journal article·2020-09Open access

Experimental and computational studies of melting of the spinel phase in the Fe–Al–O ternary system

Can Agca, Greta Lindwall, Jake W. McMurray, Jörg C. Neuefeind, Zi-Kui Liu, Alexandra Navrotsky

Calphad· Volume 70

Abstract

Abstract The melting behavior of spinel in the Fe–Al–O system at high temperatures (1500–1800 °C) was studied by a combination of experimental and computational investigations. Differential thermal analysis (DTA) at ultra-high temperatures coupled with cooling traces on CO2 laser-heated levitated samples provided melting temperatures and the heats of fusion of (Fe,Al)3O4 spinel phases. The experimental results are in fair agreement with the predictions using a published CALPHAD description and areas for modeling improvement are identified. New insights into the melting of defect spinel are provided.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Nuclear Materials and Properties · Advanced materials and composites

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