journal article·2009-09

Thermodynamic modeling of the C–Pu–U system

Evelyne Fischer

Calphad· Volume 33· Issue 3
Publisher page

Abstract

The ternary C–Pu–U system is thermodynamically assessed to pursue the development of a thermodynamic database for future nuclear fuels. The substitution model was used for the liquid phase, and a two-sublattice model for the PuC–UC monocarbide, PuC2–UC2 dicarbide and Pu2C3–U2C3 sesquicarbide phases. Ternary interaction parameters were adjusted on the experimental information for the phase relationships. Isoplethal and isothermal ternary sections, as well as some liquidus temperatures are calculated and compared with the experimental data. The overall agreement is discussed, and shows that experimental uncertainties still remain.
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Research context

OpenAlex topics: Nuclear Materials and Properties · High Temperature Alloys and Creep · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (23)

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