. Soc., 2020, 40(15):5037.10.1016/j.jeurceramsoc.2020.05.040 ↗
98. HUO S J, CHEN L, LIU X R, et al. Reactive sintering of dual- phase high-entropy ceramics with superior mechanical properties. J. Mater. Sci. Technol., 2022, 129: 223.10.1016/j.jmst.2022.03.035 ↗
99. QIN M D, VEGA H D, ZHANG D W, et al. 21-Component compositionally complex ceramics: discovery of ultrahigh-entropy weberite and fergusonite phases and a pyrochlore-weberite transition. J. Adv. Ceram., 2022, 11(4):641.10.1007/s40145-022-0575-5 ↗
100. WANG Y C, WANG X C, LI S, et al. Improved oxidation resistance of (Zr-Nb-Hf-Ta)(C, N) high entropy carbonitrides. Corros. Sci., 2023, 225: 111583.10.1016/j.corsci.2023.111583 ↗