Assessment of the ternary Fe–Si–B phase diagram
Source abstract
Abstract
An improvement of the thermodynamic description of the ternary Fe–Si–B system by means of Calphad method has been carried out in this work considering not only the equilibria involving the stable Fe2B phase but also the metastable ternary equilibria in which the Fe3B phase occurs. Furthermore, the glass transition is introduced in the Calphad framework as a second-order one using the tools provided by the Hillert–Jarl formalism of the ferromagnetic transitions not yet applied to Fe–B and Fe–Si–B. The assessments have been made using data available in the literature regarding both the amorphous and crystalline phases. The results improve the previous ones for the glassy phase while keeping the agreement with experimental data concerning stable equilibria.
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Research context
OpenAlex topics: Metallic Glasses and Amorphous Alloys · Intermetallics and Advanced Alloy Properties · Microstructure and Mechanical Properties of Steels
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References (50)
Show source-provided references
1. Thermodynamic evaluation of the phase equilibria and glass-forming ability of the Fe–Si–B system10.1016/j.calphad.2004.11.004 ↗
2. Thermodynamic analysis of glass formation in Fe–B system10.1016/S0364-5916(02)00012-3 ↗
3. Formation and magnetic properties of Fe–B–Si amorphous alloys10.1109/TMAG.1979.1145870 ↗
4. ® Metglas2605 SA1 Iron Based Alloy, Metglas®, Inc., 440 Allied Dr. Conway, SC - 29526.
5. Study of strain sensor using fesib magnetostrictive thin film10.1109/TMAG.2009.2033553 ↗
6. New position sensor based on ultraacoustic standing waves in FeSiB amorphous wires10.1016/S0924-4247(99)00081-3 ↗
7. Amorphous metallic glass biosensors10.1016/j.intermet.2012.03.030 ↗
8. The effect of Cu on the plasticity of Fe–Si–B–P-based bulk metallic glass10.1016/j.scriptamat.2008.09.008 ↗
9. Glass formability of ferrous- and aluminum- based structural metallic alloys10.1016/S0022-3093(02)02000-8 ↗
10. Local ordering model in Fe–Si–B amorphous alloys10.1016/S0921-5093(96)10630-4 ↗
11. Crystallization of stable and metastable eutectics in FeSiB metallic glasses10.1007/BF00544190 ↗
12. X-ray investigations on Me–Si–B a systems (Me=Mn, Fe, Co)10.3891/acta.chem.scand.14-1403 ↗
13. The structure of the rapidly hardened Fe–Si–B alloys
14. Phase equilibria in the systems manganese–silicon–boron and iron–silicon–boron
15. Prediction of amorhpous phase stability in metallic glasses10.1063/1.1289788 ↗
16. A model for alloying effects in ferromagnetic metal10.1016/0364-5916(78)90011-1 ↗
17. SGTE data for pure elemts10.1016/0364-5916(91)90030-N ↗
18. Thermodynamic modeling of the undercooled liquid in the Cu–Zr system10.1016/j.actamat.2005.10.019 ↗
19. Thermodynamics of supercooled liquids and their glass transition
20. Thermodynamics and kinetics of metallic amorphous phases in the framework of the CALPHAD approach10.1016/j.calphad.2007.12.002 ↗
21. Thermodynamic and kinetic aspects of intermetallic amorphous alloys10.1016/S0966-9795(02)00248-0 ↗
22. Glass forming ability of multi-component metallic systems10.1016/j.intermet.2004.07.030 ↗
23. Thermodynamic analysis of the undercooled liquid and glass transition in the Cu–Mg–Y system10.2320/matertrans.47.2950 ↗
24. Determination of chemical and magnetic interchange energies in BCC alloys
25. N. Saunders, A.P. Miodownik CALPHAD, A comprensive Guide, Pergamon Material Series, 1998, (Chapter 8).
26. Thermodynamic and dynamic fragility in metallic glass-formers10.1016/j.actamat.2012.12.045 ↗
27. An assessment of the Fe–C–Si system10.1007/BF02664987 ↗
28. Phase equilibria in the Ni–Si–B system10.2320/matertrans.44.1651 ↗
29. Thermodynamic reassessment and calculation of the Fe–B phase diagram
30. Thermodynamic optimization of the B–Fe system10.1016/S0925-8388(01)01777-7 ↗
31. Division of Computational Thermodynamics, SGTE Solution Database, Ver. 2
32. Esin · Izv. Adak. Nauk. SSSR Met. · 1975 · 82
33. Activity of the constituents in molten Fe–B and Fe–B–C alloys10.1016/j.calphad.2006.07.001 ↗
34. Critical thermodynamic evaluation and optimization of the Fe–B, Fe–Nd, B–Nd and Nd–Fe–B systems10.1016/j.jallcom.2012.08.127 ↗
35. Transformation, stability and Pourbaix diagrams of high performance corrosion resistant (HPCRM) alloys10.1016/j.calphad.2008.09.019 ↗
36. The phase Fe2B
37. Undercooling of Ni–B and Fe–B alloys and their metastable phase diagrams10.1016/S0925-8388(96)02570-4 ↗
38. The structure of Fe–B alloy10.1007/BF00652720 ↗
39. Constitution diagram of the system iron–boron10.1007/BF00775428 ↗
40. A thermodynamic study of liquid Fe–Si–B alloys; an influence of ternary associates on a liquid: glass transition
41. Crystallization characterisics in the Fe–Si–B glassy ribbon system10.1016/S0921-5093(96)10567-0 ↗
42. The effect of microstructure on properties and behaviours of annealled Fe78B13Si9 amorphous alloy ribbon10.1007/BF02647494 ↗
43. Thermochemical and structural investigation of crystallization in Fe–B and Fe–Si–B metallic glasses
44. Glass transition behavior of Fe–Al–B–Si amorphous alloys10.2320/matertrans1989.31.1021 ↗
45. Mechanical properties of Fe–Si–B amorphous wires produced by in-rotating-water spinning method10.1007/BF02643346 ↗
46. Determination of the heats of formation of intermetallics in an isothermal calorimeter by the sintering method
47. Entalpies of formation of borides of iron,cobalt and nickel by solution calorimetry in liquid copper10.1007/BF02664582 ↗
48. Plotnikova · Trans. Inst. Electrochim. Ural Nauchn Tsentr. Akad. Nauk. SSSR · 1972 · 18 · 112
49. Thermodynamic properties of Fe2B and FeB by EMF measuraments of cells with solids oxide electrolytes10.2320/matertrans1960.21.790 ↗
50. Thermophysical properties of iron and cobalt monoborides