A remark on the configurational entropy of a liquid solution with a weak tendency to association
Source abstract
Abstract
Abstract A weak tendency to association may significantly increase the molar configurational entropy of a liquid solution. This circumstance should not be overlooked if one intends to use a positive excess entropy to describe experimental data within the framework of the CALPHAD method.
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Source: openaire · Quality: needs review · Source record ↗
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Research context
OpenAlex topics: Chemical Thermodynamics and Molecular Structure · Phase Equilibria and Thermodynamics · Theoretical and Computational Physics
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References (7)
Show source-provided references
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2. Association model for the description of thermodynamic functions of liquid alloys II. Numerical treatment and results
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4. An entropy paradox of the association model
5. Modeling short-range ordering in solutions10.3139/146.101554 ↗
6. Modeling short-range ordering in liquids: the Mg–Al–Sn system10.1016/j.calphad.2010.02.003 ↗
7. Fowler · 1952