journal article·2020-03

Interdiffusion and atomic mobility in the bcc Ti–rich Ti–Cr–Mn system

Jingjing Zhou, Yang Xu, Zhenyu Zhang, Chenggong Gong, Liujie Xu, Yao Wang, Weimin Chen

Calphad· Volume 68
Publisher page

Abstract

Abstract In this work, ternary interdiffusivities in the bcc Ti–rich Ti–Cr–Mn alloys at 1273 K were determined by using the combination of the diffusion couple technique and the Matano–Kirkaldy method. Subsequently, on the basis of the presently obtained interdiffusivities along with the diffusivity and mobility parameters of binary sub–systems within the Ti–Cr–Mn system and thermodynamic descriptions for the bcc Ti–Cr–Mn system, the atomic mobilities of Ti, Cr and Mn in the bcc Ti–Cr–Mn alloys were assessed using the optimization module within the Thermo-Calc software package. Moreover, the comprehensive comparisons between the experimental diffusion properties (i.e., interdiffusivities, composition profiles, and diffusion paths) and the calculated/model–predicted data due to the present atomic mobilities were conducted in order to verify the reliability of the mobilities. At present, the atomic mobilities for the bcc Ti–Cr–Mn system can provide an accurate interdiffusivity matrix over a wide composition range.
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Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Intermetallics and Advanced Alloy Properties · High Temperature Alloys and Creep

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References (31)

Show source-provided references
1. Effects of Mo contents on the microstructure, properties and cytocompatibility of the microwave sintered porous Ti–Mo alloys10.1016/j.msec.2018.12.028 ↗
2. Experimental investigation and thermodynamic description of the Fe–Ta–Ti system10.1016/j.calphad.2019.03.002 ↗
3. Effects of Sc addition on the diffusion kinetics and mechanical properties of bcc Ti alloys10.1007/s11661-019-05198-w ↗
4. Kinetic modeling of diffusion mobilities in bcc Ti–Nb alloys10.1016/j.jallcom.2008.09.019 ↗
5. High-throughput screening for biomedical applications in a Ti–Zr–Nb alloy system through masking co-sputtering10.1007/s11433-019-9387-7 ↗
6. A MGI-oriented investigation of the Young's modulus and its application to the development of a novel Ti–Nb–Zr–Cr bio-alloy10.1016/j.msec.2019.110265 ↗
7. Design and fabrication of Ti–Zr–Hf–Cr–Mo and Ti–Zr–Hf–Co–Cr–Mo high-entropy alloys as metallic biomaterials10.1016/j.msec.2019.110322 ↗
8. Fabrication of low-cost beta-type Ti–Mn alloys for biomedical applications by metal injection molding process and their mechanical properties10.1016/j.jmbbm.2016.02.035 ↗
9. Interdiffusion and atomic mobility in bcc Ti-rich Ti–Nb–Zr system10.1016/j.calphad.2017.12.002 ↗
10. Thermodynamic description of the Ti–Mo–Nb–Ta–Zr system and its implications for phase stability of Ti bio-implant materials10.1016/j.calphad.2018.02.004 ↗
11. Diffusivities and atomic mobilities in bcc Ti–Mo–Zr alloys10.3390/ma11101909 ↗
12. Experimental investigations on the quaternary interdiffusion coefficients, Young's modulus and hardness in bcc Ti–Nb–Ta–Zr quaternary alloys10.1007/s11669-018-0702-8 ↗
13. Thermodynamic modeling of Ti–Cr–Mn ternary system10.1016/j.calphad.2009.08.002 ↗
14. Phase equilibria, thermodynamics and microstructure simulation of metastable spinodal decomposition in c–Ti1−xAlxN coatings10.1016/j.calphad.2016.12.006 ↗
15. Effect of Cr on metastable phase equilibria and spinodal decomposition in c–TiAlN coatings: a CALPHAD and Cahn-Hilliard study10.1016/j.surfcoat.2017.01.007 ↗
16. High–throughput determination of interdiffusion coefficients for Co–Cr–Fe–Mn–Ni high–entropy alloys10.1007/s11669-017-0569-0 ↗
17. Thermodynamic description of the Ti–Mo–Nb–Ta–Zr system and its implications for phase stability of Ti bio–implant materials10.1016/j.calphad.2018.02.004 ↗
18. Diffusivities and atomic mobilities in bcc Ti–Nb–Ta alloys10.1016/j.calphad.2019.03.012 ↗
19. Experimental diffusion Research on BCC Ti–Mn binary and Ti–Al–Mn ternary alloys10.1007/s11669-018-0675-7 ↗
20. Assessment of atomic mobility for BCC Ti–Mn and Ti–Al–Mn alloys10.1016/j.calphad.2018.06.005 ↗
21. THERMO-CALC & DICTRA, computational tools for materials science10.1016/S0364-5916(02)00037-8 ↗
22. Investigations on diffusion behaviors in Ti–rich Ti–Nb–Zr–Cr system: experimental measurement and CALPHAD modeling10.1016/j.calphad.2018.07.005 ↗
23. Thermodynamic and kinetic modeling of the Cr–Ti–V system10.1361/105497102770331569 ↗
24. Kirkaldy · 1987
25. An analysis of concentration profiles of fluxes, diffusion depths, and zero–flux planes in multicomponent diffusion10.1007/BF02645555 ↗
26. Experimental procedure to determine the interdiffusion coefficient of miscibility gap liquid alloys: case of GaPb system10.1103/PhysRevB.76.174203 ↗
27. Volume interdiffusion coefficient and uncertainty assessment for polycrystalline materials10.62721/diffusion-fundamentals.17.661 ↗
28. Models for numerical treatment of multicomponent diffusion in simple phases10.1063/1.351745 ↗
29. Calculation of phase diagrams: Calphad10.1016/S1359-0286(96)80025-8 ↗
30. Modelling of thermodynamics and diffusion in multicomponent systems10.1179/174328408X372001 ↗
31. Solvent and solute diffusion in b.c.c. Ti–Co and Ti–Mn alloys10.1080/14786437508229632 ↗