journal article·2007-10

The effect of sulfur on the number of layers in a carbon nanotube

Jinquan Wei, Hongwei Zhu, Yi Jia, Qinke Shu, Chuangang Li, Kunlin Wang, Bingqing Wei, Yanqiu Zhu, Zhicheng Wang, Jianbin Luo, Wenjin Liu, Dehai Wu

Carbon· Volume 45· Issue 11
Publisher page

Abstract

Abstract This study shows that S concentration in the Fe catalyst plays an important role in controlling the number of graphene layers during carbon nanotube (CNT) growth via chemical vapor deposition. Using different S concentrations, we have grown thin carbon nanotubes with from 1 to 5 layers. Single-walled carbon nanotubes growing from the active surface of an FeS–Fe eutectic were observed. A growth model basing on the HRTEM characterization and thermodynamic analysis is suggested in which the CNT nucleates and grows on the active surface area of the catalyst where S accumulates in the form of an FeS–Fe eutectic, and the S distribution on the catalyst particle surface determines the number of CNT layers.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Thermal properties of materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Are fullerene tubules metallic?10.1103/PhysRevLett.68.631 ↗
2. New one-dimensional conductors: graphitic microtubules10.1103/PhysRevLett.68.1579 ↗
3. Electronic structure of chiral graphene tubules10.1063/1.107080 ↗
4. Size dependence of the thin-shell model for carbon nanotubes10.1103/PhysRevLett.95.105501 ↗
5. Atomic-resolution imaging of the nucleation points of single-walled carbon nanotubes10.1002/smll.200500200 ↗
6. Isotope labeling of carbon nanotubes and a formation of C12–C13 nanotube junctions10.1021/ja0167304 ↗
7. Atomic-scale imaging of carbon nanofibre growth10.1038/nature02278 ↗
8. Diameter-controlled synthesis of carbon nanotubes10.1021/jp0142278 ↗
9. Role of thin Fe catalyst in the synthesis of double- and single-wall carbon nanotubes via microwave chemical vapor deposition10.1063/1.1796529 ↗
10. Roles of metal-support interaction in growth of single- and double-walled carbon nanotubes studied with diameter-controlled iron particles supported on MgO10.1021/jp046856y ↗
11. Carbon nanotubes: dynamics of synthesis processes10.1016/S0008-6223(02)00005-2 ↗
12. Growth mechanisms and diameter evolution of single wall carbon nanotubes10.1016/S0009-2614(01)00565-6 ↗
13. The effect of sulfur on the structure of carbon nanotubes produced by a floating catalyst method10.1166/jnn.2006.301 ↗
14. Evidence for, and an understanding of, the initial nucleation of carbon nanotubes produced by a floating catalyst method10.1021/jp062526x ↗
15. Size-selective growth of double-walled carbon nanotube forests from engineered iron catalysts10.1038/nnano.2006.95 ↗
16. Direct synthesis of long single-walled carbon nanotube strands10.1126/science.1066996 ↗
17. Large-scale and low-cost synthesis of single-walled carbon nanotubes by the catalytic pyrolysis of hydrocarbons10.1063/1.121624 ↗
18. Producing cleaner double-walled carbon nanotubes in a floating catalyst system10.1016/S0008-6223(03)00336-1 ↗
19. Raman characterization and tunable growth of double-wall carbon nanotubes10.1021/jp026516h ↗
20. Gas-phase synthesis of single-wall carbon nanotubes from colloidal solution of metal nanoparticles10.1021/jp012084j ↗
21. Double wall carbon nanotubes promoted by sulfur in a floating iron catalyst CVD system10.1016/S0009-2614(02)00600-0 ↗
22. Large-scale synthesis of long double-walled carbon nanotubes10.1021/jp049434x ↗
23. Synthesis of single- and double-walled carbon nanotubes by catalytic decomposition of methane10.1016/S0009-2614(03)00636-5 ↗
24. Microscopic growth mechanisms for carbon nanotubes10.1126/science.275.5300.647 ↗
25. Solid–liquid–solid growth mechanism of single-wall carbon nanotubes10.1016/S0008-6223(01)00080-X ↗
26. Growth of carbon nanotubes on metal nanoparticles: A microscopic mechanism from ab initio molecular dynamics simulations10.1103/PhysRevLett.95.096103 ↗
27. A two-stage mechanism of bimetallic catalyzed growth of single-walled carbon nanotubes10.1021/nl048663s ↗
28. Continuous production of aligned carbon nanotubes: a step closer to commercial realization10.1016/S0009-2614(99)00282-1 ↗
29. Organized assembly of carbon nanotubes – Cunning refinements help to customize the architecture of nanotube structures10.1038/416495a ↗
30. Preparation of carbon nanofibers by the floating catalyst method10.1016/S0008-6223(00)00030-0 ↗
31. The interplay between sulfur adsorption and carbon deposition on cobalt catalyst10.1006/jcat.1993.1289 ↗
32. Why are carbon filaments tubular?10.1016/0022-0248(84)90163-5 ↗