Semiconductivity and superhydrophobicity in an oligo-(p-phenyleneethynylene) (OPE)-based luminescent MOF
Source abstract
Abstract
An oligo-(p-phenyleneethynylene) (OPE)-based water repellent, luminescent and electrically conducting Mg-metal-organic framework (MOF) {[Mg3(OPE-C18)3(H2O)2]·2DMF}n (1) has been synthesized and structurally characterized. Ultra-high water contact angles (170°) and isotropic semiconductivity have been observed in 1 in both crystalline and thin-film states. DFT calculations support a ‘through bond’ mode of electrical conductance. To the best our knowledge, this report is only the second instance of a superhydrophobic and electrically conducting luminescent bulk MOF.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Organic and Molecular Conductors Research · Magnetism in coordination complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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