Reply to comment on the paper “Experimental investigation of the Ni-V-W ternary phase diagram”
Source abstract
Abstract
The comment (Joubert, 2022) regarding the controversial “NiW” phase detected in our previous study (Tang et al., 2022) was clarified in this work. Our previous conclusion about the presence of the “NiW” phase in the Ni-V-W ternary phase diagram is drawn without considering the contamination of C. In this work, alloys with a composition of Ni49V1W50 (at. %) were equilibrated at 1100 and 900 °C and characterized. The result showed that the NiW phase observed in the previous work (Tang et al., 2022) was actually Ni6W6C carbide, which resulted in misinterpretation of ternary phase constitutions in our previous studies about Ni-V-W (Tang et al., 2022) and Mo-Ni-W (Tang et al., 2020) systems. A new thermodynamic modeling of the Mo-Ni-W ternary system is performed by excluding the presence of “NiW” phase, and this set of parameters can describe the experimental results reasonably.
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Research context
OpenAlex topics: Advanced materials and composites · Metal and Thin Film Mechanics · Intermetallics and Advanced Alloy Properties
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References (35)
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1. Comment on the paper" Experimental investigation of the Ni–V–W ternary phase diagram", Calphad: comput
2. Experimental investigation of the Ni-V-W ternary phase diagrams10.1016/j.calphad.2021.102384 ↗
3. Experimental phase diagram, thermodynamic modeling and solidified microstructure in the Mo–Ni–W ternary system10.1016/j.calphad.2020.101748 ↗
4. On the existence and the crystal structure of Ni4W, NiW and NiW2 compounds10.1016/j.intermet.2008.11.001 ↗
5. Solid-state reactive diffusion between Ni and W10.1016/j.jallcom.2011.01.139 ↗
6. The critical influence of carbon on the thermal stability of nanocrystalline Ni–W alloys10.1016/j.scriptamat.2014.10.022 ↗
7. First principles, thermal stability and thermodynamic assessment of the binary Ni–W system10.3139/146.111557 ↗
8. Experimental determination of the phase diagrams of the Co-Ni-X (X= W, Mo, Nb, Ta) ternary systems using diffusion multiples10.1016/j.intermet.2017.11.005 ↗
9. The nickel-tungsten system
10. Diagramma sostav-zharoprovhnost splavov dvoinoi sistemy Nikel-Volfram
11. Hofmann · 1983
12. Experimental and calculated phase diagrams of the Ni-W, Co-W and Co-Ni-W system10.1515/ijmr-1985-760902 ↗
13. Pearson · 1958
14. Phase eaquilibria of the Ni-W-Cr system in the composition and temperature ranges of the liquid phase sintering of heavy alloys10.1515/ijmr-1985-760211 ↗
15. Method of non-interacting thermodynamic calculation of binary phase diagrams containing p disordered phases with variable composition and q phases with constant composition at
16. On the cold rolling textures in some fcc Ni–W alloys10.1016/j.msea.2004.05.024 ↗
17. An accidental visualization of the Brillouin zone in an Ni–W alloy via diffuse scattering10.1107/S0021889813016270 ↗
18. Vogel · Allg. Chem. · 1921 · 116 · 23110.1002/zaac.19211160123 ↗
19. Rntgenspektroskopie an metallverbindungen
20. Electron microscopy and electron diffraction study of ordering in Ni4W10.1007/BF02396657 ↗
21. Crystalline structure of the intermetallic phases of WNi3 and MoNi3
22. Determination of the quantity of hexagonal phase of Ni3W in nickel alloys with 20, 25, and 50 at.% tungsten
23. Discovery of a thermally persistent h.c.p. solid-solution phase in the Ni-W system10.1063/1.4894148 ↗
24. On a new intermetallic phase in the nickel-tungsten system
25. A new intermetallic phase in the W-Ni system10.1016/0036-9748(74)90349-4 ↗
26. Experimental and theoretical study of the phase equilibria in the fe-ni-w system10.1007/BF02817278 ↗
27. Influence of carbon on bond strength between nickel and Ni–W alloys10.1179/mst.1991.7.3.228 ↗
28. Irradiation-induced nanoprecipitation in Ni-W alloys10.1007/s11661-014-2704-4 ↗
29. Powder densification behavior and microstructure formation mechanism of W-Ni alloy processed by selective laser melting10.1016/j.jallcom.2022.164609 ↗
30. Microstructure and phase equilibria in the Ni
31. Experimental study and thermodynamic assessment of the Ni-Mo-Ta ternary system10.1007/s11661-999-0110-0 ↗
32. An Experimental Study and a Thermodynamic Evaluation of the Fe-Mo-W System/Experimentelle Untersuchung und thermodynamische Optimierung des Systems Fe-Mo-W10.1515/ijmr-1988-790605 ↗
33. Isothermal cross section of the phase diagram of the nickel-molybdenum-tungsten system at 1200 and 700 °C
34. Study of a nickel-molybdenum-tungsten phase diagram
35. Structural features of phase diagrams formed by molybdenum and tungsten with iron-group metals