Critical assessment and thermodynamic modeling of Mg–Zn, Mg–Sn, Sn–Zn and Mg–Sn–Zn systems
Source abstract
Abstract
All available thermodynamic and phase diagram data of Mg–Zn, Mg–Sn and Sn–Zn are critically evaluated and most reliable data are incorporated to model each system. The binary liquid phases are modeled using the modified quasi-chemical model in order to incorporate the strong ordering in the Mg–Sn and Mg–Zn systems. The binaries are extrapolated to construct the Mg–Sn–Zn ternary using the symmetric Kohler geometric model without using any ternary interaction parameter. The calculated Mg–Sn–Zn ternary diagram shows very good consistency with the published experimental data. Highlights ► Mg–Zn, Mg–Sn and Sn–Zn binary systems are thermodynamically modeled. ► The binary liquid phases are modeled using the modified quasi-chemical model. ► The binaries are extrapolated to construct the Mg–Sn–Zn ternary. ► No ternary parameter is used to construct the ternary. ► The calculated Mg–Sn–Zn diagram shows very good consistency with experimental data.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metallurgical and Alloy Processes · Electronic Packaging and Soldering Technologies · Thermodynamic and Structural Properties of Metals and Alloys
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Emley · 1966
2. Fair fight for the light weights
3. Phase formation in Mg–Sn–Zn alloys-thermodynamic calculations vs experimental verification10.1007/s10853-006-6294-4 ↗
4. I.-H. Jung, W.-J. Park, S.H. Ahn, D.-H. Kang, N.J. Kim, Thermodynamic modeling of the Mg–Sn–Zn–Al system and its application to Mg alloy design, in: A.A. Luo, N.R. Neelameggham, R.S. Beals (Eds.), Magnesium Technology 2006, pp. 457–61.
5. B. Otani, Constitution of the phase equilibrium diagram of the magnesium–zinc–tin system. Tetsu to Hagane 1993, 19, pp. 566–574 Experimental, Equi. Diagram, vol. 6 (in Japanese).
6. Stable and metastable phase equilibria in MgZn2–Zn and Mg2Sn–MgZn2–Sn–Zn alloys
7. Thermodynamic modeling of the Mg–Sn–Zn ternary system10.1016/j.jallcom.2010.08.124 ↗
8. Modeling short-range ordering in liquids: the Mg–Al–Sn system10.1016/j.calphad.2010.02.003 ↗
9. Standard Gibbs energy of formation of Mg48Zn52 determined by solution calorimetry and measurement of heat capacity from near absolute zero Kelvin10.1007/s11663-004-0083-8 ↗
10. Thermodynamics of the formation of magnesium–zinc intermetallic compounds in the temperature range from absolute zero to high temperature10.1016/j.actamat.2006.03.004 ↗
11. Alloys of zinc and magnesium
12. Alloys of magnesium with cadmium, zinc, bismuth and antimony10.1002/zaac.19060490108 ↗
13. The ternary of magnesium, zinc and cadmium10.1002/zaac.19100680109 ↗
14. The ternary of magnesium, zinc and cadmium II10.1002/zaac.19120780123 ↗
15. The constitution of the alloys of magnesium and zinc
16. Solidus and solvus of the magnesium solid solution of magnesium–zinc alloys
17. The electrical conductivity, thermal expansion and hardness of magnesium–zinc10.1002/bbpc.19290350604 ↗
18. On the solid solution of magnesium saturation curve for Al–Mg, Zn–Mg, and Mg–Mg
19. J.J. Park, L.L. Wyman, Phase relationship in Mg alloys, WADC Technical Report 1957, 57–504: Astia Document No. AD142110; pp. 1–27.
20. The system magnesium–zinc
21. T.B. Massalski (Ed.) Binary Alloy Phase Diagrams, ASM, Metals Park, Ohio, 1990.
22. The crystal structure of Mg2Zn11: isomorphism between Mg2Zn11 and Mg2Cu6Al510.3891/acta.chem.scand.03-0835 ↗
23. Central region of the magnesium–zinc phase diagram
24. The equilibrium diagram of the system magnesium–zinc
25. Laves · Naturwissenschaften · 1939 · 27 · 45410.1007/BF01489229 ↗
26. Constituent studies on the system magnesium–zinc
27. The magnesium zinc phase diagram
28. Urazov · Metallurgica · 1940 · 15 · 3
29. Koster · Zeitschrift fur Metallkunde · 1948 · 39 · 352
30. Koster · Zeitschrift fur Metallkunde · 1950 · 41 · 37
31. Clark · Phase Diagrams of Binary Magneisium Alloys · 1988 · 353
32. The crystal structure of Mg51Zn2010.1016/0022-4596(81)90161-4 ↗
33. H. Pyka, Untersuchungen zur thermodynamik glasbildender ternärer Legierungen, Ph.D. thesis, University Stuttgart, Stuttgart, Germany, 1984.
34. R. Agarwal, F. Sommer, Calorimetric investigations of Mg–Zn and Mg–Y liquid alloys, in: Proceedings of Eighth National Symposium Thermal Analysis, Bombay, India, Indian Thermal Analysis Society, 1991, pp. 249–54.
35. Thermodynamic properties of liquid zinc–magnesium solutions
36. Thermodynamic properties of Mg–Zn alloys
37. Thermodynamic properties of dilute solutions of magnesium in zinc10.1007/BF02646631 ↗
38. Thermodynamic study of molten magnesium and zinc alloys
39. Pedokand · Trudy Lenigr. Politekh · 1976 · 34 · 34
40. Activity of the component metal in fused binary alloys — Zn–Al and Zn–Mg systems
41. Agarwal · Zeitschrift fur Metallkunde · 1992 · 83 · 216
42. Thermochemistry of magnesium alloys10.1351/pac196102010013 ↗
43. A thermochemical study of some selected laves phases10.1016/0001-6160(64)90056-2 ↗
44. Calorimetric study of Mg2Zn310.3139/146.018072 ↗
45. Calorimetric study of MgZn2 and Mg2Zn1110.3139/146.030967 ↗
46. Experimental investigation and thermodynamic calculation of the Al–Mg–Zn system10.1016/S0040-6031(97)00458-9 ↗
47. Critical Assessment and Thermodynamic Modeling of the Binary Mg–Zn, Ca–Zn and Ternary Mg–Ca–Zn Systems10.1016/j.intermet.2009.03.014 ↗
48. Grube · Zeitschrift fur Anorganische Chemie · 1905 · 46 · 7610.1002/zaac.19050460106 ↗
49. Kurnakow · Zeitschrift fur Anorganische Chemie · 1905 · 46 · 17710.1002/zaac.19050460112 ↗
50. The system magnesium–tin and the compound Mg4Sn2
51. The constitution of the magnesium-rich alloys in the systems magnesium–lead, magnesium–tin, magnesium–germanium, and magnesium–silicon
52. Thermal analysis of Mg–Sn alloys by calorimetric measurements for determination of the liquidus curve part 1
53. Quatitative thermal analysis of magnesium–tin alloys by calorimetric measurement for the determination of solidus and liquidus curves
54. Magnesium–tin phase diagram and thermodynamic properties of liquid magnesium–tin alloys
55. Thermodynamic properties of compounds of magnesium and group IVB elements
56. The Molecular weights of metals when in solution10.1039/CT8905700376 ↗
57. On the liquidus in tin-rich Sn–Mg alloys10.1007/BF02643105 ↗
58. Phase diagram of binary magnesium alloys
59. Electrical conductivity and binary alloys phase diagram
60. Solubility of tin in magnesium
61. Stepanow · Zeitschrift fur Anorganische Chemie · 1912 · 78 · 110.1002/zaac.19120780102 ↗
62. Gann · Transactions of the Metals Society AIME · 1929 · 83 · 309
63. Nishinura · Transactions of the Institution of Mining and Metallurgy Alumni Assocication · 1940 · 10 · 343
64. Eldridge · Transactions of the Metals Society AIME · 1967 · 239 · 775
65. Caulfield · Solid State Communications · 1966 · 4 · 29910.1016/0038-1098(66)90457-1 ↗
66. Kawakami · Scientific Reports of Reserch Institute Tohoku University · 1930 · 19 · 521
67. Sommer · MetaUkd. · 1980 · 71 · 818
68. Determination of the heats of formation of the solid and liquid Mg–Sn alloys at 20° and 800 °C respectively and the heat content of the alloys at 800 °C
69. Nayak · Transaction of The Indian Institute of Metals · 1971 · 22
70. Thermodynamic properties of Mg–Pb system
71. Thermodynamic properties of liquid Mg+Pb and Mg+Sn alloys by e.m.f. measurements10.1016/0021-9614(70)90008-X ↗
72. Kubaschewski · Z. Elektrochem. · 1939 · 45 · 732
73. Systematic affinity principle XLVII, the relation of mercury to a few metals
74. Determination of the activities of magnesium in liquid magnesium–tin alloys by vapor pressure measurements10.1139/v62-108 ↗
75. Heat of formation of magnesium-tin alloys
76. Influence of the structure of intermetallic compounds on thermodynamic properties of metallic systems
77. Thermal study of group II–IV semiconductors, II- heat capacity of Mg2Sn in the range 5–300 K10.1016/0022-3697(67)90119-9 ↗
78. Electronic and thermal transport properties of Mg2Sn crystals containing finely dispersed eutectic structures10.1002/pssa.201026119 ↗
79. Thermodynamics of liquid magnesium alloys using CaF2 solid electrolytes10.1016/0022-3115(74)90111-1 ↗
80. A chemical theory for the thermodynamics of highly-solvated liquid metal mixtures10.1002/aic.690280222 ↗
81. Nature of the dissociation of Mg stannide and thermodynamic properties of Mg–Sn melts
82. Thermodynamic modeling of the Mg–Si–Sn system10.1016/j.calphad.2006.12.003 ↗
83. Thermodynamic modeling of the Mg–Ge–Si, Mg–Ge–Sn, Mg–Pb–Si and Mg–Pb–Sn systems10.1016/j.jallcom.2010.01.045 ↗
84. Thermodynamic assessments of the Sn–Zn and In–Zn binary systems10.1016/S0364-5916(97)00009-6 ↗
85. The Sn–Zn (Tin–Zinc) system10.1007/BF02880511 ↗
86. Oelson · Z MetalWe · 1957 · 48 · 1
87. The sensitivity and re-producibility of measurements with microcalorimeter
88. Dobavisek · Rudarsko Metals of Zbornik · 1960 · 3 · 273
89. Ptak · Archiv Hutnichva · 1960 · 5 · 169
90. Hamaguchi · Mem. Ehi. Univ., sect. III Eng. · 1973 · 7 · 51
91. Thermodynamic studies on Zn–Sn liquid solutions
92. On the recrystallization of metals
93. On the presence of certain amount of eutectics in metals by the estimation of maximum tension stress in dependence with temperature
94. The solid solubility of silver, gold and zinc in metallic tin10.1007/BF01033827 ↗
95. Embrittlement of tin at elevated temperatures and its relation to impurities
96. The freezing points of alloys containing zinc and another metal10.1039/CT8977100383 ↗
97. About the binary systems of zinc–tin, zinc–cadmium, tin–cadmium and the ternary system zinc–tin–cadmium10.1002/zaac.19130830119 ↗
98. The ternary system aluminum–zinc–tin
99. The constitution of cadmium-tin-zinc alloys
100. A thermodynamic study of liquid metallic solutions, Vi. calorimentric investigations of the systems bismuth–lead, cadmium–lead, cadmium–tin and tin–zinc10.1021/j150526a018 ↗