journal article·2019-09

Experimental investigation of phase equilibria in the Al–Cr–Fe system

Maximilian Rank, Peter Franke, Jan Hoffmann, Hans J. Seifert

Calphad· Volume 66
Publisher page

Abstract

Abstract The literature of the ternary Al–Cr–Fe system was evaluated and major open questions were identified. Transition temperatures between α-Fe,Al (A2) – FeAl (B2) and FeAl (B2) – Fe3Al (D03) as well as solidus/liquidus temperatures in the Cr-rich corner were determined. The results from thermal analysis show a substantial decrease of the A2/B2 transition temperature with increasing Cr content at constant x(Al). Furthermore, a partial solidus and liquidus projection below 50 at.-% Al were created. Several partial isothermal sections have been studied with equilibrated alloys and diffusion couples. Therefore, complementary methods were used such as thermal analysis, electron microscopy, chemical analysis, X-ray powder diffraction and electron probe microanalysis. Equilibration experiments have been performed at 973 K, 1173 K, 1315 K, 1373 K and 1423 K and two partial isothermal sections at the two lowest temperatures were constructed indicating a solubility of 22 at.-% iron in the AlCr2 phase at 973 K.
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Research context

OpenAlex topics: Intermetallics and Advanced Alloy Properties · Nuclear Materials and Properties · Aluminum Alloy Microstructure Properties

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