Experimental investigation of the phase equilibria of the La–Ti–Zn system at 600 and 450 °C
Source abstract
Abstract
Abstract A series of La–Ti–Zn alloys was designed to investigate the 600 and 450 °C isothermal sections of the La–Ti–Zn system based on examination by scanning electron microscope (SEM) equipped with energy dispersive X-ray spectrometer (EDS) and X-ray powder diffraction (XRD). No ternary compound was found in the system. Nine three-phase regions were identified at both the 600 and 450 °C sections. Five Ti–Zn intermetallic compounds, TiZn16, Ti3Zn22, TiZn3, TiZn and Ti2Zn were observed in the present work. It was found that TiZn3 may not be a strictly stoichiometric compound. La does not dissolve in any of Ti–Zn binary compounds and the solubility of Ti in La-Zn binary compounds was ≤ 0.3 at%. The TiZn3 phase can equilibrate with LaZn13, LaZn11, La2Zn17, and La3Zn22, while TiZn can achieve equilibrium with La3Zn22, LaZn5, LaZn4, and LaZn2.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Rare-earth and actinide compounds · Intermetallics and Advanced Alloy Properties · Metallurgical and Alloy Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Casting with zinc alloys10.1007/BF03339527 ↗
2. An analysis of selected properties of ZA alloys10.1007/BF03258743 ↗
3. Effect of different Al contents on the microstructure, tensile and wear properties of Zn-based alloy10.1016/j.matlet.2003.10.058 ↗
4. Influence of alloying elements on the corrosion resistance of rolled zinc sheet10.1016/j.corsci.2005.05.028 ↗
5. Bulk nanostructured materials from severe plastic deformation10.1016/S0079-6425(99)00007-9 ↗
6. The mechanism of grain refinement during solidification of Zn-Ti base alloys10.1007/BF02913842 ↗
7. The effect of rare earth metals on a zinc-aluminium alloy
8. The 450 and 600 °C isothermal sections of the Al-Ce-Zn (0–33.3 at%Ce) ternary system10.1007/s11669-015-0372-8 ↗
9. 600 and 450 °C isothermal sections of the Zn–Ce–Ti system10.1016/j.jallcom.2017.03.215 ↗
10. Thermodynamical and kinetic investigation of formation of periodic layered structure in TiCu/Zn interface reaction
11. Phase equilibria in the Zn-rich corner of the Zn-Cu-Ti system
12. Experimental and thermodynamic assessment of the La–Ti and La–Zr systems10.1016/j.calphad.2015.10.015 ↗
13. New experimental investigation of the lanthanum zinc phase diagram10.1016/j.tca.2011.05.001 ↗
14. Thermodynamic properties and phase composition of La–Zn alloys
15. Thermodynamic optimization of La–Zn and La–Mg–Zn systems10.1016/j.jallcom.2010.03.062 ↗
16. Experimental investigation and thermodynamic calculation of the Zn–Fe–La system10.1016/j.jallcom.2015.09.080 ↗
17. Thermodynamic assessment of the La–Zn system10.1016/j.calphad.2011.11.004 ↗
18. The 450 °C Isothermal Section of the Zn-Fe-Ti System10.1007/s11669-007-9092-z ↗
19. The Zn-rich corner of the Zn–Al–Ti system at 723 K10.1016/j.jallcom.2010.03.148 ↗
20. Experimental investigation and thermodynamic optimization of the Al–Zn–Ti system in the Al-rich corner10.1016/j.intermet.2012.09.027 ↗
21. The 450 °C and 600 °C isothermal sections of the Zn–Ti–Si system10.1016/j.jallcom.2014.07.094 ↗
22. Experimental Investigation of the 450 and 600 °C Sections of the Ti-V-Zn System10.1007/s11669-016-0496-5 ↗
23. S. Ono, H. Ohtani, M. Hasebe Proceedings of 9th Symposium on Microjoining Assembly Technology in Electronics, Yokohama, Japan, 6–7 February.
24. Reaction kinetics and phase diagram studies in the Ti-Zn system10.1016/j.jallcom.2003.11.026 ↗
25. Preparation, properties, and crystal structures of Ti3Zn22 and TiZn1610.1006/jssc.1995.1337 ↗
26. The structure of TiZn1610.1107/S0567740881002574 ↗
27. A cursory investigation of intermediate phases in the systems Ti-Zn, Ti-Hg, Zr-Zn, Zr-Cd, and Zr-Hg by X-ray powder diffraction methods
28. The Ti-Zn (Titanium-Zinc) system
29. Some structural data of metallic phases. Part VIII10.1007/BF00622812 ↗
30. Critical assessment and optimization of phase diagrams and thermodynamic properties of RE–Zn systems-part I: Sc–Zn, La–Zn, Ce–Zn, Pr–Zn, Nd–Zn, Pm–Zn and Sm–Zn10.1016/j.jallcom.2015.03.140 ↗
31. Magnetic susceptibility, electrical resistivity and neutron spectroscopy of some cubic cerium intermetallics10.1088/0305-4608/11/3/015 ↗
32. Intermetallic phases in the systems of zinc with lanthanum, cerium, praseodymium, neodymium, and yttrium
33. Rare-earth intermediate phases with zinc10.1016/0022-5088(70)90074-3 ↗
34. Lanthanum tetrazinc, LaZn410.1107/S0108270112020367 ↗
35. Crystal structures of the compounds Ce3Zn22, La3Zn22, and Pr3Zn2210.1007/BF01551266 ↗
36. Zinc-rich phases of the rare-earth-zinc alloys10.1016/0022-5088(67)90001-X ↗
37. Crystallographic data for cerium-zinc compounds10.1107/S0365110X66001774 ↗