journal article·2011-05

A method for wet spinning of alginate fibers with a high concentration of single-walled carbon nanotubes

Vijoya Sa, Konstantin G. Kornev

Carbon· Volume 49· Issue 6
Publisher page

Abstract

Abstract A method is described for the wet spinning of alginate fibers with a loading of single-walled carbon nanotubes as high as 23 wt%. Electrostatic assembling of polyelectrolytes and nanotubes coated with sodium dodecyl sulfate is exploited by using calcium as a cross-linking agent. The Young’s modulus of these fibers depends non-monotonically on nanotube concentration which is explained using Halpin-Tsai and Voigt models. Scanning electron microscope micrographs and resistivity analysis of the fibers suggest that the nanotube-alginate system undergoes a morphological transition from a composite structure of discrete nanotube bundles embedded in an alginate matrix to a complex continuous structure consisting of a nanotube network interwoven into a macromolecular network of alginate. The nanotube-alginate fibers have unprecedented high flexibility and a very high electrical conductivity similar to semimetals (between germanium and carbon).
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Nanotechnology research and applications · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Aligned single-wall carbon nanotubes in composites by melt processing methods10.1016/S0009-2614(00)01013-7 ↗
2. Transparent poly(methyl methacrylate)/single-walled carbon nanotube (PMMA/SWNT) composite films with increased dielectric constants10.1002/adfm.200305106 ↗
3. Carbon nanotube DNA sensor and sensing mechanism10.1021/nl060613v ↗
4. Super-tough carbon-nanotube fibres – these extraordinary composite fibres can be woven into electronic textiles10.1038/423703a ↗
5. Films and fibers of oriented single wall nanotubes10.1016/S0008-6223(02)00042-8 ↗
6. Highly conducting carbon nanotube/polyethyleneimine composite fibers10.1002/adma.200401648 ↗
7. Spinning solid and hollow polymer-free carbon nanotube fibers10.1002/adma.200401130 ↗
8. Macroscopic fibers and ribbons of oriented carbon nanotubes10.1126/science.290.5495.1331 ↗
9. Continuous carbon nanotube composite fibers: properties, potential applications, and problems10.1039/b312092a ↗
10. Carbon nanotubes – the route toward applications10.1126/science.1060928 ↗
11. Chawla · 1998
12. Electrospinning of continuous carbon nanotube-filled nanofiber yarns10.1002/adma.200304955 ↗
13. Continuous spinning of a single-walled carbon nanotube–nylon composite fiber10.1021/ja0446193 ↗
14. Interfacial in situ polymerization of single wall carbon nanotube/nylon 6,6 nanocomposites10.1016/j.polymer.2006.01.087 ↗
15. Microscopic mechanism of reinforcement in single-wall carbon nanotube/polypropylene nanocomposite10.1016/j.polymer.2004.11.030 ↗
16. Kelly · 1987
17. Agarwal · 2006
18. Ribbon-to-fiber transformation in the process of spinning of carbon-nanotube dispersion10.1103/PhysRevLett.97.188303 ↗
19. Improved structure and properties of single-wall carbon nanotube spun fibers10.1063/1.1497706 ↗
20. Rheological and electrical properties of polypropylene/MWCNT composites prepared with MWCNT masterbatch chips10.1016/j.eurpolymj.2008.03.017 ↗
21. Electrical properties of poly(phenylene sulfide)/multiwalled carbon nanotube composites prepared by simple mixing and compression10.1002/app.28098 ↗
22. Strong carbon-nanotube fibers spun from long carbon-nanotube arrays10.1002/smll.200600368 ↗
23. Sustained growth of ultralong carbon nanotube arrays for fiber spinning10.1002/adma.200601344 ↗
24. Hierarchical pore structure and wetting properties of single-wall carbon nanotube fibers10.1021/nl034013x ↗
25. Arbitrarily shaped fiber assemblies from spun carbon nanotube gel fibers10.1002/adfm.200700210 ↗
26. Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide10.1016/S0009-2614(99)01029-5 ↗
27. Carbon nanotube biofiber formation in a polymer-free coagulation bath10.1002/adfm.200700822 ↗
28. Alginate fibres: an overview of the production processes and applications in wound management10.1002/pi.2296 ↗
29. Phillips GO, Williams PA, Knovel (Firm), Handbook of hydrocolloids, 2nd ed. Boca Raton, FL Cambridge: CRC Press; Woodhead Pub. 2009:xxiv, p. 924.
30. Multiple steps and critical behaviors of the binding of calcium to alginate10.1021/jp0689870 ↗
31. Biological Interactions between Polysaccharides and Divalent Cations – Egg-Box Model10.1016/0014-5793(73)80770-7 ↗
32. Chiroptical and stoichiometric evidence of a specific, primary dimerization process in alginate gelation10.1016/S0008-6215(00)83247-4 ↗
33. Characterization of cation binding and gelation of polyuronates by circular-dichroism10.1016/S0008-6215(00)81023-X ↗
34. Sa V, Kornev KG. A Route Toward Wet Spinning of Single Walled Carbon Nanotube Fibers: Sodium Alginate – SWCNT Fibers. Materials Research Society Symposium Proceedings. 2008;1134 (Paper # 1134-BB05-31).10.1557/PROC-1134-BB05-31 ↗
35. 2002
36. Halpin-Tsai equations – review10.1002/pen.760160512 ↗
37. Enhancing the strength of polypropylene fibers with carbon nanotubes10.1002/app.20703 ↗
38. Benzoyl peroxide initiated in situ functionalization, processing, and mechanical properties of single-walled carbon nanotube–polypropylene composite fibers10.1021/jp065399d ↗
39. Ward · 2004
40. Bond lengths and diameters of armchair single wall carbon nanotubes10.1016/j.cplett.2005.03.088 ↗
41. Energetics, structure, mechanical and vibrational properties of single-walled carbon nanotubes10.1088/0957-4484/9/3/007 ↗
42. Effect of encapsulated SWNT on the mechanical properties of melt mixed PA12/SWNT composites10.1016/j.cplett.2004.05.045 ↗
43. Selective dispersion of single-walled carbon nanotubes in the presence of polymers: the role of molecular and colloidal length scales10.1021/ja046377c ↗