journal article·2021-12

A thermodynamic assessment of the Mg–Sn–Sb ternary system

Jiyuan Zhang, Jun Wang, Yuan Yuan

Calphad· Volume 75
Publisher page

Abstract

Abstract Magnesium-tin-antimony (Mg–Sn–Sb) system is a promising system for developing high-creep resistance magnesium alloy and the alloy-type anode of magnesium recharge battery. Herein, the thermodynamic assessment of Mg–Sn–Sb ternary system was carried out using the CALculaiton of PHAse Diagram (CALPHAD) approach based on available literature data. The liquid phase was described via the associated model with associates Mg3Sb2 and Mg2Sn, and the compounds were described using the sublattice model. The consistency of the calculated phase equilibria relations and thermochemical properties with the available experimental data of Mg–Sn–Sb ternary system is presented. The thermodynamic descriptions of Mg–Sb, Sn–Sb binary systems and Mg–Sn–Sb ternary system assessed in this work provide a thermodynamic basis for the alloy design of magnesium alloy.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Hydrogen Storage and Materials · Aluminum Alloys Composites Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (92)

Show source-provided references
1. Latest research advances on magnesium and magnesium alloys worldwide10.1016/j.jma.2020.02.003 ↗
2. Overview of advancement and development trend on magnesium alloy10.1016/j.jma.2019.08.001 ↗
3. The high-solution design of magnesium alloys (invited speak)
4. Coupling physics in machine learning to investigate the solution behavior of binary Mg alloys
5. A review on casting magnesium alloys: modification of commercial alloys and development of new alloys10.1016/j.jmst.2016.07.001 ↗
6. Recent developments in high-strength Mg-RE-based alloys: focusing on Mg-Gd and Mg-Y systems10.1016/j.jma.2018.08.001 ↗
7. A review of magnesium die-castings for closure applications10.1016/j.jma.2019.02.005 ↗
8. Fundamentals and advances in magnesium alloy corrosion10.1016/j.pmatsci.2017.04.011 ↗
9. Thermodynamic descriptions of quaternary Mg-Al-Zn-Bi system supported by experiments and their application in descriptions of solidification behavior in Bi-additional AZ casting alloys10.1016/j.jma.2020.03.007 ↗
10. A systematic investigation of secondary phase dissolution in Mg-Sn alloys10.1016/j.jma.2019.11.002 ↗
11. Effect of Si addition on microstructure and wear properties of Mg-Sn as-cast alloys10.1016/j.jma.2018.08.004 ↗
12. Thermodynamic modeling of the Mg-Si-Sn system10.1016/j.calphad.2006.12.003 ↗
13. Microstructural features of Mg-8%Sn alloy and its correlation with mechanical properties10.1016/j.jma.2017.07.003 ↗
14. Applications of thermodynamic calculations to Mg alloy design: Mg-Sn based alloy development10.3139/146.101542 ↗
15. Effect of Bi, Sb, and Ca additions on the hot hardness and microstructure of cast Mg-5Sn alloy10.1016/j.msea.2010.08.045 ↗
16. Effect of Sb and Sr additions on the microstructural evolution of Mg-Sn-Al-Si based alloys10.2320/matertrans.MC200751 ↗
17. High temperature phase stabilized microstructure in Mg-Zn-Sn alloys with Y and Sb additions10.1007/s10853-007-1998-7 ↗
18. Microstructure and mechanical properties of as-cast AZ31 with the addition of Sb10.1016/j.msea.2008.07.010 ↗
19. Morphology of α-Mg3Sb2 precipitates in Mg-Sb binary alloys10.4028/www.scientific.net/MSF.610-613.892 ↗
20. Microstructural evolution and mechanical properties of binary Mg–xBi (x = 2, 5, and 8 wt%) alloys
21. Hot deformation of Mg-Y-Zn alloy with a low content of the LPSO phase studied by in-situ synchrotron radiation diffraction10.1016/j.jma.2019.11.009 ↗
22. A new die-cast magnesium alloy for applications at higher elevated temperatures of 200-300 °C10.1016/j.jma.2020.09.012 ↗
23. Composition optimization of high-strength Mg-Gd-Y-Zr alloys based on the structural unit of Mg-Gd solid solution10.1016/j.jmst.2020.08.041 ↗
24. Effects of Sb additions on the microstructure and impression creep behavior of a cast Mg-5Sn alloy10.1016/j.msea.2009.08.056 ↗
25. Tin-based materials as versatile anodes for alkali (earth)-ion batteries10.1016/j.jpowsour.2018.05.063 ↗
26. A review on current anode materials for rechargeable Mg batteries10.1016/j.jma.2020.09.017 ↗
27. Challenges and recent progress on key materials for rechargeable magnesium batteries
28. Thermodynamic re-assessment of the Mg-Y binary system coupling with the precipitation sequence during aging process10.1016/j.calphad.2020.102010 ↗
29. Thermodynamic database of multi-component Mg alloys and its application to solidification and heat treatment10.1016/j.jma.2016.11.004 ↗
30. Thermodynamic modeling of the Mg-Sn-Zn ternary system10.1016/j.jallcom.2010.08.124 ↗
31. The Mg-Sn (Magnesium-Tin) system10.1007/BF02872898 ↗
32. Optimization of the Mg-Sn system10.1051/jcp/1993900181 ↗
33. Phase equilibria, thermodynamics and solidification microstructures of Mg-Sn-Ca alloys, Part 1: experimental investigation and thermodynamic modeling of the ternary Mg-Sn-Ca system10.1016/j.intermet.2007.10.010 ↗
34. The Mg-Sb (Magnesium-Antimony) system10.1007/BF02868320 ↗
35. A theoretical evaluation of chemical ordering and glass-transition in liquid Mg-Sb alloys10.1007/BF02646653 ↗
36. Thermodynamic modeling of the Mg-Al-Sb system10.1016/j.calphad.2005.03.001 ↗
37. Re-optimization of the Mg-Sb system under topological constraints10.3139/146.101267 ↗
38. Thermodynamic modeling of the Mg-Bi and Mg-Sb binary systems and short-range-ordering behavior of the liquid solutions10.1016/j.calphad.2009.10.002 ↗
39. Sgte data for pure elements10.1016/0364-5916(91)90030-N ↗
40. The ternary system lead-antimone-magnesium antimonide10.1002/zaac.19301900109 ↗
41. Crystal structures of the elements at 25 °C
42. Alloys of magnesium with cadmium, zinc, bismuth and antimony10.1002/zaac.19060490108 ↗
43. Binary diagram of magnesium-antimony
44. The effect of antimony on magnesium
45. Thermodynamic study of the Mg-Sb system10.1007/BF02913412 ↗
46. Liquid semiconductors and thermoelectric power generation: Mg-sb
47. Kubaschewski · 1979
48. Experiences and results in the high temperature calorimetry of alloys
49. Vapor pressure of magnesium over its binary liquid alloys with antimony and bismuth
50. Thermodynamics of liquid magnesium alloys using Caf2 solid electrolytes10.1016/0022-3115(74)90111-1 ↗
51. Thermodynamic activity of magnesium in several highly-solvating liquid alloys10.1007/BF02654364 ↗
52. On the heat capacity of metals and compounds10.1515/zpch-1910-7118 ↗
53. The phase equilibria in the Sb-Sn system - Part I: literature review10.1016/j.jallcom.2017.08.215 ↗
54. Sb-Sn (Antimony-Tin)
55. Phase equilibria of the Sn-Sb binary system10.1007/s11664-008-0464-x ↗
56. Sb-Sn (antimony-tin)
57. Constitution and thermodynamics of antimony-tin system
58. The phase equilibria in the Sb-Sn system - Part II: experimental results10.1016/j.jallcom.2017.11.367 ↗
59. On the binary Sb-Sn system: ab initio calculation and thermodynamic remodeling10.1007/s10853-019-03934-6 ↗
60. New insights into phase equilibria of the Sb-Sn system10.1007/s11669-020-00849-7 ↗
61. Thermodynamic study of phase equilibria in the Pb-Sn-Sb system10.1007/BF02645349 ↗
62. Thermodynamic assessment of Sb-Sn system10.1179/mst.1986.2.9.913 ↗
63. Assessment techniques, database design and software facilities for thermodynamics and diffusion10.1016/j.calphad.2006.02.007 ↗
64. Inherently consistent temperature function for interaction parameters demonstrated for the Mg-Si assessment10.1016/j.calphad.2016.06.003 ↗
65. Thermodynamic reassessment of the Sb-Sn and In-Sb-Sn systems10.1016/j.jallcom.2018.10.223 ↗
66. Incommensurate stistaite-order made to order10.1021/ic900496p ↗
67. DTA measurements in Sb–Sn alloys
68. On the constitution of the ternary layers of lead, tin, and antimony
69. Alloys of antimony and tin10.1002/zaac.19000250106 ↗
70. Thermodynamic investigation in In-Sb, Sb-Sn and In-Sb-Sn liquid systems10.1016/S0925-8388(00)01243-3 ↗
71. The activity of mixing antimony with tin metals
72. Ternary experimental excess functions by means of high-order polynomials-enthalpy of mixing of liquid Pb-Sn-Sb alloys
73. Chemical short-range order in liquid Sb-Sn alloys proved with the aid of the dependence of the mixing enthalpies on temperature10.1016/0025-5408(83)90221-0 ↗
74. A thermodynamic study of the tin-antimony system10.1149/1.3071686 ↗
75. Activity measurement of Pb-Sn and Sn-Sb based molten alloys
76. Thermodynamic properties of liquid (antimony + tin) and (gold + antimony + tin) alloys determined from e.m.f. measurements10.1016/j.jct.2015.01.010 ↗
77. Mg-Sb-Sn ternary phase diagram evaluation, MSI
78. The system Mg2Sn-Mg3Sb2
79. Three-component systems studied by the variable composition sample method eksp
80. Kinzhibalo · 1981 · 73
81. Chemical ordering and isentropic temperatures in the Mg-Sb-Sn system
82. A thermodynamic study on an associated solution model for liquid alloys10.1016/0364-5916(85)90004-5 ↗
83. The compound energy formalism10.1016/S0925-8388(00)01481-X ↗
84. Studies on AB2-type intermetallic compounds, I. Mg2Ge and Mg2Sn: single-crystal structure refinement and ab initio calculations10.1016/0925-8388(95)02058-6 ↗
85. Daams · 1991 · 6706
86. Thermodynamic properties of magnesium-tin alloys by an improved isopiestic method
87. On the alloys of magnesium with tin and thallium
88. Magnesium-tin phase diagram and thermodynamic properties of liquid magnesium -tin alloys
89. The system magnesium-tin and the compound Mg4Sn2
90. Thermodynamic properties of compounds of magnesium and group IVB elements
91. Nayak · 1968 · 15
92. The constitution of the magnesium-rich alloys in the systems magnesium-lead magnesium-tin, magnesium-germanium, and magnesium-silicon