Exploring the electrochemical properties of Cu-substituted Li2CoTi3O8 as anode material for lithium-ion batteries
Source abstract
Abstract
Spinel Li2Co1–xCuxTi3O8 nanopowders (x = 0, 0.25, 0.5 molar ratios) were synthesized via a sol–gel auto-combustion scheme. The preparation conditions like annealing temperature, Cu2+ ion substituted on the crystallinity, microstructure and chemical composition were inspected using X-ray diffraction, X-rays photoelectron spectroscopy and field emission scanning electron microscopy. Furthermore, the electrochemical performance of the Li2Co0.75Cu0.25Ti3O8 electrode towards the Li-ion battery was inspected via potentiodynamic cyclic voltammetry experiment, galvanostatic charge/discharge tests and electrochemical impedance spectroscopy. Li2Co0.75Cu0.25Ti3O8 electrode exhibited a good reversible charge–discharge capacity with a primary discharge capacity of 527 mAh g−1 and excellent cycling stability of 98.75% coulombic efficiency.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (34)
Show source-provided references
1. Tarascon J M and Armand M 2001 Nature 414 35910.1038/35104644 ↗
2. Fayed M G, Attia S Y, Barakat Y F, El-Shereafy E E, Rashad M M and Mohamed S G 2021 Sustain Mater. Technol. 29 e00306
3. Choi J W and Aurbach D 2016 Nat. Rev. Mater. 1 1601310.1038/natrevmats.2016.13 ↗
4. Manthiram A 2017 ACS Cent. Sci. 3 106310.1021/acscentsci.7b00288 ↗
5. Bresser D, Paillard E, Copley M, Bishop P, Winter M and Passerini S 2012 J. Power Sources 219 21710.1016/j.jpowsour.2012.07.035 ↗
6. Luo W, Chen X Q, Xia Y, Chen M, Wang L J, Wang Q Q et al 2017 Adv. Energy Mater. 7 170108310.1002/aenm.201701083 ↗
7. Park C-M, Kim J-H, Kim H and Sohn H-J 2010 Chem. Soc. Rev. 39 311510.1039/b919877f ↗
8. Li H, Wang Z, Chen L and Huang X 2009 Adv. Mater. 21 459310.1002/adma.200901710 ↗
9. Barreca D, Cruz-Yusta M, Gasparotto A, Maccato C, Morales J, Pozza A et al 2010 J. Phys. Chem. C 114 1005410.1021/jp102380e ↗
10. Zhang L, Hu P, Zhao X, Tian R, Zou R and Xia D 2011 J. Mater. Chem. 21 1827910.1039/c1jm12990b ↗
11. Mohamed S G, Hung T-F, Chen C-J, Chen C K, Hu S F, Liu R S et al 2013 RSC Adv. 3 2014310.1039/c3ra42625d ↗
12. Halankar K K, Mandal B P, Nigam S, Majumder C, Srivastava A P, Agarwal R et al 2021 Energy Fuels 35 1255610.1021/acs.energyfuels.1c01017 ↗
13. Luan S, Han M, Xi Y, Wei K, Wang Y, Zhou J et al 2020 Ionics 26 5110.1007/s11581-019-03182-3 ↗
14. Halankar K K, Mandal B P, Jangid M K, Mukhopadhyay A, Abharana N, Nayak C et al 2020 J Alloys Compd. 844 15607610.1016/j.jallcom.2020.156076 ↗
15. Shi Y, Hua C, Li B, Fang X, Yao C, Zhang Y et al 2013 Adv. Funct. Mater. 23 183210.1002/adfm.201202144 ↗
16. Li N, Zhang Y, Zhao H, Liu Z, Zhang X and Du Y 2016 Inorg. Chem. 55 276510.1021/acs.inorgchem.5b02558 ↗
17. Lu Y, Yu L and Lou X W D 2018 Chem. 4 97210.1016/j.chempr.2018.01.003 ↗
18. Hong Z and Wei M 2013 J. Mater. Chem. A 1 440310.1039/c2ta01312f ↗
19. Wang J, Zhao H, Shen Y, Du Z, Chen X and Xia Q 2013 ChemPlusChem. 78 153010.1002/cplu.201300235 ↗
20. Chen W, Du R, Liang H, Zhou Z, Shao L, Shu J et al 2014 J. Power Sources 272 62210.1016/j.jpowsour.2014.09.011 ↗
21. Fang L, Chu D, Zhou H, Chen X and Yang Z 2011 J. Alloys Compd. 509 188010.1016/j.jallcom.2010.10.078 ↗
22. Wang L, Xiao Q, Li Z, Lei G, Wub L, Zhang P et al 2012 J. Electrochim. Acta 77 7710.1016/j.electacta.2012.05.072 ↗
23. Hong Z, Zheng X, Ding X, Jiang L, Wei M and Wei K 2011 Energy Environ. Sci. 4 188610.1039/c0ee00833h ↗
24. Li X, Xiao Q, Liu B, Lin H and Zhao J 2015 J. Power Sources 273 12810.1016/j.jpowsour.2014.08.129 ↗
25. Chen W, Du R, Ren W, Liang H, Xu B, Shu J et al 2014 Ceram. Int. 40 1375710.1016/j.ceramint.2014.05.083 ↗
26. Chen W, Liang H, Qi Z, Shao L, Shu J and Wang Z 2015 Electrochim. Acta 174 120210.1016/j.electacta.2015.06.101 ↗
27. Rao C V and Rambabu B 2010 Solid State Ion. 181 83910.1016/j.ssi.2010.04.016 ↗
28. Rashad M M, Khalifa A, Rayan D A and Fayed M G 2018 J. Mater. Sci: Mater. Electron. 29 3391
29. Zhang H, Zhai C, Wu J, Ma X and Yang D 2008 Chem. Commun. 43 564810.1039/b812752b ↗
30. Dambournet D, Belharouak I and Amine K 2010 Inorg. Chem. 49 282210.1021/ic902222g ↗
31. Wang G X, Bradhurst D H, Dou S X and Liu H K 1999 J. Power Sources 83 15610.1016/S0378-7753(99)00290-6 ↗
32. Yi T, Xie Y, Shu J, Wang Z, Yue C, Zhu R et al 2011 J. Electrochem. Soc. 158 26610.1149/1.3533391 ↗
33. Tian B, Xiang H, Zhang L, Li Z and Wang H 2010 Electrochim. Acta 55 545310.1016/j.electacta.2010.04.068 ↗
34. Chen Z, Wang J, Chao D, Baikie T, Bai L, Chen S et al 2016 Sci. Rep. 6 2577110.1038/srep25771 ↗