journal article·1995-03Open access

A thermodynamic assessment of the iron — Antimony system

Benyan Pei, Bo Björkman, Bo Sundman, Bo Jansson

Calphad· Volume 19· Issue 1

Abstract

A critical assessment of the Fe-Sb system was carried out by using a computerized technique. Both the liquid and solid solution phases were described by regular solution models. Nonstoichiometric phase, ε-FeSb, was modeled as (Fe)(Fe,Sb), and FeSb2 was treated as a stoichiometric compound. A set of parameters describing the Gibbs energies of the different phases was optimized by using the existing phase diagram information and thermodynamic properties under one atmosphere. Assessed phase diagram and thermodynamic data are presented and compared with experimental data.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Thermodynamic and Structural Properties of Metals and Alloys · Solidification and crystal growth phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Constitution of Binary Alloys
2. Constitution of Binary Alloys
3. Iron-Binary Phase Diagrams
4. Massalski · 1990 · 2 · 1763
5. Selected Values of the Thermodynaimc Properties of Metals and Alloys
6. Selected Values of the Thermodynamic Properties of Binary Alloys
7. Pei · Z. Metall. · 1994 · 85 · 171
8. Pei · Z. Metall. · 1994 · 85 · 178
9. Hillert · Calphad · 1978 · 2 · 22710.1016/0364-5916(78)90011-1 ↗
10. SGTE Data for Pure Element10.1016/0364-5916(91)90030-N ↗
11. Jones · J. Iron Steel Inst. · 1934 · 130 · 429
12. Fournier · Rev. chim. ind. · 1935 · 44 · 195
13. Vogel · Arch. Eisenhüttenwes. · 1934 · 8 · 3910.1002/srin.193400104 ↗
14. Svechnikov · Metallurg · 1938 · 13 · 13
15. Hillert · J. Iron Steel Inst. · 1967 · 205 · 539
16. Predel · Arch. Eisenhüttenwes. · 1971 · 42 · 36510.1002/srin.197102608 ↗
17. Nageswararao · Metall. Trans. · 1974 · 5 · 106110.1007/BF02644318 ↗
18. Takayama · Tran. Jpn. Inst. Met. · 1981 · 22 · 31510.2320/matertrans1960.22.315 ↗
19. Feschotte · J. Less-Common Met. · 1989 · 155 · 25510.1016/0022-5088(89)90235-X ↗
20. Maier · Z. Metallkd. · 1972 · 63 · 411
21. Galasso · J. Appl. Phys. · 1967 · 38 · 324110.1063/1.1710095 ↗
22. Geller · Arch. Eisenhüttenwes. · 1939 · 13 · 26310.1002/srin.193900887 ↗
23. Kurnakow · Z. Anorg Chem. · 1908 · 58 · 110.1002/zaac.19080580102 ↗
24. Vecher · J. Phys. Chem. · 1961 · 35 · 773
25. Kjekshus · Acta Chem. Scand. · 1969 · 23 · 262110.3891/acta.chem.scand.23-2621 ↗
26. Hägg · Z. Krist. · 1928 · 68 · 471
27. Dynan · J. Chemi. Thermodyn. · 1975 · 7 · 116310.1016/0021-9614(75)90037-3 ↗
28. Ageev · Izvest Akad. Nauk. S.S.S.R. Khim. · 1943 · 87
29. Gerasimov · Russ. J. Phys. Chem. · 1967 · 41 · 1323
30. Chase · Bull. Alloy Phase Diagra. · 1983 · 4 · 123
31. Swartzendruber · Bull. Alloy Phase Diagra. · 1982 · 3 · 16110.1007/BF02892374 ↗
32. Rosenqvist · Acta Crystallogr. · 1954 · 7 · 636
33. Körber · Mitt. Kaiser-Wilhelm Inst. Eisenforsch. · 1937 · 19 · 131
34. Geiderikh · Rauu. J. Phys. Chem. · 1960 · 34 · 1311
35. Predel · Thermochim. Acta · 1978 · 24 · 15510.1016/0040-6031(78)85146-6 ↗
36. Tomilin · 1960 · 1 · 225
37. Sundman · Calphad · 1985 · 9 · 15310.1016/0364-5916(85)90021-5 ↗