journal article·2023-06

Experimental investigation of Ag–Pd–Sn ternary system

Alexandr S. Pavlenko, Evgeniya A. Ptashkina, Elizaveta G. Kabanova, Galina P. Zhmurko, Maria A. Kareva, Victor N. Kuznetsov

Calphad· Volume 81
Publisher page

Abstract

Isothermal sections of the Ag–Pd–Sn system at 500 and 800 °C were plotted based on the XRD and EDX results. The solubility of Sn in palladium and silver-based fcc solid solution has nearly zero minimum around the Ag corner. The Pd3Sn and γ-Pd2–xSn phases show significant dissolution of Ag and extend towards the Ag corner. The other Pd–Sn and Ag–Sn binary phases dissolve under 5 at.% of the third component. A new τ1 ternary phase was discovered in the Pd-rich region. Its XRD pattern corresponds formally to In structure type, but the actual arrangement of the atoms in the τ1 phase most probably corresponds to tetragonal Al3Ti type structure.
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Research context

OpenAlex topics: Electronic Packaging and Soldering Technologies · Rare-earth and actinide compounds · Intermetallics and Advanced Alloy Properties

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